Novel photomaterials from layered silicate-organometal complexes nanohyrids
Project/Area Number |
20750165
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Inorganic industrial materials
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Research Institution | Tokyo Institute of Technology |
Principal Investigator |
MOCHIZUKI Dai Tokyo Institute of Technology, 大学院・理工学研究科, 助教 (90434315)
|
Project Period (FY) |
2008 – 2009
|
Project Status |
Completed (Fiscal Year 2009)
|
Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
|
Keywords | 層状 / 層間化合物 / 層状ケイ酸塩 / ナノハイブリッド / 発光材料 / イリジウム錯体 / 光物性 / 発光素子 / シリル化 |
Research Abstract |
Efficient phosphorescence of iridium complexes in homogeneous systems has a problem of lower efficiency due to luminescence self-quenching. To obtain highly efficient light-emmitting systems of iridium complexes, cyclometalated iridium(III) complexes were prepared within the interspace of the layered silicates in several ways. The products showed MLCT absortion and emmition in the visible region derived from iridium complex and some other photoluminescence properties were changed in these compounds compared with those in homogeneous systems.
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Report
(3 results)
Research Products
(29 results)