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Novel photomaterials from layered silicate-organometal complexes nanohyrids

Research Project

Project/Area Number 20750165
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic industrial materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

MOCHIZUKI Dai  Tokyo Institute of Technology, 大学院・理工学研究科, 助教 (90434315)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords層状 / 層間化合物 / 層状ケイ酸塩 / ナノハイブリッド / 発光材料 / イリジウム錯体 / 光物性 / 発光素子 / シリル化
Research Abstract

Efficient phosphorescence of iridium complexes in homogeneous systems has a problem of lower efficiency due to luminescence self-quenching. To obtain highly efficient light-emmitting systems of iridium complexes, cyclometalated iridium(III) complexes were prepared within the interspace of the layered silicates in several ways. The products showed MLCT absortion and emmition in the visible region derived from iridium complex and some other photoluminescence properties were changed in these compounds compared with those in homogeneous systems.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (29 results)

All 2010 2009 2008

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (26 results) Book (1 results)

  • [Journal Article] Measurements of Accurate Temperatures in the Microwave Reactors2010

    • Author(s)
      D. Mochizuki, Y. Wada
    • Journal Title

      Mini-Reviews in Organic Chemistry 6(in press)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Design of Molecularly Ordered Framework of Mesoporous Silica with Squared One-Dimensional Channels2008

    • Author(s)
      T. Kimura, et. al.
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 201-209

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 層状ケイ酸塩層間でのシクロメタル化イリジウム錯体の合成と発光特性の検討2010

    • Author(s)
      杉山元彦, 徐晨, 望月大, 和田雄二
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] イリジウム錯体-ゼオライトナノハイブリッド光触媒系の構築2010

    • Author(s)
      徐晨, 望月大, 和田雄二
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 可視光下での色素増感型半導体触媒による水素発生反応2010

    • Author(s)
      〓从紅, 望月大, 和田雄二
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] マイクロ波照射の不均一触媒有機化学反応系における反応促進効果2010

    • Author(s)
      太田創之, 長南聡, 棚橋俊輝, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] マイクロ波加熱によるAu/Ag/Cuナノ粒子の合成2010

    • Author(s)
      王丹, 滝沢翔平, 望月大, 和田雄二
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] マイクロ波加熱による銀を含む二元金属ナノ粒子の合成2010

    • Author(s)
      望月大, 滝沢翔平, 塚原保徳, 山内智央, 和田雄二
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-26
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] マイクロ波加熱モードの特徴を活かした金属ナノハイブリッド系の合成と触媒機能2009

    • Author(s)
      滝沢翔平, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      第3回日本電磁波エネルギー応用学会シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2009-11-19
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] マイクロ波照射下における不均一触媒作用促進効果2009

    • Author(s)
      太田創之, 長南聡, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      第3回日本電磁波エネルギー応用学会シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2009-11-19
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] Ag-Cuどんぐり型ナノ粒子触媒によるアルコールの脱水素反応2009

    • Author(s)
      滝沢翔平, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2009-09-29
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] 可視光応答性光触媒を目指すイリジウム錯体-ゼオライトナノハイブリッドの構築2009

    • Author(s)
      徐晨, 望月大, 和田雄二
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2009-09-29
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] マイクロ波照射下における不均一触媒を用いた有機化学反応での反応促進効果2009

    • Author(s)
      太田創之, 長南聡, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      第104回触媒討論会
    • Place of Presentation
      宮崎
    • Year and Date
      2009-09-29
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] ゼオライト-イリジウム錯体ナノハイブリッドの発光特性と光触媒への応用2009

    • Author(s)
      望月大, 徐晨, 和田雄二
    • Organizer
      第28回光がかかわる触媒化学シンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2009-06-05
    • Related Report
      2009 Annual Research Report 2009 Final Research Report
  • [Presentation] オクトシリケート層表面へのアルコキシシリル基を有するチタンアルコキシドの導入2009

    • Author(s)
      K. -m. CHOI, 望月大, 黒田一幸
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-29
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] マイクロ波を用いた酸化タングステンナノ粒子の合成2009

    • Author(s)
      設楽昌史, 望月大, 和田雄二
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-27
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] 感圧色素のメソポーラスシリカへの導入2009

    • Author(s)
      田村伸一, 望月大, 満尾和徳, 和田雄二
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Year and Date
      2009-03-27
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] シリカナノ空間に導入したカルボニル基を有する有機分子の光物性2008

    • Author(s)
      望月大, 塚原保徳, 山内智央, 和田雄二
    • Organizer
      第24回ゼオライト研究発表会
    • Place of Presentation
      東京
    • Year and Date
      2008-11-27
    • Related Report
      2009 Final Research Report 2008 Annual Research Report
  • [Presentation] シリカナノ空間に内包した4- acetylbiphenylの光物性2008

    • Author(s)
      望月大, 塚原保徳, 山内智央, 和田雄二
    • Organizer
      2008年光化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-11
    • Related Report
      2009 Final Research Report
  • [Presentation] ゼオライト-トリスオルトメタル化イリジウム錯体ナノハイブリッドの構築2008

    • Author(s)
      徐晨, 望月大, 塚原保徳, 山内智央, 和田雄二
    • Organizer
      2008年光化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-11
    • Related Report
      2009 Final Research Report
  • [Presentation] シリカナノ空間に内包した4-acetylbiphenylの光物性2008

    • Author(s)
      望月大ら
    • Organizer
      2008年光化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] ゼオライト・トリスオルトメタル化イリジウム錯体ナノハイブリッドの構築2008

    • Author(s)
      大阪
    • Organizer
      2008年光化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      2008-09-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] Figure. 3 ACBP反応生成物の発光スペクトル層状オクトシリケート層間への安息香酸部位の固定化2008

    • Author(s)
      松尾侑紀, 山中暁子, 望月大, 黒田一幸
    • Organizer
      第52回粘土科学討論会
    • Place of Presentation
      沖縄
    • Year and Date
      2008-09-03
    • Related Report
      2009 Final Research Report
  • [Presentation] 層状オクトシリケート層間への安息香酸部位の固定化2008

    • Author(s)
      松尾侑紀, 山中暁子, 望月大, 黒田一幸
    • Organizer
      第52回粘土科学討論会
    • Place of Presentation
      沖縄
    • Year and Date
      2008-09-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Bimetallic Nanoparticles Prepared by Microwave-Assisted Alcohol Reduction2008

    • Author(s)
      滝沢翔平, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      GCMEA2008
    • Place of Presentation
      大津
    • Year and Date
      2008-08-05
    • Related Report
      2009 Final Research Report
  • [Presentation] Specific Microwave Effects in Microwave-Assisted Ether Generating Reaction through Dimerization of Alcohol and the Following Friedel-Crafts Reaction2008

    • Author(s)
      太田創之, 長南聡, 望月大, 山内智央, 塚原保徳, 和田雄二
    • Organizer
      GCMEA2008
    • Place of Presentation
      大津
    • Year and Date
      2008-08-05
    • Related Report
      2009 Final Research Report
  • [Presentation] Bimetallic Nanoparticles Prepared by Microwave-Assisted Alcohol Reduction2008

    • Author(s)
      S.Takizawa ら
    • Organizer
      GCMEA2008
    • Place of Presentation
      Otsu
    • Year and Date
      2008-08-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] Specific Microwave Effects in Microwave-Assisted Ether Generating Reaction through Dimerization of Alcohol and the Following Friedel-Crafts Reaction2008

    • Author(s)
      S. Ohta ら
    • Organizer
      GCMEA2008
    • Place of Presentation
      Otsu
    • Year and Date
      2008-08-05
    • Related Report
      2008 Annual Research Report
  • [Book] ディスプレイと照明の材料技術2010

    • Author(s)
      和田雄二, 望月大
    • Total Pages
      11
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Annual Research Report 2009 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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