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Direct observation of nanoscale structural changes in bulk metallicglasses

Research Project

Project/Area Number 20760442
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Physical properties of metals
Research InstitutionOsaka University

Principal Investigator

AKIHIKO Hirata  Osaka University, 原子分子材料科学高等研究機構, 助教 (90350488)

Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords原子 / 電子構造 / 金属ガラス / ナノ構造 / 透過電子顕微鏡 / ナノ結晶化 / ガラス安定性 / バルク金属ガラス / 局所構造解析 / 結晶化過程 / 透過型電子顕微鏡 / 原子クラスター / 準結晶 / ナノビーム電子回折 / 複雑金属間化合物
Research Abstract

I have examined nanoscale structural changes during crystallization in Fe-based bulk metallic glasses mainly by means of transmission electron microscopy. As a result, the crystallization took place via a formation and sequence change of atomic clusters rather than thorough a nucleation and growth mechanism. In addition, quasicrystal-like structures were also found in the initial stages of crystallization. The existences of such multiple stable structures based on atomic clusters are probably related to the high glass stabilities in these glasses.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (23 results)

All 2010 2009 2008 Other

All Journal Article (17 results) (of which Peer Reviewed: 17 results) Presentation (4 results) Remarks (2 results)

  • [Journal Article]2010

    • Author(s)
      A. Hirata, Y. Hirotsu, K. Amiya, A. Inoue
    • Journal Title

      J. Alloy. Compd. (in press)

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      A. Hirata, Y. Hirotsu, K. Amiya, N. Nishiyama, A. Inoue
    • Journal Title

      Phys. Rev. B 80, 140201

      Pages: 1-4

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      A. Hirata, Y. Hirotsu, E. Matsubara
    • Journal Title

      Intermetallics 17

      Pages: 796-801

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      A. Hirata, N. Kawahara, Y. Hirotsu, A. Makino
    • Journal Title

      Intermetallics 17

      Pages: 186-189

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      A. Hirata, Y. Hirotsu, K. Amiya, A. Inoue
    • Journal Title

      Phys. Rev. B 79, 020205R

      Pages: 1-4

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      A. Hirata, S. Kuboya, Y. Hirotsu, T. G. Nieh
    • Journal Title

      J. Alloy. Compd. 483

      Pages: 64-69

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local structure changes on annealing in an Fe-Si-B-P bulk metallic glass2009

    • Author(s)
      Akihiko Hirata, Naoto Kawahara, Yoshihiko Hirotsu, Akihiro Makino
    • Journal Title

      Intermetallics 17

      Pages: 186-189

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoscale metastable state exhibiting pseudotenfold diffraction pattern in Fe-based bulk metallic glass2009

    • Author(s)
      Akihiko Hirata, Yoshihiko Hirotsu, Kenji Amiya, Akihisa Inoue
    • Journal Title

      Physical Review B 79

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization behaviours around the glass transition temperature in an amorphous Fe-Nb-B alloy2009

    • Author(s)
      Akihiko Hirata, Yoshihiko Hirotsu, Eiichiro Matsubara
    • Journal Title

      Intermetallics 17

      Pages: 796-801

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fe23B6-type quasicrystal-like structures without icosahedral atomic arrangement in an Fe-based metallic glass2009

    • Author(s)
      Akihiko Hirata, Yoshihiko Hirotsu, Eiichiro Matsubara
    • Journal Title

      Physical Review B 80

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoscale metastable state exhibiting pseudotenfold diffraction pattern in Fe-based bulk metallic glass2009

    • Author(s)
      Akihiko Hirata, Yoshihiko Hirotsu, Kenji Amiya, and Akihisa Inoue
    • Journal Title

      Physical Review B 79

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2008

    • Author(s)
      A. Hirata, Y. Hirotsu, K. Amiya, A. Inoue
    • Journal Title

      Phys. Rev. B 78

      Pages: 144205-144205

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article]2008

    • Author(s)
      A. Hirata, Y. Hirotsu, K. Amiya, N. Nishiyama, A. Inoue
    • Journal Title

      Intermetallics 16

      Pages: 491-497

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Nanocrystallization of complex Fe_<23>B_6-type structure in glassy Fe-Co-B-Si-Nb alloy2008

    • Author(s)
      Akihiko Hirata, Yoshihiko Hirotsu, Kenji Amiya, Nobuyuki Nishiyama, and Akihisa Inoue
    • Journal Title

      Intermetallics 16

      Pages: 491-500

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization process and glass stability of an Fe_<48>Cr_<15>Mo_<14>C_<15>B_6Tm_2 bulk metallic glass2008

    • Author(s)
      Akihiko Hirata, Yoshihiko Hirotsu, Kenji Amiya, and Akihisa Inoue
    • Journal Title

      Physical Review B 78

      Pages: 1442051-6

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local structural fluctuation in Pd-Ni-P bulk metallic glasses examined using nanobeam electron diffraction

    • Author(s)
      Akihiko Hirata, Satoru Kuboya, Yoshihiko Hirotsu, and T. G. Nieh
    • Journal Title

      Journal of Alloys and Compounds (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallization behaviours around the glass transition temperature in an amorphous Fe-Nb-B alloy

    • Author(s)
      Akihiko Hirata, Yoshihiko Hirotsu, and Eiichiro Matsubara
    • Journal Title

      Intermetallics (in press)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Amorphous and Nanostructured Materials2009

    • Author(s)
      A. Hirata, Y. Hirotsu, K. Amiya, A. Inoue
    • Organizer
      16th International Symposium on Metastable
    • Place of Presentation
      Beijing, China.
    • Year and Date
      2009-07-08
    • Related Report
      2009 Final Research Report
  • [Presentation] Nanoscale structural changes on the crystallization of Fe-based BMG2009

    • Author(s)
      Akihiko Hirata, Yoshihiko Hirotsu, Kenji Amiya, Akihisa Inoue
    • Organizer
      16th International Symposium on Metastable, Amorphous and Nanostructured Materials
    • Place of Presentation
      Beijing, China
    • Year and Date
      2009-07-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] Formation process of χ-FeCrMo structure in Fe-Cr-Mo-C-B-Tm metallic glass2008

    • Author(s)
      kihiko Hirata, Yoshihiko Hirotsu, Kenji Amiya, and Akihisa Inoue
    • Organizer
      9th Asia-Pacific Microscopy Conference
    • Place of Presentation
      韓国、済州島
    • Year and Date
      2008-11-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] Fe_<48>Cr_<15>Mo_<14>C_<15>B_6Tm_2金属ガラスにおけるX-Fe_<62>Cr_<21>Mo_<17>相形成の初期過程2008

    • Author(s)
      平田秋彦、弘津禎彦、網谷健児、井上明久
    • Organizer
      日本金属学会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/chen_labo/html-e/personal-Hirata.htm

    • Related Report
      2009 Final Research Report
  • [Remarks]

    • URL

      http://www.wpi-aimr.tohoku.ac.jp/chen_labo/html-e/personal-Hirata.htm

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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