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Synthesis of novel fullerene liquid crystals and their charge-transfer delivertives

Research Project

Project/Area Number 20850025
Research Category

Grant-in-Aid for Young Scientists (Start-up)

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionOsaka University

Principal Investigator

IKUMA Naohiko  Osaka University, 工学研究科, 助教 (70505990)

Research Collaborator OSHIMA Takumi  大阪大学, 工学研究科, 教授 (40107082)
KOKUBO Ken  大阪大学, 工学研究科, 講師 (20304008)
Project Period (FY) 2008 – 2009
Project Status Completed (Fiscal Year 2009)
Budget Amount *help
¥3,276,000 (Direct Cost: ¥2,520,000、Indirect Cost: ¥756,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,716,000 (Direct Cost: ¥1,320,000、Indirect Cost: ¥396,000)
Keywords自己組織化 / 電気・電子デバイス / フラーレン / 液晶
Research Abstract

To obtain novel fullerene liquid crystals, several fullerene delivertives has been synthesized via four reaction pathways ; (i) Rh-catalytic hydroarylation, (ii) 1,3-dipolar cycloaddition, (iii) Diels-Alder reaction of fulleroid, and (iv) Fridel-Crafts arylation of fullerene oxide. The tharmal analysis of the product from the (iv) pathway indicated some mesomorphic phase transition.

Report

(3 results)
  • 2009 Annual Research Report   Final Research Report ( PDF )
  • 2008 Annual Research Report
  • Research Products

    (11 results)

All 2010 2009 Other

All Journal Article (2 results) (of which Peer Reviewed: 2 results) Presentation (6 results) Remarks (3 results)

  • [Journal Article] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroids vs Methanofullerene and C602010

    • Author(s)
      Naohiko Ikuma, Yasunori Susami, Takumi Oshima
    • Journal Title

      Org. Biomol. Chem. 8

      Pages: 1394-1398

    • Related Report
      2009 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroids vs Methanofullerene and C_602010

    • Author(s)
      N.Ikuma
    • Journal Title

      Org.Biomol.Chem. 8

      Pages: 1394-1398

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] フレロイドの酸化反応における速度論的研究2010

    • Author(s)
      住岡慧子, 伊熊直彦, 小久保研, 大島巧
    • Organizer
      日本化学会第90回春季年会
    • Year and Date
      2010-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] フレロイド、メタノフラーレン及びアザフレロイドと各種ジエンとのDiels-Alder反応における速度論的研究2010

    • Author(s)
      田中伸英, 伊熊直彦, 小久保研, 大島巧
    • Organizer
      日本化学会第90回春季年会
    • Year and Date
      2010-03-28
    • Related Report
      2009 Final Research Report
  • [Presentation] フレロイドの酸化反応における速度論的研究2010

    • Author(s)
      住岡慧子
    • Organizer
      日本化学会 第90回春季年会
    • Place of Presentation
      東大阪市
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] フレロイド、メタノフラーレン及びアザフレロイドと各種ジエンとのDiels-Alder反応における速度論的研究2010

    • Author(s)
      田中伸英
    • Organizer
      日本化学会 第90回春季年会
    • Place of Presentation
      東大阪市
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroid2009

    • Author(s)
      Naohiko. Ikuma, Yasunori Susami, Ken Kokubo, Takumi Oshima
    • Organizer
      the 11th International KYOTO conference on New Aspests of Organic Chemistry (IKCOC-11)
    • Year and Date
      2009-11-12
    • Related Report
      2009 Final Research Report
  • [Presentation] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroid2009

    • Author(s)
      N.Ikuma
    • Organizer
      The 11th International KYOTO conference on New Aspests of Organic Chemistry(IKCOC-11)
    • Place of Presentation
      京都市リーガロイヤルホテル
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Remarks] 大島研ホームページ

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/

    • Related Report
      2009 Final Research Report
  • [Remarks] 大島研webページ

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/

    • Related Report
      2009 Annual Research Report
  • [Remarks] 大島研論文リスト

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/publist.htm

    • Related Report
      2009 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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