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Ultrahigh pressure structural change in silicate magma at pressures near the core-mantle boundary

Research Project

Project/Area Number 20H00201
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Review Section Medium-sized Section 17:Earth and planetary science and related fields
Research InstitutionEhime University

Principal Investigator

Kono Yoshio  愛媛大学, 地球深部ダイナミクス研究センター, 准教授 (20452683)

Co-Investigator(Kenkyū-buntansha) 新田 清文  公益財団法人高輝度光科学研究センター, 分光推進室, 研究員 (00596009)
尾原 幸治  島根大学, 学術研究院機能強化推進学系, 教授 (00625486)
則竹 史哉  山梨大学, 大学院総合研究部, 助教 (50755569)
近藤 望  愛媛大学, 地球深部ダイナミクス研究センター, 特定研究員 (70824275)
Project Period (FY) 2020-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥45,630,000 (Direct Cost: ¥35,100,000、Indirect Cost: ¥10,530,000)
Fiscal Year 2023: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2022: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2021: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2020: ¥29,640,000 (Direct Cost: ¥22,800,000、Indirect Cost: ¥6,840,000)
Keywords高圧 / マグマ / ガラス / 非晶質構造 / ケイ酸塩 / 動径分布関数 / マントル / 動径分布関数測定
Outline of Research at the Start

高圧下におけるケイ酸塩マグマの構造転移の理解は、鉱物の結晶構造転移と同様に、地球深部の構造・状態を理解する上で必要不可欠である。本研究では、研究代表者が独自に開発した対向型二段式大容量セル技術を基に、核-マントル境界の超高圧下における非晶質大試料の超高圧実験技術の開発と、それと組み合わせた高精度のケイ酸塩ガラスの動径分布関数測定システムを開発することにより、ケイ酸塩マグマのアナログ物質であるケイ酸塩ガラスにおけるSi-O配位数6配位以上の超高圧構造転移を実験的に明らかにし、核-マントル境界の超高圧下におけるケイ酸塩マグマの構造・状態の理解を目指す。

Outline of Final Research Achievements

Combination of ultrahigh pressure experiment using opposed type double stage cell and pair distribution function measurement enabled us to determined X-ray structure factor [S(Q)] at much wider range of Q compared to previous studies. The new experiment enabled us to precisely determine Si-O coordination number of SiO2 glass at in situ high pressure conditions. The results revealed occurrence of ultrahigh pressure structural change accompanied with the Si-O coordination number change to more than six at ~95 GPa. In addition, precise measurement of S(Q) by using newly developed high pressure pair distribution function measurement setup, combined with molecular dynamics simulation and reverse Monte Carlo modelling, enabled us to conduct detailed structural analysis of SiO2 glass at high pressure conditions. These new experiments advance understanding of the structural change of silicate magmas at high pressure conditions of the Earth’s interior.

Academic Significance and Societal Importance of the Research Achievements

本研究により、地球のマントル深部の圧力下において、ケイ酸塩マグマの構造はSi-O配位数6以上の超高圧構造に変化することを明らかにし、6配位構造を持つマントル鉱物よりも高密度な構造に変化することを提案した。このマグマの超高圧構造変化とそれに伴う高密度化が核-マントル境界に存在する高密度マグマの形成要因になっていることが考えられ、地球内部におけるマグマダイナミクスとそれに伴う物理化学現象を議論する上で重要な知見を創出した。さらに、本研究で開発した高精度の高圧下動径分布関数測定は、地球科学のマグマ研究だけでなく、物理学・材料科学など幅広い分野における液体・ガラスの構造研究にも貢献すると考えられる。

Report

(6 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Comments on the Screening Results   Annual Research Report
  • Research Products

    (17 results)

All 2024 2023 2022 2021 2020

All Journal Article (8 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 6 results,  Open Access: 2 results) Presentation (9 results) (of which Int'l Joint Research: 4 results,  Invited: 6 results)

  • [Journal Article] <i>In situ</i> high-pressure pair distribution function measurement of liquid and glass by using 100?keV pink beam2024

    • Author(s)
      Kono Yoshio、Ohara Koji、Kondo Nozomi M.、Higo Yuji、Kakizawa Sho、Yumoto Hirokatsu、Koyama Takahisa、Yamazaki Hiroshi、Senba Yasunori、Ohashi Haruhiko、Inoue Ichiro、Hayashi Yujiro、Yabashi Makina
    • Journal Title

      Review of Scientific Instruments

      Volume: 95 Issue: 1 Pages: 013904-013904

    • DOI

      10.1063/5.0176975

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strong effect of liquid Fe?S on elastic wave velocity of olivine aggregate: Implication for the low velocity anomaly at the base of the lunar mantle2023

    • Author(s)
      Kono Yoshio、Kuwahara Hideharu、Greaux Steeve、Rivers Mark L.、Wang Yanbin、Higo Yuji、Mitsu Keisuke、Kondo Nozomi
    • Journal Title

      Earth and Planetary Science Letters

      Volume: 618 Pages: 118287-118287

    • DOI

      10.1016/j.epsl.2023.118287

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Pressure-induced reversal of Peierls-like distortions elicits the polyamorphic transition in GeTe and GeSe2023

    • Author(s)
      Fujita Tomoki、Chen Yuhan、Kono Yoshio、Takahashi Seiya、Kasai Hidetaka、Campi Davide、Bernasconi Marco、Ohara Koji、Yumoto Hirokatsu、Koyama Takahisa、Yamazaki Hiroshi、Senba Yasunori、Ohashi Haruhiko、Inoue Ichiro、Hayashi Yujiro、Yabashi Makina、Nishibori Eiji、Mazzarello Riccardo、Wei Shuai
    • Journal Title

      Nature Communications

      Volume: 14 Issue: 1 Pages: 7851-7851

    • DOI

      10.1038/s41467-023-43457-y

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] 大容量プレスを活用した動的地球深部科学の開拓2023

    • Author(s)
      河野義生
    • Journal Title

      SPring-8/SACLA利用者情報

      Volume: 28 Pages: 26-33

    • Related Report
      2022 Annual Research Report
  • [Journal Article] Experimental evidence of tetrahedral symmetry breaking in SiO2 glass under pressure2022

    • Author(s)
      Y. Kono, K. Ohara, N. Kondo, H. Yamada, S. Hiroi, F. Noritake, K. Nitta, O. Sekizawa, Y. Higo, Y. Tange, H. Yumoto, T. Koyama, H. Yamazaki, Y. Senba, H. Ohashi, S. Goto, I. Inoue, Y. Hayashi, K. Tamasaku, T. Osaka, J. Yamada, M. Yabashi
    • Journal Title

      Nature Communications

      Volume: 13 Issue: 1 Pages: 2292-2292

    • DOI

      10.1038/s41467-022-30028-w

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] 高圧環境下その場におけるガラスの構造・物性研究2022

    • Author(s)
      河野義生,佐藤友子
    • Journal Title

      放射光

      Volume: 35 Pages: 285-294

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高圧下におけるSiO2ガラスの四面体構造変化のその場測定2022

    • Author(s)
      河野義生
    • Journal Title

      SPring-8/SACLA利用者情報

      Volume: 27 Pages: 294-299

    • Related Report
      2022 Annual Research Report
  • [Journal Article] Structural Evolution of SiO2 Glass with Si Coordination Number Greater than 62020

    • Author(s)
      Kono Yoshio、Shu Yu、Kenney-Benson Curtis、Wang Yanbin、Shen Guoyin
    • Journal Title

      Physical Review Letters

      Volume: 125 Issue: 20 Pages: 205701-205701

    • DOI

      10.1103/physrevlett.125.205701

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Tetrahedral symmetry breaking in SiO2 glass under pressure investigated by high-pressure pair distribution function measurement2023

    • Author(s)
      Yoshio Kono
    • Organizer
      9th International Discussion Meeting on Relaxations in Complex Systems
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Tetrahedral symmetry breaking in SiO2 glass under pressure observed by in situ pair distribution function measurement2023

    • Author(s)
      Yoshio Kono
    • Organizer
      11th International Workshop on Warm Dense Matter
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] SiO2 ガラスにおける四面体構造の変化の高圧下その場放射光X 線測定2022

    • Author(s)
      河野義生,尾原幸治,近藤望,山田大貴,廣井慧,則竹史哉,新田清文,関澤央輝,肥後祐司,丹下慶範,湯本博勝,小山貴久,山崎裕史,仙波泰徳,大橋治彦,後藤俊治,井上伊知郎,林雄二郎,玉作賢治,大坂泰斗,山田純平,矢橋牧名
    • Organizer
      第63回高圧討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Structure measurement of silicate and oxide glasses under ultrahigh pressure conditions to >100 GPa2021

    • Author(s)
      Kono, Y., Ohira, I., Shu, Y., Wang, Y., Shen, G.
    • Organizer
      10th Asian Conference on High Pressure Research
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高温高圧下における液体・非晶質物質のPDF解析2021

    • Author(s)
      河野義生
    • Organizer
      Spring-8シンポジウム2021
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] Interaction between cerium and H2O in hydrous rhyolitic melts2021

    • Author(s)
      近藤望,河野義生,尾原幸治,中田亮一,伊奈稔哲,Skrzypek Etienne,山田明寛,齊藤哲
    • Organizer
      日本地球惑星科学連合2021年大会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 圧力最大120GPaにおけるSiO2ガラスの超高圧構造変化2021

    • Author(s)
      河野義生,SHU Yu,KENNEY-BENSON Curtis,WANG Yanbin,SHEN Guoyin
    • Organizer
      第62回高圧討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] MgSiO3ガラスとCaSiO3ガラスの高圧構造変化2021

    • Author(s)
      近藤望,河野義生,大平格,HRUBIAK Ross,尾原幸治,新田清文,関澤央輝
    • Organizer
      第62回高圧討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] X-ray Research with PE press2020

    • Author(s)
      Yoshio Kono
    • Organizer
      Workshop 'Compact Synchrotron Sources and New X-ray Science Opportunities'
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited

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Published: 2020-04-28   Modified: 2025-01-30  

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