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Novel quantum properties and lattice dynamics caused by suppression of ferroelectricity

Research Project

Project/Area Number 20H01844
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 13020:Semiconductors, optical properties of condensed matter and atomic physics-related
Research InstitutionOsaka Metropolitan University (2022)
Osaka Prefecture University (2020-2021)

Principal Investigator

Ishii Yui  大阪公立大学, 大学院工学研究科, 准教授 (50708013)

Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2022: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2021: ¥8,190,000 (Direct Cost: ¥6,300,000、Indirect Cost: ¥1,890,000)
Fiscal Year 2020: ¥7,800,000 (Direct Cost: ¥6,000,000、Indirect Cost: ¥1,800,000)
Keywords構造量子臨界点 / ソフトモード / ソフトフォノン / フォノン / 構造相転移 / 量子臨界点 / 強誘電体
Outline of Research at the Start

本研究では、(a)BaAl2O4間接型強誘電体が示す強誘電的揺らぎに起因した、新奇フォノン物性を開拓するとともに、(b)非弾性X線散乱、非弾性中性子散乱、PDF解析などの散乱手法を用いて、この強誘電的な揺らぎに起因したdisorder状態での格子ダイナミクスを解明する。これに加え、(c)直接型・間接型強誘電体それぞれに対し、強誘電性の抑制に伴う物性変化を系統的に調べることで、強誘電体の量子物性の開拓とそのミクロスコピックな解明を行い、「強誘電的揺らぎがもたらす物理」の学理基盤を築く。

Outline of Final Research Achievements

In this project, we have revealed that a “sublattice glass state” appears at the structural quantum critical point where an acoustic-phonon-driven structural phase transition is suppressed down to the absolute zero temperature. This state possesses both crystalline periodicity and glasslike atomic arrangement. As a result of the glasslike atomic arrangement, the lattice-specific heat shows an excess approximately at 10 K and a T-linear term at the lowest temperatures, and the thermal conductivity shows a plateau, all of which are the typical characteristics of amorphous solids. In addition, it was found that the atomic vibrational state of this state resembles that amorphous solids typically exhibit.

Academic Significance and Societal Importance of the Research Achievements

量子臨界点の研究はこれまで磁気秩序などスピンのかかわる秩序相を対象として発展し、それに隣接して現れる新奇量子相の研究は、今日に至るまで物性物理学の一大分野を築いている。しかしながら、スピンと並びフォノンも固体中の基本的な量子の1つであるにもかかわらず、フォノンが主役となって現れる量子臨界点の研究はほとんど進んで来なかった。本研究で得られた成果は、従来のスピン主体の量子臨界研究をフォノン系に展開するための足がかりとなると期待できる。

Report

(4 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • Research Products

    (20 results)

All 2023 2022 2021 2020

All Journal Article (5 results) (of which Int'l Joint Research: 3 results,  Peer Reviewed: 5 results) Presentation (15 results) (of which Int'l Joint Research: 8 results,  Invited: 7 results)

  • [Journal Article] Comparative study on the specific heat of ferroelectrics with a structural quantum critical point2022

    • Author(s)
      Yui Ishii, Arisa Yamamoto, Shigeo Mori
    • Journal Title

      JAPANESE JOURNAL OF APPLIED PHYSICS

      Volume: 61 Issue: SN Pages: SN1017-SN1017

    • DOI

      10.35848/1347-4065/ac8047

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Partial breakdown of translation symmetry at a structural quantum critical point associated with a ferroelectric soft mode2022

    • Author(s)
      Ishii Y.、Yamamoto A.、Sato N.、Nambu Y.、Ohira-Kawamura S.、Murai N.、Ohara K.、Kawaguchi S.、Mori T.、Mori S.
    • Journal Title

      Physical Review B

      Volume: 106 Issue: 13 Pages: 134111-134111

    • DOI

      10.1103/physrevb.106.134111

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Lone-Pair-Induced Intra-and Interlayer Polarizations in Sillen-Aurivillius Layered Perovskite Bi4NbO8Br2022

    • Author(s)
      Zhong C, Ishii Y, Tassel C, Zhu T, Kato D, Kurushima K, Fujibayashi Y, Saito T, Ogawa T, Kuwabara A, Mori S, Kageyama H
    • Journal Title

      Inorganic chemistry

      Volume: 61 Issue: 25 Pages: 9816-9822

    • DOI

      10.1021/acs.inorgchem.2c01358

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superconductivity Enhanced by Abundant Low-Energy Phonons in (Sr1-xCax)3Rh4Sn132021

    • Author(s)
      Y. Terasaki, R. Yamaguchi, Y. Ishii, Y. Tada, A. Yamamoto, and S. Mori
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 90 Issue: 11 Pages: 113704-113704

    • DOI

      10.7566/jpsj.90.113704

    • NAID

      210000159383

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Structural phase transition in cobalt oxyfluoride Co3Sb4O6F6 observed by high-resolution synchrotron and neutron diffraction2021

    • Author(s)
      S. Shimono, H. Ishibashi, Y. Nagayoshi, H. Ikeno, S. Kawaguchi, M. Hagihala, S. Torii, T. Kamiyama, K. Ichihashi, S. Nishihara, K. Inoue, Y. Ishii, Y. Kubota
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 163 Pages: 110568-110568

    • DOI

      10.1016/j.jpcs.2021.110568

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Ag1-xAuxCrSe2の熱伝導率に対するAu置換効果2023

    • Author(s)
      泉翔太, 石井悠衣, 森茂生
    • Organizer
      日本物理学会 2023年春季大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Low-Energy Phonons Enhanced near the Structural Quantum Critical Point of the Strong-Coupling Superconductor (Sr1-xCax)3Rh4Sn132022

    • Author(s)
      Yasuhiro Terasaki, Ratsuki Yamaguchi, Yui Ishii, Yurina Tada, Arisa Yamamoto, and Shigeo Mori
    • Organizer
      LT29
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Glasslike thermal properties caused by a structural quantum critical point2022

    • Author(s)
      Y. Ishii, A. Yamamoto, N. Sato, Y. Nambu, S. Ohira-Kawamura, N. Murai, K. Ohara, S. Kawaguchi, T. Mori, and S. Mori
    • Organizer
      IInd INTERNATIONAL WORKSHOP - THERMAL CONDUCTIVITY OF SOLID STATES at low temperatures
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 構造量子臨界点をもつ強誘電体の比熱に関する比較研究2022

    • Author(s)
      石井 悠衣, 山本 有梨沙, 森 茂生
    • Organizer
      第39回強誘電体会議
    • Related Report
      2022 Annual Research Report
  • [Presentation] (Sr1-xCax)3Rh4Sn13の強結合超伝導と低エネルギーフォノン2022

    • Author(s)
      石井悠衣, 寺崎保裕, 山口羅月, 多田有里奈, 山本有梨沙, 森茂生
    • Organizer
      日本物理学会
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ferroelastic Domain and Low-Temperature Structures of Sillen-Aurivillius-type Photocatalysts Bi4NbO8X (X = Cl, Br)2021

    • Author(s)
      Y. Ishii, Y. Fujibayashi, K. Kurushima, K. Uchihashi, S. Mori, C. Zhong, D. Kato, H. Kageyama
    • Organizer
      International Conference on Mixed-Anion Compounds
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Spin reorientation in layered perovskite oxyfluoride Pb3Fe2O5F22021

    • Author(s)
      K. Oka, Y. Nambu, M. Ochi, N. Hayashi, Y. Kusano, T. Aoyama, Y. Ishii, K. Kuroki, S. Mori, M. Takano, N. Noma, M. Iwasaki and H. Kageyama
    • Organizer
      International Conference on Mixed-Anion Compounds
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ナノ結晶軟磁性合金の微細構造と磁気特性2021

    • Author(s)
      大迫 明弘,吉年 規治,中島 宏,石井 悠衣, 原田 研,森 茂生
    • Organizer
      日本顕微鏡学会
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Ba1-xSrxAl2O4が示すフォノンの低エネルギー励起2021

    • Author(s)
      石井悠衣, 山本有梨沙, 佐藤直大, 南部雄亮, 河村聖子, 村井直樹, 森孝雄, 森茂生
    • Organizer
      日本物理学会
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 放射光 X 線回折による酸素四面体の頂点共有ネットワークをもつ強誘電体の構造相転移2021

    • Author(s)
      中平夕貴, 若松徹, 石井悠衣, 森茂生, 寺崎一郎, 谷口博基, 森吉千佳子
    • Organizer
      日本物理学会
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 充填トリジマイト型酸化物Ba1-xSrxAl2O4の熱物性2020

    • Author(s)
      石井悠衣、山本有梨沙、佐藤直大、森孝雄、森茂生
    • Organizer
      日本物理学会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Hollow-cone Foucault imaging of magnetic microstructures in large magnetostrictive FeGa alloy2020

    • Author(s)
      S. Mori, A. Kawaguchi, A. Kotani, H. Numakura, Y. Ishii and K. Harada
    • Organizer
      M&M 2020 Conference
    • Related Report
      2020 Annual Research Report
  • [Presentation] 蓄光型蛍光体Sr1-x-yEuxBayAl2O4の微細構造と発光特性2020

    • Author(s)
      鴨井 智宏、塚崎 裕文、中島 宏、林 直顕、石井 悠衣、森 茂生
    • Organizer
      日本セラミックス協会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 六方晶マンガン酸化物におけるTi置換に伴う結晶構造変化と特異なドメイン構造2020

    • Author(s)
      内橋 研人、塚崎 裕文、Ferrnando Cubillasm、石橋 広記、久保田佳基、石井 悠衣、森 茂生、山崎 順
    • Organizer
      日本セラミックス協会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ホロコーン暗視野法/フーコ法を用いた磁性材料の微細構造解析2020

    • Author(s)
      森茂生、大迫明弘、中島宏、石井悠衣、原田研
    • Organizer
      日本結晶学会
    • Related Report
      2020 Annual Research Report

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Published: 2020-04-28   Modified: 2024-01-30  

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