• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Accurate Measurements of Thermodynamic Properties and Thermodynamic Analysis of a State-of-the-Art Equation of State for Ternary Fluid Mixtures with Hydrogen Extended from Type III Binary Systems

Research Project

Project/Area Number 20H02091
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 19020:Thermal engineering-related
Research InstitutionKyushu University

Principal Investigator

Sakoda Naoya  九州大学, 工学研究院, 准教授 (30532337)

Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2022: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2021: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2020: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Keywords水素 / 混合系 / 飽和密度 / PVTx性質 / 熱物性 / 冷媒 / 精密計測 / 混合流体
Outline of Research at the Start

臨界曲線が高圧域へ発散し,純物質の性質とは全く異なるType IIIの水素 + 二酸化炭素の2成分系に第3成分を追加し,Type III + 第3成分系の熱力学状態曲面について,PVT性質,気液平衡および臨界点の各装置を開発するとともに,精密測定を行って明らかにする.また,臨界点測定に関しては,試料容器内に直接センサプローブを設置した測定手法を試みる.本研究ではさらに最新の高精度状態方程式において,複数臨界点が存在する可能性のある3成分系への適用可能性について,計算アルゴリズムの確立とともに検証を行う.

Outline of Final Research Achievements

Accurate thermodynamic properties of hydrogen mixtures are essential in the hydrogen society. Binary systems of hydrogen + hydrocarbons or carbon dioxide have a discontinuous critical curve that diverges to a high pressure region, and are classified as Type III, whose behavior is far different from that of pure fluids. In this study, a saturated density and PVTx properties of hydrogen mixtures have been accurately measured. The phase boundary behavior of ternary mixtures including hydrogen calculated from an equation of state was discussed.

Academic Significance and Societal Importance of the Research Achievements

これまでの混合系の飽和状態に関する実測値は温度,圧力,組成に限られることが多く,密度情報は十分で無い.水素を含む混合系の場合,正確な組成の決定や密度測定は非常に困難であるが,本研究では重量法を用いた組成の決定や正確な飽和密度測定を確立した.本研究で確立した方法により,水素混合系の正確な熱物性値の取得が可能になる.さらに状態方程式を用いて水素を含む3成分系の相境界線の挙動につて検証しており,今後の水素利用社会において水素混合物の正確な熱的挙動の解明の一助となる.

Report

(4 results)
  • 2023 Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • Research Products

    (5 results)

All 2024 2022 2021

All Presentation (5 results) (of which Int'l Joint Research: 1 results)

  • [Presentation] 水素 + 二酸化炭素 2 成分系混合流体の飽和密度測定2024

    • Author(s)
      迫田 直也, 田頭 大飛, 河野 正道
    • Organizer
      第60回日本伝熱シンポジウム
    • Related Report
      2022 Annual Research Report
  • [Presentation] 非凝縮性気体を含む2成分系混合流体のPVTx性質および粘性係数測定2022

    • Author(s)
      迫田直也, 緑川優太郎, 岡本剛明, 河野正道
    • Organizer
      第59回日本伝熱シンポジウム
    • Related Report
      2021 Annual Research Report
  • [Presentation] PVTx Property Measurement of a Hydrogen Binary Mixture by an Isochoric Method and Application of the Method to Other Properties2022

    • Author(s)
      Naoya Sakoda, Yutaro Midorikawa, Takeaki Okamoto, Masamichi Kohno
    • Organizer
      The 13th Asian Thermophysical Properties Conference
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水素を含む2成分系混合流体の熱力学性質とPVTx性質測定2021

    • Author(s)
      迫田直也, 戸島健太郎, 緑川優太郎, 河野正道
    • Organizer
      第58回日本伝熱シンポジウム
    • Related Report
      2020 Annual Research Report
  • [Presentation] 非凝縮性気体を含む2成分系混合流体における粘性係数測定装置の開発2021

    • Author(s)
      緑川優太郎, 岡本剛明, 河野正道, 迫田直也
    • Organizer
      熱工学コンファレンス2021
    • Related Report
      2020 Annual Research Report

URL: 

Published: 2020-04-28   Modified: 2025-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi