• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Hierarchical Chain Dynamics and Carrier Porpeties for Functional Polymers

Research Project

Project/Area Number 20H02802
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Review Section Basic Section 35020:Polymer materials-related
Research InstitutionThe University of Tokyo (2023)
Kyushu University (2020-2022)

Principal Investigator

Kawaguchi Daisuke  東京大学, 大学院工学系研究科(工学部), 特任教授 (70362267)

Project Period (FY) 2020-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥17,550,000 (Direct Cost: ¥13,500,000、Indirect Cost: ¥4,050,000)
Fiscal Year 2023: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2022: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Fiscal Year 2021: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2020: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Keywords分子鎖ダイナミクス / 界面 / 薄膜 / 励起状態 / 電荷生成 / 電荷移動 / 凝集状態 / 薄膜化効果
Outline of Research at the Start

エレクトロニクス・エネルギーデバイスに資する高分子半導体や高分子電解質などの機能性高分子の電荷特性と分子鎖ダイナミクスの関係を明らかにする。まず、官能基レベルの局所ダイナミクスを評価し、セグメントダイナミクスとの融合を図ることで、機能性高分子の階層的分子鎖ダイナミクスについて検討する。さらに、これと電荷の生成および移動に関するダイナミクスを比較することで、機能発現に及ぼす分子鎖ダイナミクスの効果について明らかにする。

Outline of Final Research Achievements

In this study, the chain dynamics and the carrier properties for various functional polymers were examined. The carrier properties in a typical semiconducting polymer of poly(3-hexylthiophene) were closely related to the relaxation temperature for the twisting motion of thiophene rings in a crystalline phase. Also, we directly examined the energy state of the cured epoxy compound near the copper interface through the behavior of the excited species.

Academic Significance and Societal Importance of the Research Achievements

本研究成果の学術的意義は、従来、主に分子構造と機能の関係が着目されてきた機能性高分子に構造・物性の観点から機能発現の要因を探る方法論を与えた点にある。これは、機能性高分子の研究開発サイクルの加速化に貢献するものと期待される。また、励起子をプローブにした相互作用の評価法は、埋もれた界面の新しい解析方法を提案するとともに、界面の理解を促進させるものである。

Report

(5 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Annual Research Report
  • 2021 Annual Research Report
  • 2020 Annual Research Report
  • Research Products

    (116 results)

All 2024 2023 2022 2021 2020

All Journal Article (31 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 31 results,  Open Access: 4 results) Presentation (85 results) (of which Int'l Joint Research: 16 results,  Invited: 5 results)

  • [Journal Article] Electronic Interaction of Epoxy Resin with Copper at the Adhered Interface2024

    • Author(s)
      Saeki Shintaro、Kawaguchi Daisuke、Tsuji Yuta、Yamamoto Satoru、Yoshizawa Kazunari、Tanaka Keiji
    • Journal Title

      Langmuir

      Volume: 40 Issue: 18 Pages: 9725-9731

    • DOI

      10.1021/acs.langmuir.4c00711

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Neutron Reflectometry Analysis of Condensed Water Layer Formation at a Solid Interface of Epoxy Resins Under High Humidity2023

    • Author(s)
      Liu Yuwei、Miyata Noboru、Miyazaki Tsukasa、Shundo Atsuomi、Kawaguchi Daisuke、Tanaka Keiji、Aoki Hiroyuki
    • Journal Title

      Langmuir

      Volume: 39 Issue: 29 Pages: 10154-10162

    • DOI

      10.1021/acs.langmuir.3c01091

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aggregation states, thermal molecular motion and carrier properties in functional polymer thin films2023

    • Author(s)
      Kawaguchi Daisuke
    • Journal Title

      Polymer Journal

      Volume: 55 Issue: 12 Pages: 1237-1245

    • DOI

      10.1038/s41428-023-00820-6

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 界面分子鎖の緩和挙動に基づく複合材料設計2023

    • Author(s)
      川口大輔
    • Journal Title

      日本接着学会誌

      Volume: 59 Pages: 296-301

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Demonstration of efficient transfer learning in segmentation problem in synchrotron radiation X-ray CT data for epoxy resin2023

    • Author(s)
      Hamamoto Satoru、Oura Masaki、Shundo Atsuomi、Kawaguchi Daisuke、Yamamoto Satoru、Takano Hidekazu、Uesugi Masayuki、Takeuchi Akihisa、Iwai Takahiro、Seto Yasuo、Joti Yasumasa、Sato Kento、Tanaka Keiji、Hatsui Takaki
    • Journal Title

      Science and Technology of Advanced Materials: Methods

      Volume: 3 Issue: 1 Pages: 2270529-2270529

    • DOI

      10.1080/27660400.2023.2270529

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Enhanced ionic conductivity in block copolymer electrolytes through interfacial passivation using mixed ionic liquids2023

    • Author(s)
      Min Jaemin、Bae Suhyun、Kawaguchi Daisuke、Tanaka Keiji、Park Moon Jeong
    • Journal Title

      The Journal of Chemical Physics

      Volume: 159 Issue: 17 Pages: 174906-174906

    • DOI

      10.1063/5.0173322

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Depth analysis of local conformation in poly(methyl methacrylate) adsorbed onto SiOx studied by soft X-ray absorption spectroscopy combined with an Ar gas cluster ion beam2023

    • Author(s)
      Yamane Hiroyuki、Oura Masaki、Kawaguchi Daisuke、Nitta Kiyofumi、Sekizawa Oki、Ishikawa Tetsuya、Yamamoto Satoru、Tanaka Keiji、Hatsui Takaki
    • Journal Title

      Polymer Journal

      Volume: 56 Issue: 3 Pages: 215-220

    • DOI

      10.1038/s41428-023-00864-8

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Absolute local conformation of poly(methyl methacrylate) chains adsorbed on a quartz surface2023

    • Author(s)
      Kawaguchi Daisuke、Sasahara Kazuki、Inutsuka Manabu、Abe Tatsuki、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      The Journal of Chemical Physics

      Volume: 159 Issue: 24 Pages: 1-8

    • DOI

      10.1063/5.0184315

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Improvement of polymer adhesion by designing the interface layer2023

    • Author(s)
      Kawaguchi Daisuke、Nakayama Reika、Koga Hiroki、Totani Masayasu、Tanaka Keiji
    • Journal Title

      Polymer

      Volume: 265 Pages: 125581-125581

    • DOI

      10.1016/j.polymer.2022.125581

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pyridyl anchoring squaraine as a near-infrared dye sensitizer for effective sensitized hydrogen production over a titanium dioxide photocatalyst in water medium2023

    • Author(s)
      Xiao Feng Shen, Motonori Watanabe, Atsushi Takagaki, Jun Tae Song, Tatsuki Abe, Daisuke Kawaguchi, Keiji Tanaka, Tatsumi Ishihara
    • Journal Title

      Applied Physics A: Materials Science and Processing

      Volume: 129 Issue: 1 Pages: 28-28

    • DOI

      10.1007/s00339-022-06281-7

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Aggregation States of Polymer Chains at Interfaces Based on Neutron Reflectivity2023

    • Author(s)
      Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Oleoscience

      Volume: 23 Issue: 3 Pages: 143-151

    • DOI

      10.5650/oleoscience.23.143

    • ISSN
      1345-8949, 2187-3461
    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Change in Local Conformation of Polymer Chains at Film Surface Attached to Solid Surface2022

    • Author(s)
      Harada Rei、Kawaguchi Daisuke、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      Soft Matter

      Volume: 18 Issue: 17 Pages: 3304-3307

    • DOI

      10.1039/d1sm01833g

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Oligomer Segregation on the Aggregation State and Strength at the Polystyrene/Substrate Interface2022

    • Author(s)
      Inutsuka Manabu、Watanabe Hirohmi、Aoyagi Masaru、Yamada Norifumi L.、Tanaka Chisa、Ikehara Takayuki、Kawaguchi Daisuke、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      ACS Macro Letters

      Volume: 11 Issue: 4 Pages: 504-509

    • DOI

      10.1021/acsmacrolett.2c00062

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sum Frequency Generation Imaging for Semi-Crystalline Polymers2022

    • Author(s)
      Abe Tatsuki、Shimada Hironao、Hoshino Taiki、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Polymer Journal

      Volume: 54 Issue: 5 Pages: 679-685

    • DOI

      10.1038/s41428-021-00613-9

    • Related Report
      2022 Annual Research Report 2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics of the interfacial curing reaction for an epoxy-amine mixture2022

    • Author(s)
      Yamaguchi Ko、Kawaguchi Daisuke、Miyata Noboru、Miyazaki Tsukasa、Aoki Hiroyuki、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 24 Issue: 36 Pages: 21578-21582

    • DOI

      10.1039/d2cp03394a

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystalline Structure, Molecular Motion and Photocarrier Formation in Thin Films of Monodisperse Poly(3-Hexylthiophene) with Various Molecular Weights2022

    • Author(s)
      Kawaguchi Daisuke、Higasayama Ayano、Ogata Yudai、Kabe Taizo、Matsushita Yushu、Tanaka Keiji
    • Journal Title

      Polymer Journal

      Volume: 55 Issue: 4 Pages: 497-505

    • DOI

      10.1038/s41428-022-00713-0

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The role of the molecular weight of the adsorbed layer on a substrate in the suppressed dynamics of supported thin polystyrene films2022

    • Author(s)
      Ren Weizhao、Wang Xin、Shi Jiahui、Xu Jianquan、Taneda Hidenobu、Yamada Norifumi L.、Kawaguchi Daisuke、Tanaka Keiji、Wang Xinping
    • Journal Title

      Soft Matter

      Volume: 18 Issue: 10 Pages: 1997-2005

    • DOI

      10.1039/d2sm00067a

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Enhanced Glass Transition Temperature of Thin Polystyrene Films Having an Underneath Cross-Linked Layer2022

    • Author(s)
      Bai Lu、Luo Pan、Yang Xudong、Xu Jianquan、Kawaguchi Daisuke、Zhang Cuiyun、Yamada Norifumi L.、Tanaka Keiji、Zhang Wei、Wang Xinping
    • Journal Title

      ACS Macro Letters

      Volume: 11 Issue: 2 Pages: 210-216

    • DOI

      10.1021/acsmacrolett.1c00611

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] ポリプロピレン系複合材料の引張特性に及ぼす無水マレイン酸変性プロピレンの添加効果2022

    • Author(s)
      甲加晃一, 日笠茂樹, 織田ゆか里, 川口大輔, 田中敬二
    • Journal Title

      日本接着学会誌

      Volume: 58 Pages: 29-35

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 表面・界面のレオロジー2021

    • Author(s)
      川口大輔, 田中敬二
    • Journal Title

      接着の技術

      Volume: 41 Pages: 26-30

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two-Dimensional Cellular Patterning on a Polymer Film Based on Interfacial Stiffness2021

    • Author(s)
      Kawabata Kento、Totani Masayasu、Kawaguchi Daisuke、Matsuno Hisao、Tanaka Keiji
    • Journal Title

      Langmuir

      Volume: 37 Issue: 51 Pages: 14911-14919

    • DOI

      10.1021/acs.langmuir.1c02776

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Sum Frequency Generation Spectroscopy for Understanding the Polymer Dynamics at Buried Interfaces2021

    • Author(s)
      Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Spectroscopic Techniques for Polymer Characterization

      Volume: 1 Pages: 227-258

    • DOI

      10.1002/9783527830312.ch8

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular picture of fluoropolymer adsorption on nanocarbon materials2021

    • Author(s)
      Kawaguchi Daisuke、Sasahara Kazuki、Saito Daiki、Uejima Mitsugu、Fujiwara Hirotada、Nishimura Shin、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      Polymer Journal

      Volume: 53 Issue: 12 Pages: 1469-1473

    • DOI

      10.1038/s41428-021-00528-5

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local Orientation of Chains at Crystal/Amorphous Interfaces Buried in Isotactic Polypropylene Thin Films2021

    • Author(s)
      Kawaguchi Daisuke、Yamamoto Kentaro、Abe Tatsuki、Jiang Naisheng、Koga Tadanori、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 23 Issue: 41 Pages: 23466-23472

    • DOI

      10.1039/d1cp03959h

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Mobility gradients yield rubbery surfaces on top of polymer glasses2021

    • Author(s)
      Hao Zhiwei、Ghanekarade Asieh、Zhu Ningtao、Randazzo Katelyn、Kawaguchi Daisuke、Tanaka Keiji、Wang Xinping、Simmons David S.、Priestley Rodney D.、Zuo Biao
    • Journal Title

      Nature

      Volume: 596 Issue: 7872 Pages: 372-376

    • DOI

      10.1038/s41586-021-03733-7

    • Related Report
      2021 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] An Effect of Crystallographic Distortion on Carrier Mobility in Poly(3-hexylthiophene) Thin Films2021

    • Author(s)
      Tatsuki Abe、Daisuke Kawaguchi、Motonori Watanabe、Taiki Hoshino、Tatsumi Ishihara、Keiji Tanaka
    • Journal Title

      Applied Physics Letters

      Volume: 118 Issue: 18 Pages: 181601-181601

    • DOI

      10.1063/5.0041881

    • Related Report
      2021 Annual Research Report 2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Poly[oligo(2-ethyl-2-oxazoline) methacrylate] as a surface modifier for bioinertness2021

    • Author(s)
      Hong Jin-Hyeok、Totani Masayasu、Kawaguchi Daisuke、Yamada Norifumi L.、Matsuno Hisao、Tanaka Keiji
    • Journal Title

      Polymer Journal

      Volume: 53 Issue: 5 Pages: 643-653

    • DOI

      10.1038/s41428-020-00459-7

    • Related Report
      2021 Annual Research Report 2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of a Bioinert Interface Using an Amphiphilic Block Copolymer Containing a Bottlebrush Unit of Oligo(oxazoline)2020

    • Author(s)
      Hong Jin-Hyeok、Totani Masayasu、Kawaguchi Daisuke、Masunaga Hiroyasu、Yamada Norifumi L.、Matsuno Hisao、Tanaka Keiji
    • Journal Title

      ACS Applied Bio Materials

      Volume: 3 Issue: 11 Pages: 7363-7368

    • DOI

      10.1021/acsabm.0c01118

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Direct observation of morphological transition for an adsorbed single polymer chain2020

    • Author(s)
      Oda Yukari、Kawaguchi Daisuke、Morimitsu Yuma、Yamamoto Satoru、Tanaka Keiji
    • Journal Title

      Scientific Reports

      Volume: 10 Issue: 1 Pages: 20914-20914

    • DOI

      10.1038/s41598-020-77761-0

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Surface Segregation of a Star-Shaped Polyhedral Oligomeric Silsesquioxane in a Polymer Matrix2020

    • Author(s)
      Yamamoto Kentaro、Kawaguchi Daisuke、Abe Tatsuki、Komino Takeshi、Mamada Masashi、Kabe Taizo、Adachi Chihaya、Naka Kensuke、Tanaka Keiji
    • Journal Title

      Langmuir

      Volume: 36 Issue: 33 Pages: 9960-9966

    • DOI

      10.1021/acs.langmuir.0c01785

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Detailed Structural Study on the Poly(vinyl alcohol) Adsorption Layers on a Si Substrate with Solvent Vapor-Induced Swelling2020

    • Author(s)
      Miyazaki Tsukasa、Miyata Noboru、Yoshida Tessei、Arima Hiroshi、Tsumura Yoshihiro、Torikai Naoya、Aoki Hiroyuki、Yamamoto Katsuhiro、Kanaya Toshiji、Kawaguchi Daisuke、Tanaka Keiji
    • Journal Title

      Langmuir

      Volume: 36 Issue: 13 Pages: 3415-3424

    • DOI

      10.1021/acs.langmuir.9b03964

    • Related Report
      2020 Annual Research Report
    • Peer Reviewed
  • [Presentation] Observation of the Interfacial Layer Designed to Improve Polymer Adhesion2024

    • Author(s)
      〇Daisuke Kawaguchi, Reika Nakayama, Hiroki Koga, Masayasu Totani, Keiji Tanaka
    • Organizer
      APS March Meeting 2024
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Conformational Relaxation of Styrene-Butadiene Rubbers Having a Different Microstructure but the Same Composition at Hydrophilic and Hydrophobic Interface2023

    • Author(s)
      〇Hidenobu Taneda, Kosuke Fujino, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      PRCR2023
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 湿熱劣化により促進されるエポキシ接着界面における水の偏析2023

    • Author(s)
      〇山口晃, 川口大輔, 戸谷匡康, 宮田登, 宮崎司, Yuwei Liu, 青木裕之, 田中敬二
    • Organizer
      第72回高分子学会年次大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 固体吸着鎖のバルク鎖への化学結合形成による界面接着強度の向上2023

    • Author(s)
      ○川口大輔、中山峰花、古賀弘樹、戸谷匡康、田中敬二
    • Organizer
      第72回高分子学会年次大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 高分子半導体薄膜の凝集構造と励起子ダイナミクスに及ぼす分子量の効果2023

    • Author(s)
      〇川口大輔、日笠山綾乃、山口修平、緒方雄大、加部泰三、松下裕秀、田中敬二
    • Organizer
      2023年繊維学会年次大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 湿熱劣化過程におけるエポキシ接着界面への水の収着2023

    • Author(s)
      〇山口晃、川口大輔、戸谷匡康、宮田登、宮崎司、Yuwei Liu、青木裕之、田中敬二
    • Organizer
      第61回日本接着学会年次大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 石英界面におけるポリメタクリル酸メチルの局所配向と接着特性2023

    • Author(s)
      〇阿部建樹、川口大輔、田中敬二
    • Organizer
      第61回日本接着学会年次大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 固体界面におけるポリメタクリル酸メチルの配向イメージング2023

    • Author(s)
      ○阿部建樹、川口大輔、田中敬二
    • Organizer
      九州地区高分子若手研究会・夏の講演会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 界面相互作用の理解に向けたエポキシ硬化物の励起状態評価2023

    • Author(s)
      〇佐伯慎太郎、川口大輔、田中敬二
    • Organizer
      化学関連支部合同九州大会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Sum Frequency Generation Imaging of Chain Orientation for Polymer Thin Films2023

    • Author(s)
      ◯Tatsuki Abe, Hironao Shimada, Taiki Hoshino, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      9IDMRCS
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 化学状態の異なる固体表面上へのポリスチレン吸着鎖の凝集状態2023

    • Author(s)
      ◯種子田 英伸、川口 大輔、山本 智、田中 敬二
    • Organizer
      第72回高分子討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 石英界面におけるポリメタクリル酸メチルの配向イメージング2023

    • Author(s)
      ◯阿部建樹、川口大輔、田中敬二
    • Organizer
      第72回高分子討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] [1.1.1]プロペランとフルオロアルケンの共重合による新規フッ素ポリマーの合成と物性評価2023

    • Author(s)
      〇奥田 瑞来, 増田 潤季, 木幡 愛, 中川 慎太郎, 柏木 王明, 杉山 徳英, 岡添 隆, 川口 大輔, 秋山 みどり
    • Organizer
      第72回高分子討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] フッ素ガスを用いた液相フッ素化法による環状ペルフルオロアルキル化合物の合成2023

    • Author(s)
      〇中島稔喜・門田晃司・相川光介・川口大輔・岡添隆
    • Organizer
      第46回フッ素化学討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] 湿熱環境が促進するエポキシ接着界面における水の収着2023

    • Author(s)
      ◯山口晃、川口大輔、戸谷匡康、宮田登、宮崎司、Yuwei Liu、青木裕之、田中敬二
    • Organizer
      令和5年度九州地区高分子若手研究会・冬の講演会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Synthesis and Properties of Copolymers Composed of [1.1.1]Propellane and Fluoroalkenes2023

    • Author(s)
      〇Mizuki Okuda, Junki Masuda, Ai Kohata, Shintaro Nakagawa, Kimiaki Kashiwagi, Norihide Sugiyama, Takashi Okazoe, Daisuke Kawaguchi, Midori Akiyama
    • Organizer
      The 6th G'L'owing Polymer Symposium in KANTO (GPS-K 2023)
    • Related Report
      2023 Annual Research Report
  • [Presentation] 液相直接フッ素化法による環状ペルフルオロアルキル化合物の合成とその性質2023

    • Author(s)
      〇中島稔喜・門田晃司・杦山真史・相川光介・川口大輔・岡添隆
    • Organizer
      第12回フッ素化学若手の会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Surface Relaxation Behavior of a Cross-linked Poly(dimethyl siloxane) Film after Exposure to CO22023

    • Author(s)
      ○Daisuke Kawaguchi, Huiqiang Lu, Keiji Tanaka
    • Organizer
      MRM2023
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 背面入射中性子反射率測定に基づく湿熱劣化したエポキシ接着界面における水の偏析2023

    • Author(s)
      山口 晃, 〇種子田英伸, 戸谷匡康, 宮田 登, 宮崎 司, Yuwei Liu, 川口大輔, 青木裕之, 田中敬二
    • Organizer
      量子ビームサイエンスフェスタ
    • Related Report
      2022 Annual Research Report
  • [Presentation] Direct Observation of In-plane Diffusion of Isolated Polymethacrylates Chains on Solid Surfaces2023

    • Author(s)
      ◯Masayuki Kawano, Yuma Morimitsu, Satoru Yamamoto, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      APS March Meeting 2023
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Kinetics of Initial Curing Reaction for an Epoxy-Amine Mixture at an Outermost Solid Interface2022

    • Author(s)
      ○Ko Yamaguchi, Daisuke Kawaguchi, Satoru Yamamoto, Keiji Tanaka
    • Organizer
      5th G'L'owing Polymer Symposium in KANTO (GPS-K 2022)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Direct Observation of In-plane Diffusion for Isolated Chains of Poly(methacrylate)s on Solid Surfaces2022

    • Author(s)
      ○Masayuki Kawano, Yuma Morimitsu, Satoru Yamamoto, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      The 3rd Kyushu-Mainz Chemistry Symposium & The 7th CMS International Symposium (CMS-7)
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ポリジメチルシロキサン表面分子鎖の二酸化炭素収着に伴う緩和挙動2022

    • Author(s)
      〇川口大輔, Huiqiang Lu, 田中敬二
    • Organizer
      2022年繊維学会秋季研究発表会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 背面入射中性子反射率測定に基づく固体界面におけるエポキシ硬化物の凝集状態解析2022

    • Author(s)
      〇川口大輔, 山口 晃, 戸谷匡康, 宮田 登, 宮崎 司, Yuwei Liu, 青木裕之, 田中敬二
    • Organizer
      日本中性子科学会第22回年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] ポリジメチルシロキサン架橋膜表面の凝集状態と緩和挙動2022

    • Author(s)
      〇川口大輔, Huiqiang Lu, 田中敬二
    • Organizer
      第70回レオロジー討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 固体界面におけるエポキシ/アミンの硬化挙動2022

    • Author(s)
      〇山口 晃, 川口大輔, 山本 智, 田中敬二
    • Organizer
      第70回レオロジー討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 半導体高分子の励起子ダイナミクスに及ぼす分子量依存性2022

    • Author(s)
      ○川口大輔, 日笠山綾乃, 山口修平, 緒方雄大, 加部泰三, 松下裕秀, 田中敬二
    • Organizer
      第71回高分子討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 高分子薄膜の機能発現に及ぼす界面構造・物性の効果2022

    • Author(s)
      川口大輔
    • Organizer
      第71回高分子討論会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] Surface Aggregation States of Poly(dimethylsiloxane) in Cross-linked Films2022

    • Author(s)
      ○Huiqiang Lu, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第71回高分子討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Direct Observation of Diffusion Behavior for Poly(tert-butyl methacrylate) Single Chains on Solid Surfaces2022

    • Author(s)
      ○Masayuki Kawano, Yuma Morimitsu, Daisuke Kawaguchi, Satoru Yamamoto, Keiji Tanaka
    • Organizer
      第71回高分子討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 接着現象の理解と制御に向けた界面構造解析2022

    • Author(s)
      ○川口大輔, 田中敬二
    • Organizer
      令和4年度中性子産業利用報告会
    • Related Report
      2022 Annual Research Report
    • Invited
  • [Presentation] 表面分子鎖の異種固体接触に伴う局所コンフォメーション変化2022

    • Author(s)
      ○原田 怜、川口大輔、山本 智、田中敬二
    • Organizer
      令和4年度 九州地区高分子若手研究会・夏の講演会
    • Related Report
      2022 Annual Research Report
  • [Presentation] (ポリスチレン/エポキシ)硬化物の界面凝集状態と接着特性2022

    • Author(s)
      ○田 牧翰, 川口大輔, 田中敬二
    • Organizer
      化学関連支部合同九州大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 架橋性基を含有する吸着鎖の凝集状態と界面接着2022

    • Author(s)
      ○川口大輔, 中山峰花, 古賀弘樹, 戸谷匡康, 田中敬二
    • Organizer
      第60回日本接着学会年次大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 固体最界面におけるエポキシ/アミンの硬化挙動2022

    • Author(s)
      ○山口 晃, 川口大輔, 山本 智, 田中敬二
    • Organizer
      第60回日本接着学会年次大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 結晶性高分子膜の和周波発生イメージング2022

    • Author(s)
      ○川口大輔, 阿部建樹, 嶋田紘尚, 星野大樹, 田中敬二
    • Organizer
      2022年繊維学会年次大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] ナノカーボン材料に吸着したフッ素ゴム分子鎖の凝集状態と熱運動性2022

    • Author(s)
      ○川口大輔, 齋藤大輝, 笹原一輝, 上島 貢, 藤原広匡, 西村 伸, 山本  智, 田中敬二
    • Organizer
      日本ゴム協会2022年年次大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Orientational Reorganization of Poly(methyl methacrylate) Chains at a Solid Interface2022

    • Author(s)
      ○Daisuke Kawaguchi, Kazuki Sasahara, Manabu Inutsuka, Satoru Yamamoto, Keiji Tanaka
    • Organizer
      第71回高分子学会年次大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Sum Frequency Generation Imaging for Semi-Crystalline Polymer Films2022

    • Author(s)
      ○Tatsuki Abe, Hironao, Shimada, Taiki Hoshino, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第71回高分子学会年次大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] An Effect of Humidity on Thermal Molecular Motion of Isolated Poly(tert-butyl methacrylate) Chains on Substrates2022

    • Author(s)
      〇Masayuki Kawano, Yuma Morimitsu, Yukari Oda, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第71回高分子学会年次大会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 固体界面におけるポリメタクリル酸メチル鎖の配向緩和2022

    • Author(s)
      ○川口大輔, 笹原一輝, 犬束 学, 山本 智, 田中敬二
    • Organizer
      日本レオロジー学会2022年通常年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 固体最界面におけるエポキシ/アミンの硬化反応動力学2022

    • Author(s)
      ○山口 晃, 川口大輔, 山本 智, 田中敬二
    • Organizer
      日本レオロジー学会2022年通常年会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Observing Thermal Motion for Isolated Poly(tert-butyl methacrylate) Chains on Solid Surfaces2022

    • Author(s)
      Masayuki Kawano,Yuma Morimitsu,Yukari Oda,Daisuke Kawaguchi,Keiji Tanaka
    • Organizer
      APS March meeting 2022
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Initial Curing Process between Epoxy and Amine at a Solid Interface2022

    • Author(s)
      Daisuke Kawaguchi,Ko Yamaguchi,Satoru Yamamoto,Keiji Tanaka
    • Organizer
      APS March meeting 2022
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] エポキシ硬化物の界面凝集状態に及ぼす湿度の効果2022

    • Author(s)
      川口大輔,種子田英伸,青木美佳,宮田 登,宮崎 司,Yuwei Liu,青木裕之,田中敬二
    • Organizer
      2021年度量子ビームサイエンスフェスタ
    • Related Report
      2021 Annual Research Report
  • [Presentation] Orientational Reorganization of Poly(methyl methacrylate) Chains at Quartz Interface2021

    • Author(s)
      Daisuke Kawaguchi,Kazuki Sasahara,Manabu Inutsuka,Satoru Yamamoto,Keiji Tanaka
    • Organizer
      Pacifichem 2021
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体表面におけるポリ(メタクリル酸tert-ブチル)孤立鎖の熱運動観察2021

    • Author(s)
      [川野雅恭,盛満裕真,織田ゆか里,川口大輔,田中敬二
    • Organizer
      高分子学会九州地区高分子若手研究会・冬の講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 固体最界面におけるエポキシ/アミンの硬化初期反応の動力学2021

    • Author(s)
      山口 晃,川口大輔,山本 智,田中敬二
    • Organizer
      高分子学会九州地区高分子若手研究会・冬の講演会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 異なる表面自由エネルギーを有する基板への高分子吸着動力学2021

    • Author(s)
      川口大輔,種子田英伸,山本 智,田中敬二
    • Organizer
      2021年繊維学会秋季研究発表会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 半導体高分子の熱運動特性と電荷生成2021

    • Author(s)
      川口大輔,阿部建樹,緒方雄大,山口修平,田中敬二
    • Organizer
      第69回レオロジー討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] ポリスチレン膜表面の固体接触による局所構造変化とその緩和ダイナミクス2021

    • Author(s)
      原田 怜,川口大輔,田中敬二
    • Organizer
      第69回レオロジー討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 固体最界面におけるエポキシ/アミン硬化初期過程の反応動力学2021

    • Author(s)
      [山口 晃,川口大輔,山本 智,田中敬二
    • Organizer
      第69回レオロジー討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 固体界面におけるポリ(tert-ブチルメタクリレート)孤立鎖の熱運動観察2021

    • Author(s)
      川野雅恭,盛満裕真,織田ゆか里,川口大輔,田中敬二]
    • Organizer
      第69回レオロジー討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Conformational Change of Polystyrene at Film Surface After Contact with a Different Surface2021

    • Author(s)
      〇Rei Harada,Daisuke Kawaguchi,Keiji Tanaka
    • Organizer
      Fall Annual Meeting of The Polymer Society of Korea (PSK)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Direct Observation of Thermal Motion for Isolated Poly(tert-butyl methacrylate) Chains on Solid Surfaces2021

    • Author(s)
      〇Masayuki Kawano,Yuma Morimitsu,Yukari Oda,Daisuke Kawaguchi,Keiji Tanaka
    • Organizer
      Fall Annual Meeting of The Polymer Society of Korea (PSK)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Curing Reaction Kinetics of Epoxy/amine at a Quartz Interface2021

    • Author(s)
      〇Ko Yamaguchi,Daisuke Kawaguchi,Satoru Yamamoto,Keiji Tanaka
    • Organizer
      Fall Annual Meeting of The Polymer Society of Korea (PSK)
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高分子マトリクス中における星型かご状オリゴシルセスキオキサンの表面偏析2021

    • Author(s)
      川口大輔,山本健太郎,阿部建樹,小蓑剛,儘田正史,加部泰三,安達千波矢,中建介,田中敬二
    • Organizer
      第70回高分子討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 石英最界面におけるエポキシ/アミンの反応動力学2021

    • Author(s)
      山口 晃,川口大輔,山本 智,田中敬二
    • Organizer
      第70回高分子討論会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Aggregation States and Proton Conductivity in Perfluorosulfonic Acid Thin Films under Humidity Condition2021

    • Author(s)
      〇Daisuke Kawaguchi,Sigeki Yonemori,Yudai Ogata,Noboru Miyata,Tetsuo Yoshida,Tsukasa Miyazaki,Hiroyuki Aoki,Keiji Tanaka
    • Organizer
      25th Congress of the International Union of Crystallography
    • Related Report
      2021 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 固体表面におけるポリ(tert-ブチルメタクリレート)孤立鎖の形態と熱運動の直接観察2021

    • Author(s)
      川野雅恭,盛満裕真,織田ゆか里,川口大輔,田中敬二
    • Organizer
      第58回化学関連支部合同九州大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 石英界面におけるエポキシ/アミンの硬化初期反応2021

    • Author(s)
      山口 晃,川口大輔,山本 智,田中敬二
    • Organizer
      第58回化学関連支部合同九州大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 界面分子鎖の緩和挙動に基づく複合材料設計2021

    • Author(s)
      川口大輔
    • Organizer
      第59回 日本接着学会年次大会
    • Related Report
      2021 Annual Research Report
    • Invited
  • [Presentation] 水素終端シリコン表面におけるポリ(tert-ブチルメタクリレート)鎖の吸着形態と熱運動の直接観察2021

    • Author(s)
      〇川野雅恭,盛満裕真,織田ゆか里,川口大輔,田中敬二
    • Organizer
      第59回 日本接着学会年次大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 石英界面におけるエポキシ/アミンの硬化初期過程2021

    • Author(s)
      〇山口晃,川口大輔,山本智,田中敬二
    • Organizer
      第59回 日本接着学会年次大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 異種固体界面における高分子鎖の凝集状態に及ぼす吸着エネルギーの影響2021

    • Author(s)
      〇種子田英伸,川口大輔,山本智,田中敬二
    • Organizer
      第70回高分子年次大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] 埋もれた界面における官能基の 配向イメージング2021

    • Author(s)
      〇阿部建樹, 川口大輔, 田中敬二
    • Organizer
      第70回高分子年次大会
    • Related Report
      2021 Annual Research Report
  • [Presentation] Architecture Effect on Conformational Relaxation of Polymer Chains at an Interface2021

    • Author(s)
      Hung K. Nguyen, Daisuke Kawaguchi, ○Keiji Tanaka
    • Organizer
      APS March Meeting 2021
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research
  • [Presentation] エポキシ薄膜界面の凝集状態に及ぼす湿度の効果2021

    • Author(s)
      〇川口大輔, 青木美佳, 宮田 登, 吉田鉄生, 宮崎 司, 青木裕之, 田中敬二
    • Organizer
      2020年度量子ビームサイエンスフェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] ポリオキサゾリンを基盤とする生体不活性界面の凝集状態2021

    • Author(s)
      〇松野寿生, Jinhyeok HONG, 戸谷匡康, 川口大輔, 山田悟史, 田中敬二
    • Organizer
      2020年度量子ビームサイエンスフェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水界面におけるポリオキサゾリン薄膜の分子鎖凝集状態と生体不活性2020

    • Author(s)
      〇松野寿生, Jinhyeok Hong, 戸谷匡康, 川口大輔, 山田悟史, 田中敬二
    • Organizer
      2020年繊維学会秋季研究会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 高分子半導体中の正孔輸送に及ぼす薄膜化効果2020

    • Author(s)
      ○川口大輔, 阿部建樹, 渡邊源規, 石原達己, 田中敬二
    • Organizer
      第68回レオロジー討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] シリコン酸化層界面におけるシンジオタクチックポリメタクリル酸メチルのガラス転移温度2020

    • Author(s)
      ○古賀弘樹, 阿部建樹, 川口大輔, 田中敬二
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] 固体接触界面におけるポリスチレン鎖の緩和挙動2020

    • Author(s)
      ○原田 怜, 川口大輔, 田中敬二
    • Organizer
      第10回CSJ化学フェスタ
    • Related Report
      2020 Annual Research Report
  • [Presentation] SiOx界面におけるシンジオタクチックポリメタクリル酸メチルのガラス転移温度2020

    • Author(s)
      〇古賀弘樹, 阿部建樹, 川口大輔, 田中敬二
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 固体接触に伴うポリスチレン表面分子鎖の緩和挙動2020

    • Author(s)
      〇原田 怜, 川口大輔, 田中敬二
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] ポリ(3-ヘキシルチオフェン)薄膜の正孔輸送に及ぼす界面分子鎖配向の効果2020

    • Author(s)
      〇阿部建樹, 川口大輔, 渡邊源規, 石原達己, 田中敬二
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水浸漬および調湿環境下における高分子電解質薄膜のプロトン伝導に及ぼす界面効果2020

    • Author(s)
      〇川口大輔, 米盛茂樹, 緒方雄大, 宮田 登, 吉田鉄生, 宮崎 司, 山田悟史, 青木裕之, 田中敬二
    • Organizer
      第69回高分子討論会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 中性子反射率測定に基づく高分子電解質薄膜の界面構造解析2020

    • Author(s)
      〇川口大輔, 田中敬二
    • Organizer
      2020年物性研究所短期研究会
    • Related Report
      2020 Annual Research Report
    • Invited
  • [Presentation] モデル接着界面におけるポリスチレン鎖の緩和挙動2020

    • Author(s)
      〇原田 怜, 川口大輔, 田中敬二
    • Organizer
      第58回日本接着学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Local Chain Conformation of Poly(2-ethyl cyanoacrylate) Chains at Alumina Interface2020

    • Author(s)
      ○Daisuke Kawaguchi, Daiki Saito, Keiji Tanaka
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] Chain Dynamics of a Hydrogel Film at Water Interface2020

    • Author(s)
      ○Atsuomi Shundo, Nozomi Itagaki, Daisuke Kawaguchi, Keiji Tanaka
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 固体界面におけるシンジオタクチックポリメタクリル酸メチルのガラス転移温度2020

    • Author(s)
      ○古賀弘樹, Jae Hyun Sim, 川口大輔, 田中敬二
    • Organizer
      第69回高分子学会年次大会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 石英界面におけるポリメタクリル酸メチル鎖の配向緩和2020

    • Author(s)
      ○川口大輔, 笹原一輝, 山本 智, 田中敬二
    • Organizer
      日本レオロジー学会第47年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 水と接した高分子ヒドロゲル界面における分子鎖ダイナミクス2020

    • Author(s)
      ○春藤淳臣, 板垣 望, 川口大輔, 田中敬二
    • Organizer
      日本レオロジー学会第47年会
    • Related Report
      2020 Annual Research Report
  • [Presentation] 固体界面における高分子電解質の 凝集状態とイオン伝導特性2020

    • Author(s)
      ○川口大輔
    • Organizer
      Materials Research Meeting 2020
    • Related Report
      2020 Annual Research Report
    • Int'l Joint Research / Invited

URL: 

Published: 2020-04-28   Modified: 2025-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi