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Development of a method to form hollow silicon spheres, with application to photovoltaic cells: experiment and computation.

Research Project

Project/Area Number 20K04293
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 19010:Fluid engineering-related
Research InstitutionRitsumeikan University

Principal Investigator

WELLS John C.  立命館大学, 理工学部, 教授 (60301644)

Co-Investigator(Kenkyū-buntansha) 河野 悠  立命館大学, 理工学部, 助教 (40822838)
Project Period (FY) 2020-04-01 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2022: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2021: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2020: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
KeywordsSilicon / Hollow spheres / Hollow jet method / Solidification / Silicon. / Hollow spheres. / Hollow jet method. / Hollow / silicon / millisphere / solidification / horn / hollow metal spheres / hollow jet instability / two phase simulations / hollow Si spheres / solar cells / dropping method / coaxial jet flow / numerical simulation
Outline of Research at the Start

By extending the dropping method for production of solid metal spheres to a hollow jet of molten silicon (Si), we aim to develop a simple method of mass-producing hollow Si spheres that are suited to application as photovoltaic cells.

Outline of Final Research Achievements

Hollow silicon millispheres have been fabricated using a hollow coaxial jet for the first time.
Silicon was melted in a graphite crucible at 1823 K, then ejected from the annulus of a coaxial nozzle as argon gas was injected from an inner nozzle whose inner and outer diameters are 0.4 mm and 1 mm respectively. Sphere diameters were 1 - 2 mm with spherical outer surfaces, and the frequency of formation was approximately 145 Hz.
The wall thicknesses varied gradually between antipodes. The interior surfaces were somewhat non-spherical, with horn-like structures where the wall was thicker, most likely owing to silicon expansion as solidification finishes. This is the first report of such a “horn expansion structure” observed on a concave substrate.

Academic Significance and Societal Importance of the Research Achievements

Hollow silicon millispheres have been fabricated using a hollow coaxial jet for the first time. It is hoped that such hollow structures could permit higher photovoltaic energy efficiency that the solid spheres that are currently used for spherical silicon solar cells.

Report

(4 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • 2020 Research-status Report
  • Research Products

    (2 results)

All 2023 2021

All Journal Article (1 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 1 results) Presentation (1 results)

  • [Journal Article] Fabrication of Hollow Silicon Millispheres Through a Coaxial Nozzle, with Observation of a Novel Horn Structure2023

    • Author(s)
      BHAGAT, K.D., VU, T.V., WELLS, J.C., YAMAUE, H., KAWANO, Y., TAKAKURA, H.
    • Journal Title

      Materials Today Communications

      Volume: -

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Presentation] Fabrication of hollow semiconductor spheres by dropping method2021

    • Author(s)
      Kunal D. Bhagat, Truong V. Vu, John C. Wells, Hideyuki Takakura, Yu Kawano and Fumio Ogawa
    • Organizer
      Japanese Society for Multiphase Flow Symposium
    • Related Report
      2021 Research-status Report

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Published: 2020-04-28   Modified: 2024-12-25  

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