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Comprehensive Observation of Interface dipoles at Insulator Semiconductor Interface

Research Project

Project/Area Number 21246008
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionTokyo Institute of Technology

Principal Investigator

IWAI Hiroshi  東京工業大学, フロンティア研究機構, 教授 (40313358)

Co-Investigator(Kenkyū-buntansha) KAKUSHIMA Kuniyuki  東京工業大学, 大学院・総合理工学研究科, 准教授 (50401568)
AHMET Parhat  東京工業大学, フロンティア研究機構, 特任准教授 (00418675)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥46,410,000 (Direct Cost: ¥35,700,000、Indirect Cost: ¥10,710,000)
Fiscal Year 2011: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Fiscal Year 2010: ¥17,680,000 (Direct Cost: ¥13,600,000、Indirect Cost: ¥4,080,000)
Fiscal Year 2009: ¥22,490,000 (Direct Cost: ¥17,300,000、Indirect Cost: ¥5,190,000)
Keywords高誘電体薄膜 / 半導体 / 界面ダイポール / シリケート / 価数変化 / 固定電荷 / 表面・界面物性
Research Abstract

To elucidate the origin of interface dipoles presented at dielectric and semiconductor interface, flatband voltages of MOS capacitors with rare earth oxides have been characterized. A model to reproduce the thickness dependent flatband voltage shift has been proposed. The composition of Si atoms in oxides rarely affects the magnitude of interface dipole. Oxygen atom supply at the interface, either by rare earth oxide stacking or by process, can shift the flatband voltage, suggesting that the main origin of interface dipole is due to oxygen defect during silicate reaction.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (33 results)

All 2012 2011 2010 2009

All Journal Article (20 results) (of which Peer Reviewed: 16 results) Presentation (13 results)

  • [Journal Article] EOT of 0. 62 nm and High Electron Mobility in La-silicate/Si Structure Based nMOSFETs Achieved by Utilizing Metal-Inserted Poly-Si Stacks and Annealing at High Temperature2012

    • Author(s)
      T. Kawanago, K. Kakushima, P. Ahmet, K. Tsutsui, A. Nishiyama, N. Sugii, K. Natori, T. Hattori, H. Iwai
    • Journal Title

      IEEE Trans. Electron Devices

      Volume: Vol.59 Pages: 269-276

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] CovalentNature in La-Silicate Gate Dielectrics for Oxygen Vacancy Removal2012

    • Author(s)
      T. Kawanago, K. Kakushima, P. Ahmet, K. Tsutsui, A. Nishiyama, N. Sugii, K. Natori, T. Hattori, H. Iwai
    • Journal Title

      IEEEElectron Dev. Lett

      Volume: Vol.33 Pages: 423-425

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Valence number transition and silicate formation of cerium oxide films onSi(100)2012

    • Author(s)
      M. Mamatrishat, M. Kouda, K. Kakushima, H. Nohira, P. Ahmet, Y. Kataoka, A. Nishiiyama, K. Tsutsui, N. Sugii, K. Natori, T. Hattori, H. Iwai
    • Journal Title

      Vacuum

      Volume: Vol.86 Pages: 1513-1516

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Properties of CeO_x/La_2O_3 gate dielectric and its effects on the MOS transistor characteristics2012

    • Author(s)
      H. Wong, B. L. Yang, K. Kakushima, P. Ahmet, H. Iwai
    • Journal Title

      Vacuum

      Volume: Vol.86 Pages: 990-993

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Valence number transition and silicate formation of cerium oxide films on Si(100)2012

    • Author(s)
      M. Mamatrishat
    • Journal Title

      Vacuum

      Volume: 86(10) Issue: 10 Pages: 1513-1516

    • DOI

      10.1016/j.vacuum.2012.02.050

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Covalent Nature in La-Silicate Gate Dielectrics for Oxygen Vacancy Removal2012

    • Author(s)
      T.Kawanago, K.Kakushima, P.Ahmet, K.Tsutsui, A.Nishiyama, N.Sugii, K.Natori, T.Hattori, H.Iwai
    • Journal Title

      IEEE Electron Device Letters

      Volume: 33 Issue: 3 Pages: 423-425

    • DOI

      10.1109/led.2011.2178111

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] EOT of 0.62 nm and High Electron Mobility in La-silicate/Si Structure Based nMOSFETs Achieved by Utilizing Metal-Inserted Poly-Si Stacks and Annealing at High Temperature2012

    • Author(s)
      T.Kawanago, K.Kakushima, P.Ahmet, K.Tsutsui, A.Nishiyama, N.Sugii, K.Natori, T.Hattori, H.Iwai
    • Journal Title

      IEEE Transactions on Electron Devices

      Volume: 59 Issue: 2 Pages: 269-276

    • DOI

      10.1109/ted.2011.2174442

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Properties of CeOx/La2O3 gate dielectric and its effects on the MOS transistor characteristics2012

    • Author(s)
      H.Wong, B.L.Yang, K.Kakushima, P.Ahmet, H.Iwai
    • Journal Title

      Vacuum

      Volume: 86 Pages: 990-993

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interface and electrical properties of Tm_2O_3 gate dielectrics for gate oxide scaling in MOS devices2011

    • Author(s)
      M. Kouda, T. Kawanago, P. Ahmet, K. Natori, T. Hattori, H. Iwai, K. Kakushima, A. Nishiyama, N. Sugii, K. Tsutsui
    • Journal Title

      J. Vac. Sci. Technol. B

      Volume: Vol.29 Pages: 62202-62202

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Compensation of oxygen defects in La-silicate gate dielectrics for improving effective mobility in high-k/metal gate MOSFET using oxygen annealing process2011

    • Author(s)
      T. Kawanago, Y. Lee, K. Kakushima, P. Ahmet, K. Tsutsui, A. Nishiyama, N. Sugii, K. Natori, T. Hattori, H. Iwai
    • Journal Title

      Solid-StateElectron

      Volume: Vol.68 Pages: 68-72

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rareearth oxide capping effect on La_2O_3 gatedielectrics for equivalent oxidethickness scaling toward 0. 5 nm2011

    • Author(s)
      M. Kouda, K. Kakushima, P. Ahmet, K. Tsutsui, A. Nishiyama, N. Sugii, K. Natori, T. Hattori, H. Iwai
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: Vol.50

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Compensation of oxygen defects in La-silicate gate dielectrics for improving effective mobility in high-k/metal gate MOSFET using oxygen annealing process2011

    • Author(s)
      T.Kawanago, Y.Lee, K.Kakushima, P.Ahmet, K.Tsutsui, A.Nishiyama, N.Sugii, K.Natori, T.Hattori, H.Iwai
    • Journal Title

      Solid-State Electronics

      Volume: 68 Pages: 68-72

    • DOI

      10.1016/j.sse.2011.10.006

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interface and electrical properties of Tm2O3 gate dielectrics for gate oxide scaling in MOS devices2011

    • Author(s)
      M.Kouda, T.Kawanago, P.Ahmet, K.Natori,T.Hattori, H.Iwai, K.Kakushima, A.Nishiyama, N.Sugii, K.Tsutsui
    • Journal Title

      Journal of Vacuum Science & Technology

      Volume: 29 Issue: 6 Pages: 62202-62202

    • DOI

      10.1116/1.3660800

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rare earth oxide capping effect on La2O3 gate dielectrics for equivalent oxide thickness scaling toward 0.5 nm2011

    • Author(s)
      M.Kouda, K.Kakushima, P.Ahmet, K.Tsutsui, A.Nishiyama, N.Sugii, K.Natori, T.Hattori, H.Iwai
    • Journal Title

      Japanese Journal of Applied Physcis

      Volume: 50

    • NAID

      210000071407

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of flatband voltage roll-off and roll-up behavior in La_2O_3/silicat gate dielectric2010

    • Author(s)
      K. Kakushima, T. Koyanagi, K. Tachi, J. Song, P. Ahmet, K. Tsutsui, N. Sugii, T. Hattori, H. Iwai
    • Journal Title

      Solid-State Electron

      Volume: Vol54 Pages: 720-723

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrical Characteristics of Rare Earth(La, Ce, Pr and Tm) Oxides/Silicates Gate Dielectric2010

    • Author(s)
      K. Matano, K. Funamizu, M. Kouda, K. Kakushima, P. Ahmet, K. Tsutsui, N. Sugii, K. Natori, T. Hattori, H. Iwai
    • Journal Title

      ECSTrans

      Volume: Vol.27 Pages: 1120-1134

    • Related Report
      2011 Final Research Report
  • [Journal Article] Electrical Characteristics of Rare Earth(La, Ce, Pr and Tm)Oxides/Silicates Gate Dielectric2010

    • Author(s)
      K.Matano, et al.
    • Journal Title

      ECS Transaction 27

      Pages: 1129-1134

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Characterization of flatband voltage roll-off and roll-up behavior in La_2 O_3/silicate gate dielectric2010

    • Author(s)
      K.Kakushima, et al.
    • Journal Title

      Solid-State Electronics (in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystallographic Orientation Dependent Electrical Characteristics of La_2O_3 MOS Capacitors2009

    • Author(s)
      H. Nakayama, K. Kakushima, P. Ahmet, E. Ikenaga, K. Tsutsui, N. Sugii, T. Hattori, H. Iwai
    • Journal Title

      ECS Trans

      Volume: Vol.25 Pages: 339-345

    • Related Report
      2011 Final Research Report
  • [Journal Article] Crystallographic Orientation Dependent Electrical Characteristics of La_2 O_3 MOS Capacitors2009

    • Author(s)
      H.Nakayama, et al.,
    • Journal Title

      ECS Transaction 25

      Pages: 339-345

    • Related Report
      2009 Annual Research Report
  • [Presentation] Ce酸化物/Si(100)界面におけるCeの価数とCeシリケート2012

    • Author(s)
      幸田みゆき
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      東京
    • Year and Date
      2012-03-17
    • Related Report
      2011 Final Research Report
  • [Presentation] Ce酸化物/Si(100)界面におけるCeの価数とCeシリケート2012

    • Author(s)
      幸田みゆき
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田、東京都
    • Year and Date
      2012-03-17
    • Related Report
      2011 Annual Research Report
  • [Presentation] ランタン酸化膜を用いたhigh-k/Si直接接合2012

    • Author(s)
      角嶋邦之
    • Organizer
      ゲートスタック研究会-材料・プロセス・評価の物理-
    • Place of Presentation
      静岡
    • Year and Date
      2012-01-20
    • Related Report
      2011 Final Research Report
  • [Presentation] ランタン酸化膜を用いたhigh-k/Si直接接合2012

    • Author(s)
      角嶋邦之
    • Organizer
      ゲートスタック研究会-材料・プロセス・評価の物理-
    • Place of Presentation
      三島、静岡県
    • Year and Date
      2012-01-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Metal insertedpoly-Si with high temperature annealing for achieving EOT of 0. 62 nm in La-silicate MOSFET2011

    • Author(s)
      T. Kawanago, et al
    • Organizer
      European Solid-State Device Research Conference
    • Place of Presentation
      Helsinki
    • Year and Date
      2011-09-12
    • Related Report
      2011 Final Research Report
  • [Presentation] Metal inserted poly-Si with high temperature annealing for achieving EOT of 0.62nm in La-silicate MOSFET2011

    • Author(s)
      T.Kawanago
    • Organizer
      European Solid-State Device Research Conference (ESSDERC)
    • Place of Presentation
      Helsinki, Finland
    • Year and Date
      2011-09-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] W/Tm_2O_3/n-Si構造キャパシタの電気特性におけるTm_2O_3膜厚依存性2011

    • Author(s)
      常石佳奈, 他
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形
    • Year and Date
      2011-09-01
    • Related Report
      2011 Final Research Report
  • [Presentation] W/Tm2O3/n-Si構造キャパシタの電気特性におけるTm2O3膜厚依存性2011

    • Author(s)
      常石佳奈
    • Organizer
      第72回応用物理学会学術講演会
    • Place of Presentation
      山形、山形県
    • Year and Date
      2011-09-01
    • Related Report
      2011 Annual Research Report
  • [Presentation] Rare Earth Oxide Capping Effect on La_2O_3 Gate Dielectrics toward EOT of 0. 5 nm2011

    • Author(s)
      M. Kouda, et al
    • Organizer
      International Workshop on Dielectric Thin Films for Future Electron Devices : Science and Technology
    • Place of Presentation
      Tokyo
    • Year and Date
      2011-01-20
    • Related Report
      2011 Final Research Report
  • [Presentation] Rare Earth Oxide Capping Effect on La2O3 Gate Dielectrics toward EOT of 0.5nm2011

    • Author(s)
      M.Kouda
    • Organizer
      International Workshop on Dielectric Thin Films for Future Electron Devices : Science and Technology
    • Place of Presentation
      大岡山、目黒区、東京
    • Year and Date
      2011-01-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] Electrical Characteristics of Rare Earth (La, Ce, Pr and Tm) Oxides/Silicates Gate Dielectric2010

    • Author(s)
      Katsuya Matano
    • Organizer
      China Semiconductor Technology International Conference
    • Place of Presentation
      Shanghai, China
    • Related Report
      2009 Annual Research Report
  • [Presentation] Electrical Characteristics of La_2O_3 Gated MOS Capacitors with Different Wafer Orientation2009

    • Author(s)
      H. Nakayama, et al
    • Organizer
      216th ECS meeting
    • Place of Presentation
      Vienna
    • Year and Date
      2009-10-04
    • Related Report
      2011 Final Research Report
  • [Presentation] Electrical Characteristics of La2O3 Gated MOS Capacitors with Different Wafer Orientation2009

    • Author(s)
      Hiroto Nakayama
    • Organizer
      216th ECS Meeting
    • Place of Presentation
      Vienna, Austria
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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