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Fundamental research for reduction of pollutant emission of coal combustion for zero CO_2 emission

Research Project

Project/Area Number 21246035
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionTokyo Institute of Technology

Principal Investigator

OKAZAKI Ken  東京工業大学, 大学院・理工学研究科, 教授 (20124729)

Co-Investigator(Kenkyū-buntansha) FUSHINOBU Kazuyoshi  東京工業大学, 大学院・理工学研究科, 准教授 (50280996)
OKUMURA Yukihiko  舞鶴工業高等専門学校, 電子制御工学科, 教授 (80262971)
渡部 弘達  東京工業大学, 大学院・理工学研究科, 助教 (40551825)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥46,020,000 (Direct Cost: ¥35,400,000、Indirect Cost: ¥10,620,000)
Fiscal Year 2011: ¥8,970,000 (Direct Cost: ¥6,900,000、Indirect Cost: ¥2,070,000)
Fiscal Year 2010: ¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000)
Fiscal Year 2009: ¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Keywords二酸化炭素 / 低炭素 / 燃焼 / 石炭 / O_2/CO_2燃焼 / 化学反応
Research Abstract

We developed fundamental theory to achieve ultra-clean and high efficiency coal combustion for zero CO_2 emission(O_2/CO_2 coal combustion) simultaneously. The conditions are shown to use high CO_2 concentration, which is the feature in O_2/CO_2 coal combustion, for low-NO_x combustion. The lowest NO_x conversion ratio in O_2/CO_2 combustion is lower than it in air combustion by 40%. Moreover, it is shown that carbonate, which has a potential to affect ash deposition and gasification, is formed due to the mineral reaction with CO_2.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (45 results)

All 2012 2011 2010 2009 Other

All Journal Article (7 results) (of which Peer Reviewed: 3 results) Presentation (36 results) Remarks (2 results)

  • [Journal Article] Study on the N2O formation under low temperature condition in pulverized biomass combustion2012

    • Author(s)
      Yukihiko Okumura, Hirotatsu Watanabe, Ken Okazaki
    • Journal Title

      J. Thermal Science and Technology

      Volume: Vol.7 Pages: 75-89

    • NAID

      130003374772

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of CO_2 reactivity formation and reduction mechanisms in O_2/CO_2 combustion2012

    • Author(s)
      Hirotatsu Watanabe, Takashi Marumo, Ken Okazaki
    • Journal Title

      Energy & Fuels

      Volume: Vol.26 Pages: 938-951

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of CO_2 reactivity on NO_x formation and reduction mechanisms in O_2/CO_2 combustion2012

    • Author(s)
      Hirotatsu Watanabe, Takashi Marumo, Ken Okazaki
    • Journal Title

      Energy & Fuels

      Volume: 26 Issue: 2 Pages: 938-951

    • DOI

      10.1021/ef201702g

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Study on the N2O Formation under Low Temperature Condition in Pulverized Biomass Combustion2012

    • Author(s)
      Yukihiko OKUMURA, Hirotatsu WATANABE, Ken OKAZAKI
    • Journal Title

      Journal of Thermal Science and Technology

      Volume: 7 Issue: 1 Pages: 75-89

    • DOI

      10.1299/jtst.7.75

    • NAID

      130002068981

    • ISSN
      1880-5566
    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] NO_x formation and reduction mechanisms in staged O_2/CO_2 combustion2011

    • Author(s)
      Hirotatsu Watanabe, Jun-ichiro Yamamoto, Ken Okazaki
    • Journal Title

      Combustion and Flame

      Volume: Vol.158 Pages: 1255-1263

    • Related Report
      2011 Final Research Report
  • [Journal Article] 元素比による石炭の熱分解収率および熱分解生成物の予測2010

    • Author(s)
      奥村幸彦, 岡崎健
    • Journal Title

      日本エネルギー学会誌

      Volume: Vol.89 Pages: 364-372

    • NAID

      130004741168

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] NO_x formation and reduction mechanisms in staged O_2/CO_2 combustion2010

    • Author(s)
      Hirotatsu Watanabe, Jun-ichiro Yamamoto, Ken Okazaki
    • Journal Title

      Combustion and Flame

      Volume: (in press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Prediction of Pyrolysis Products and Yields from Brown to Semi-Anthracite Coals by Using Elemental Composition2012

    • Author(s)
      Yukihiko Okumura, Hirotatsu Watanabe, Ken Okazaki
    • Organizer
      Proceedings of the Eighth KSME-JSME Thermal and Fluids Engineering Conference
    • Place of Presentation
      Incheon
    • Year and Date
      2012-03-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Prediction of Pyrolysis Products and Yields from Brown to Semi-Anthracite Coals by Using Elemental Composition2012

    • Author(s)
      Yukihiko Okumura, Hirotatsu Watanabe, Ken Okazaki
    • Organizer
      The Eighth KSME-JSME Thermal and Fluids Engineering Conference
    • Place of Presentation
      Songdo Convensia center (Incheon, Korea)
    • Year and Date
      2012-03-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 石炭の揮発成分および揮発分収率の簡易予測方法-褐炭から半無煙炭まで-2011

    • Author(s)
      奥村幸彦,渡部弘達,岡崎健
    • Organizer
      第49回燃焼シンポジウム
    • Place of Presentation
      横浜
    • Year and Date
      2011-12-06
    • Related Report
      2011 Final Research Report
  • [Presentation] CO_2回収型燃焼における固体燃料の熱分解プロセスの解明2011

    • Author(s)
      渡部弘達,下村聖実,荒井郁也, Dejudom Kiatpanachart,岡崎健
    • Organizer
      第49回燃焼シンポジウム講演
    • Place of Presentation
      横浜
    • Year and Date
      2011-12-06
    • Related Report
      2011 Final Research Report
  • [Presentation] 石炭の揮発成分および揮発分収率の簡易予測方法-褐炭から半無煙炭まで-2011

    • Author(s)
      奥村幸彦, 渡部弘達, 岡崎健
    • Organizer
      第49回燃焼シンポジウム
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2011-12-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] CO_2回収型燃焼における固体燃料の熱分解プロセスの解明2011

    • Author(s)
      渡部弘達, 下村聖実, 荒井郁也, Dejudom Kiatpanachart, 岡崎健
    • Organizer
      第49回燃焼シンポジウム
    • Place of Presentation
      慶応義塾大学(横浜)
    • Year and Date
      2011-12-06
    • Related Report
      2011 Annual Research Report
  • [Presentation] エネルギーの基盤を支える燃焼プロセスとCO2削減2011

    • Author(s)
      渡部弘達
    • Organizer
      GCOEプログラム分子系高次構造体化学国際教育研究拠点シンポジウム2011(招待講演)
    • Place of Presentation
      仙台
    • Year and Date
      2011-11-19
    • Related Report
      2011 Final Research Report
  • [Presentation] エネルギーの基盤を支える燃焼プロセスとCO_2削減2011

    • Author(s)
      渡部弘達
    • Organizer
      GCOEプログラム分子系高次構造体化学国際教育研究拠点シンポジウム2011
    • Place of Presentation
      東北大学(仙台)(招待講演)
    • Year and Date
      2011-11-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 微粉炭燃焼におけるN_2O生成に及ぼすSlow Volatileの影響2011

    • Author(s)
      奥村幸彦,渡部弘達,岡崎健
    • Organizer
      第48回石炭科学会議
    • Place of Presentation
      新潟
    • Year and Date
      2011-10-25
    • Related Report
      2011 Final Research Report
  • [Presentation] 微粉炭燃焼におけるN_2O生成に及ぼすSlow Volatileの影響2011

    • Author(s)
      奥村幸彦, 渡部弘達, 岡崎健
    • Organizer
      第48回石炭科学会議
    • Place of Presentation
      朱鷺メッセ新潟コンベンションセンター(新潟)
    • Year and Date
      2011-10-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] The effect of CO_2reactivity on NO_x reduction in O_2/CO_2 combustion2011

    • Author(s)
      Hirotatsu Watanabe, Takashi Marumo, Jun-ichiro Yamamoto
    • Organizer
      2nd Oxy-fuel Combustion
    • Place of Presentation
      Queensland
    • Year and Date
      2011-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] The effect of CO_2 reactivity on NO_x reduction in O_2/CO_2 combustion2011

    • Author(s)
      Hirotatsu Watanabe, Takashi Marumo, Jun-ichiro Yamamoto
    • Organizer
      2nd Oxyfuel Combustion
    • Place of Presentation
      Capricorn Resort Yeppoon (Australia)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] O_2/CO_2石炭燃焼における窒素化合物生成メカニズムと極低NO_x化への応用2011

    • Author(s)
      荒井郁也, Dejudom Kiatpanachart,丸毛孝,渡部弘達,岡崎健
    • Organizer
      日本機械学会2011年次大会
    • Place of Presentation
      東京
    • Year and Date
      2011-09-13
    • Related Report
      2011 Final Research Report
  • [Presentation] O_2/CO_2石炭燃焼における窒素化合物生成メカニズムと極低NO_x化への応用2011

    • Author(s)
      荒井郁也, Dejudom Kiatpanachart, 丸毛孝, 渡部弘達, 岡崎健
    • Organizer
      日本機械学会2011年次大会
    • Place of Presentation
      東工大(東京)
    • Year and Date
      2011-09-11
    • Related Report
      2011 Annual Research Report
  • [Presentation] 燃料過濃条件下のO_2/CO_2石炭燃焼におけるCO_2の反応性の影響2011

    • Author(s)
      渡部弘達,丸毛孝,岡崎健
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      大阪
    • Year and Date
      2011-08-09
    • Related Report
      2011 Final Research Report
  • [Presentation] 燃料過濃条件下のO_2/CO_2石炭燃焼におけるCO_2の反応性の影響2011

    • Author(s)
      渡部弘達, 丸毛孝, 岡崎健
    • Organizer
      第20回日本エネルギー学会大会
    • Place of Presentation
      関西大学(大阪)
    • Year and Date
      2011-08-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] THE CHARACTERISTICS OF RECYCLED-NO REDUCTION IN O_2/CO_2 COAL COMBUSTION2011

    • Author(s)
      Takashi Marumo, Jun-ichiro Yamamoto, Hirotatsu Watanabe, Ken Okazaki
    • Organizer
      Proceedings of ASME/JSME 2011 8th Thermal Engineering Joint Conference
    • Place of Presentation
      Hawaii
    • Year and Date
      2011-03-15
    • Related Report
      2011 Final Research Report
  • [Presentation] NO REDUCTION MECHANISM PECULIAR TO O_2/CO_2 COAL COMBUSTION CHARACTERIZED BY HIGH CO_2 CONCENTRATION2011

    • Author(s)
      Hirotatsu Watanabe, Takashi Marumo, Jun-ichiro Yamamoto, Ken Okazaki
    • Organizer
      Proceedings of ASME/JSME 2011 8th Thermal Engineering Joint Conference
    • Place of Presentation
      Hawaii
    • Year and Date
      2011-03-15
    • Related Report
      2011 Final Research Report
  • [Presentation] EFFECTS OF HETEROGENEOUS REACTION AND SLOW/RAPID VOLATILIZATION PROCESS ON N2O FORMATION DURING THE COMBUSTION OF PULVERIZED BIOMASS2011

    • Author(s)
      Yukihiko OKUMURA, Hirotatsu WATANABE, Ken OKAZAKI
    • Organizer
      Proceedings of ASME/JSME 2011 8th Thermal Engineering Joint Conference
    • Place of Presentation
      Hawaii
    • Year and Date
      2011-03-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 石炭酸素燃焼における再循環NO_xの還元メカニズムの解明2010

    • Author(s)
      丸毛孝,山本潤一郎,渡部弘達,岡崎健
    • Organizer
      第48回燃焼シンポジウム
    • Place of Presentation
      福岡
    • Year and Date
      2010-12-03
    • Related Report
      2011 Final Research Report
  • [Presentation] 石炭酵素燃焼における再循環NO_xの還元メカニズムの解明2010

    • Author(s)
      丸毛孝, 山本潤一郎, 渡部弘達, 岡崎健
    • Organizer
      第48回燃焼シンポジウム
    • Place of Presentation
      福岡ガーデンパレス(福岡市)
    • Year and Date
      2010-12-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] バイオマス低温燃焼場におけるN_2O生成に及ぼす揮発分放出速度の影響2010

    • Author(s)
      奥村幸彦,渡部弘達,岡崎健
    • Organizer
      第48回燃焼シンポジウム
    • Place of Presentation
      福岡
    • Year and Date
      2010-12-02
    • Related Report
      2011 Final Research Report
  • [Presentation] バイオマス低温燃焼場におけるN_2O生成に及ぼす揮発分放出速度の影響2010

    • Author(s)
      奥村幸彦, 渡部弘達, 岡崎健
    • Organizer
      第48回燃焼シンポジウム
    • Place of Presentation
      福岡ガーデンパレス(福岡市)
    • Year and Date
      2010-12-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 石炭酸素燃焼におけるNO_x生成および還元メカニズムの解明2010

    • Author(s)
      渡部弘達, 山本潤一郎, 丸毛孝, 岡崎健
    • Organizer
      第47回石炭科学会議
    • Place of Presentation
      長良川国際会議場(岐阜県)
    • Year and Date
      2010-09-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] 石炭酸素燃焼におけるNO_x生成および還元メカニズムの解明2010

    • Author(s)
      渡部弘達,山本潤一郎,丸毛孝,岡崎健
    • Organizer
      第47回石炭科学会議
    • Place of Presentation
      岐阜
    • Year and Date
      2010-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] 石炭酸素燃焼と空気燃焼における二段燃焼によるNOx低減効果の比較2010

    • Author(s)
      渡部弘達,山本潤一郎,岡崎健
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      京都
    • Year and Date
      2010-09-08
    • Related Report
      2011 Final Research Report
  • [Presentation] 石炭酵素燃焼と空気燃焼における二段燃焼によるNO_x低減効果の比較2010

    • Author(s)
      渡部弘達, 山本潤一郎, 岡崎健
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学(京都府)
    • Year and Date
      2010-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] バイオマス低温燃焼における亜酸化窒素の生成特性2010

    • Author(s)
      奥村幸彦, 岡崎健
    • Organizer
      第19回日本エネルギー学会大会
    • Place of Presentation
      工学院大学(東京都)
    • Year and Date
      2010-08-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] バイオマス低温燃焼における亜酸化窒素の生成特性2010

    • Author(s)
      奥村幸彦,岡崎健
    • Organizer
      第19回日本エネルギー学会大会
    • Place of Presentation
      東京
    • Year and Date
      2010-08-02
    • Related Report
      2011 Final Research Report
  • [Presentation] 石炭酸素燃焼におけるNO_x生成に及ぼすCO_2濃度の影響2010

    • Author(s)
      丸毛孝,山本潤一郎,渡部弘達,岡崎健
    • Organizer
      第47回日本伝熱シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2010-05-26
    • Related Report
      2011 Final Research Report
  • [Presentation] 石炭酵素燃焼におけるNO_x生成に及ぼすCO_2濃度の影響2010

    • Author(s)
      丸毛孝, 山本潤一郎, 渡部弘達, 岡崎健
    • Organizer
      第47回日本伝熱シンポジウム
    • Place of Presentation
      札幌コンベンションセンター「SORA」(北海道)
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 石炭酸素燃焼の循環ガス混合過程におけるNO_x低減効果2010

    • Author(s)
      山本潤一郎,丸毛孝,渡部弘達,岡崎健
    • Organizer
      化学工学会第75年会
    • Place of Presentation
      鹿児島
    • Year and Date
      2010-03-18
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] EFFECTS OF HETEROGENEOUS REACTION AND SLOW/RAPID VOLATILIZATION PROCESS ON N_2O FORMATION DURING THE COMBUSTION OF PULVERIZED BIOMASS2010

    • Author(s)
      Yukihiko OKUMURA, Hirotatsu WATANABE, Ken OKAZAKI
    • Organizer
      ASME/JSME 2011 8th thermal Engineering Joint Conference
    • Place of Presentation
      Waikiki Beach Marriott Resort & Spa (Honolulu, Hawaii)
    • Year and Date
      2010-03-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] NO REDUCTION MECHANISM PECULIAR TO O2/CO2 COAL COMBUSTION CHARACTERIZED BY HIGH CO2 CONCENTRATION2010

    • Author(s)
      Hirotatsu Watanabe, Takashi Marumo, Jun-ichiro Yamamoto, Ken Okazaki
    • Organizer
      ASME/JSME 2011 8th thermal Engineering Joint Conference
    • Place of Presentation
      Waikiki Beach Marriott Resort & Spa (Honolulu, Hawaii)
    • Year and Date
      2010-03-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] THE CHARACTERISTICS OF RECYCLED-NO REDUCTION IN O2/CO2 COAL COMBUSTION2010

    • Author(s)
      Takashi Marumo, Jun-ichiro Yamamoto, Hirotatsu Watanabe, Ken Okazaki
    • Organizer
      ASME/JSME 2011 8th Thermal Engineering Joint Conference
    • Place of Presentation
      Waikiki Beach Marriott Resort & Spa (Honolulu, Hawaii)
    • Year and Date
      2010-03-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] 石炭酸素燃焼における炉内局所条件制御による極低NO_x化の検討2009

    • Author(s)
      山本潤一郎,丸毛孝,渡部弘達,岡崎健
    • Organizer
      第47回燃焼シンポジウム
    • Place of Presentation
      札幌
    • Year and Date
      2009-12-04
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.mech.titech.ac.jp/~epl

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.mech.titech.ac.jp/~epl/research/coal.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2020-12-23  

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