Development of electrode functions by controlling interface structure
Project/Area Number |
21350115
|
Research Category |
Grant-in-Aid for Scientific Research (B)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic industrial materials
|
Research Institution | Mie University |
Principal Investigator |
|
Co-Investigator(Kenkyū-buntansha) |
HIRANO Atsushi 三重大学, 大学院・工学研究科, 助教 (60324547)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥18,720,000 (Direct Cost: ¥14,400,000、Indirect Cost: ¥4,320,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2010: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2009: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
|
Keywords | 固体電解質 / インターカレーション / 界面 / リチウム電池 / 全固体電池 / 界面抵抗 / 活性化エネルギー / 相互拡散 / 電位窓 / ガーネット / NASICON / リチウムイオン電池 / 電荷移動抵抗 / Pulsed Laser Deposition / 電気二重層 / キャパシタンス / 頻度因子 |
Research Abstract |
Electrode/solid electrolyte interfaces were studied for development of all solid-state batteries. The resistance was discussed about its correlation to ion diffusion formula in some active materials. The appropriate technique was investigated to estimate lithium ion diffusion coefficient, and potential-step was the method to give the most reasonable result. As a result, the interfacial resistance decreased in the order of electrode with one, two, three dimensional diffusion pathways. It is concluded that three dimensional diffusion is most effective to reduce the interfacial resistance.
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Report
(4 results)
Research Products
(55 results)