Development of thin films of layered double hydroxides with electron-, ion-and photo-functions

• Project/Area Number: 21350118
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Osaka Prefecture University
• Principal Investigator: TADANAGA Kiyoharu 大阪府立大学, 大学院・工学研究科, 准教授 (90244657)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥18,070,000 (Direct Cost: ¥13,900,000、Indirect Cost: ¥4,170,000); Fiscal Year 2011: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000); Fiscal Year 2010: ¥7,930,000 (Direct Cost: ¥6,100,000、Indirect Cost: ¥1,830,000); Fiscal Year 2009: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
• Keywords: ゾル-ゲル法 / 温水処理 / 層状複水酸化物 / 陰イオン交換体 / 薄膜 / イオン伝導性 / 蛍光 / 光触媒活性 / 炭酸イオン / 電極材料 / ゾルーゲル法

Research Abstract

Thin films of layered double hydroxide(LDH) intercalated with various anions were prepared by immersing sol-gel derived precursor thin films. Organic dyes with sulfo groups were found to be easily intercalated in LDH nanocrystals in this process. Orientation of the nanocrystals on the surface can be controllable with the kind of organic molecules. Mg-Al and Ni-Al LDHs were found to show high hydroxide ion conductivity.

Research Products

• [Journal Article] Effect of Mg/Al ratio on hydroxide ion conductivity for Mg-Al layered double hydroxide and application to direct ethanol fuel cells (2012)
  • Author(s): K. Tadanaga, Y. Furukawa, A. Hayashi and M. Tatsumisago
  • Journal Title: J. Electrochem. Soc. Volume: 159
  • Peer Reviewed
• [Journal Article] Preparation of Co-Al and Ni-Al layered double hydroxide thin films by a sol-gel process with hot water treatment (2012)
  • Author(s): K. Tadanaga, A. Miyata, N. Yamaguchi, D. Ando, and M. Tatsumisago
  • Journal Title: J. Sol-Gel Sci. Tech. Volume: 62 Pages: 111-116
  • Peer Reviewed
• [Journal Article] Hydroxide ion conduction in Ni-Al layered double hydroxide (2012)
  • Author(s): D. Kubo, K. Tadanaga, A. Hayashi, and M. Tatsumisago
  • Journal Title: J. Electroanal. Chem. Volume: 671 Pages: 102-106
  • Peer Reviewed
• [Journal Article] Effect of Mg/Al ratio on hydroxide ion conductivity for Mg-Al layered double hydroxide and application to direct ethanol fuel cells (2012)
  • Author(s): K.Tadanaga
  • Journal Title: Journal of the Electrochemical Society Volume: 159 Issue: 4 Pages: B368-B370
  • DOI: 10.1149/2.007204jes
  • Peer Reviewed
• [Journal Article] Preparation of Co-Al and Ni-Al layered double hydroxide thin films by a sol-gel process with hot water treatment (2012)
  • Author(s): K.Tadanaga
  • Journal Title: Journal of Sol-Gel Science and Technology Volume: 62 Issue: 1 Pages: 111-116
  • DOI: 10.1007/s10971-012-2692-z
  • Peer Reviewed
• [Journal Article] Hydroxide ion conduction in Ni-Al layered double hydroxide (2012)
  • Author(s): D.Kubo
  • Journal Title: Journal of Electroanalytical Chemistry Volume: 671 Pages: 102-105
  • DOI: 10.1016/j.jelechem.2012.02.007
  • Peer Reviewed
• [Journal Article] Evaluation of ionic conductivity for Mg. Al layered double hydroxide intercalated with inorganic anions (2011)
  • Author(s): Y. Furukawa, K. Tadanaga, A. Hayashi, and M. Tatsumisago
  • Journal Title: Solid State Ionics Volume: 192 Pages: 185-187
  • Peer Reviewed
• [Journal Article] 水酸化物イオン伝導性無機固体材料の創製 (2011)
  • Author(s): 忠永清治、辰巳砂昌弘
  • Journal Title: Electrochemistry Volume: 79 Pages: 630-633
  • NAID: 10029341839
• [Journal Article] Evaluation of ionic conductivity for Mg-Al layered double hydroxide intercalated with inorganic anions (2011)
  • Author(s): Y.Furukawa
  • Journal Title: Solid State Ionics
  • Peer Reviewed
• [Journal Article] Direct Ethanol Fuel Cell Using Hydrotalcite Clay as a Hydroxide Ion Conductive Electrolyte (2010)
  • Author(s): K. Tadanaga, Y. Furukawa, A. Hayashi, and M. Tatsumisago
  • Journal Title: Adv. Mater. Volume: 22 Pages: 4401-4404
  • Peer Reviewed
• [Journal Article] Direct Ethanol Fuel Cell Using Hydrotalcite Clay as a Hydroxide Ion Conductive Electrolyte (2010)
  • Author(s): K.Tadanaga
  • Journal Title: Advanced Materials Volume: 22 Pages: 4401-4404
  • Peer Reviewed
• [Journal Article] Formation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Sulfonated Spiropyran (2009)
  • Author(s): K. Tadanaga, N. Yamaguchi, and M. Tatsumisago
  • Journal Title: Res. Chem. Intermed. Volume: 35 Pages: 949-956
  • Peer Reviewed
• [Journal Article] 温水処理を伴うゾル-ゲル法による機能性薄膜の合成 (2009)
  • Author(s): 忠永清治
  • Journal Title: セラミックス Volume: 44 Pages: 613-615
  • NAID: 10026239861
• [Journal Article] Formation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Sulfonated Spiropyran (2009)
  • Author(s): K.Tadanaga
  • Journal Title: Res.Chem.Intermed 35 Pages: 949-956
  • Peer Reviewed
• [Journal Article] 温水処理を伴うゾルーゲル法による機能性薄膜の合成 (2009)
  • Author(s): 忠永清治
  • Journal Title: セラミックス 44[8] Pages: 613-615
  • NAID: 10026239861
• [Presentation] Preparation of materials for all-solid-state electrochemical devices by solution processes (2012)
  • Author(s): 忠永清治
  • Organizer: The 1st Japan-Italy Workshop on Sol-Gel for Advanced Functional Materials
  • Place of Presentation: 大阪府立大学中之島サテライト(Invited lecture)
  • Year and Date: 2012-02-09
• [Presentation] 水酸化物イオン伝導性を有する層状複水酸化物とMnO_2からなる金属-空気二次電池用空気極の作製と評価 (2012)
  • Author(s): 窪大樹、忠永清治、林晃敏、辰巳砂昌弘
  • Organizer: 電気化学会第79回大会
  • Place of Presentation: 浜松
• [Presentation] 様々なアニオンを層間に含むZn-Cr系層状複水酸化物の作製と光触媒活性 (2012)
  • Author(s): 忠永清治、平田直也、辰巳砂昌弘
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応大学
• [Presentation] 水酸化物イオン伝導性を有する層状複水酸化物とMnO_2からなる金属-空気二次電池用空気極の作製と評価 (2012)
  • Author(s): 窪大樹
  • Organizer: 電気化学会第79回大会
  • Place of Presentation: アクトシティ浜松
• [Presentation] Ni-Al系層状複水酸化物の水酸化物イオン伝導性と固体アルカリ形燃料電池への応用 (2011)
  • Author(s): 忠永清治、窪大樹、林晃敏、辰巳砂昌弘
  • Organizer: 電気化学会第78回大会
  • Place of Presentation: 講演要旨集
  • Year and Date: 2011-03-29
• [Presentation] Ni-Al系層状複水酸化物の水酸化物イオン伝導性の評価 (2011)
  • Author(s): 忠永清治、窪大樹、林晃敏、辰巳砂昌弘
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 講演要旨集
  • Year and Date: 2011-03-11
• [Presentation] スルホローダミンBを含むZn-Al系層状複水酸化物薄膜の作製と発光特性 (2011)
  • Author(s): 末澤諒也、忠永清治、辰巳砂昌弘
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 講演要旨集
  • Year and Date: 2011-03-11
• [Presentation] Preparation of materials for all-solid-state electrochemical devices by solution processes(Invited lecture) (2011)
  • Author(s): K. Tadanaga
  • Organizer: The 1st Japan-Italy Workshop on Sol-Gel for Advanced Functional Materials
  • Place of Presentation: 大阪
  • Year and Date: 2011-02-09
• [Presentation] Ni-Al系層状複水酸化物のイオン伝導性評価とアルカリ形燃料電池への応用 (2011)
  • Author(s): 窪大樹、忠永清治、林晃敏、辰巳砂昌弘
  • Organizer: 第37回固体イオニクス討論会
  • Place of Presentation: 鳥取
• [Presentation] フルオレセインと界面活性剤が挿入されたZn-Al系層状複水酸化物薄膜の作製 (2011)
  • Author(s): 末澤諒也、忠永清治、辰巳砂昌弘
  • Organizer: 第52回ガラスおよびフォトニクス材料討論会
  • Place of Presentation: 姫路
• [Presentation] Ni-Al系層状複水酸化物を用いた全固体アルカリ形燃料電池 (2011)
  • Author(s): 窪大樹、忠永清治、林晃敏、辰巳砂昌弘
  • Organizer: 第52回電池討論会
  • Place of Presentation: 東京
• [Presentation] 温水処理による層状複水酸化物微結晶の析出における配向制御 (2011)
  • Author(s): 忠永清治
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
• [Presentation] Hydroxide Ion Conductivity of Ni-Al Layered Double Hydroxides for Alkaline Fuel Cell (2011)
  • Author(s): D. Kubo, K. Tadanaga, A. Hayashi and M. Tatsumisago
  • Organizer: The 62nd Annual Meeting of the International Society of Electrochemistry
  • Place of Presentation: 新潟国際会議場
• [Presentation] ケミカルプロセスによる全固体電気化学デバイス用材料の合成 (2011)
  • Author(s): 忠永清治、林晃敏、辰巳砂昌弘
  • Organizer: 日本セラミックス協会第24回秋季シンポジウム
  • Place of Presentation: 北海道大学
• [Presentation] Preparation and Fluorescent Properties of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Sulforhodamine B (2011)
  • Author(s): R. Suezawa, K. Tadanaga, M. Tatsumisago
  • Organizer: The 16^<th> International Sol-Gel Conference
  • Place of Presentation: Hangzhou, China
• [Presentation] スルホローダミンBが挿入されたZn-Al系層状複水酸化物薄膜の作製と蛍光特性 (2011)
  • Author(s): 末澤諒也、忠永清治、辰巳砂昌弘
  • Organizer: 日本ゾル-ゲル学会第9回討論会
  • Place of Presentation: 関西大学
• [Presentation] アルカリ形燃料電池への応用にむけたNi-Al系層状複水酸化物の作製と評価 (2011)
  • Author(s): 窪大樹、忠永清治、林晃敏、辰巳砂昌弘
  • Organizer: 第13回化学電池材料ミーティング
  • Place of Presentation: 日本化学会会館
• [Presentation] アルカリ形燃料電池への応用にむけたNi-Al系層状複水酸化物の作製と評価 (2011)
  • Author(s): 窪大樹
  • Organizer: 第13回化学電池材料研究会ミーティング
  • Place of Presentation: 日本化学会会館
• [Presentation] スルホローダミンBが挿入されたZn-Al系層状複水酸化物薄膜の作製と蛍光特性 (2011)
  • Author(s): 末澤諒也
  • Organizer: 日本ゾルーゲル学会第9回討論会
  • Place of Presentation: 関西大学
• [Presentation] 微細な凹凸構造を有するアルミナ膜上へのシリカ系薄膜の形成と評価 (2011)
  • Author(s): 森圭介
  • Organizer: 日本ゾルーゲル学会第9回討論会
  • Place of Presentation: 関西大学
• [Presentation] Preparation and Fluorescent Properties of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Sulforhodamine B (2011)
  • Author(s): 末澤諒也
  • Organizer: The 16th International Sol-Gel Conference
  • Place of Presentation: Hangzhou, China
• [Presentation] ケミカルプロセスによる全固体電気化学デバイス用材料の合成 (2011)
  • Author(s): 忠永清治
  • Organizer: 日本セラミックス協会第24回秋季シンポジウム
  • Place of Presentation: 北海道大学(依頼講演)
• [Presentation] 温水処理による層状複水酸化物微結晶の析出における配向制御 (2011)
  • Author(s): 忠永清治
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学(依頼講演)
• [Presentation] Ni-Al系層状複水酸化物を用いた全固体アルカリ形燃料電池 (2011)
  • Author(s): 窪大樹
  • Organizer: 第52回電池討論会
  • Place of Presentation: 東京都・船堀タワーホール
• [Presentation] フルオレセインと界面活性剤が挿入されたZn-Al系層状複水酸化物薄膜の作製 (2011)
  • Author(s): 末澤諒也
  • Organizer: 第52回ガラスおよびフォトニクス材料討論会
  • Place of Presentation: 姫路市・イーグレ姫路
• [Presentation] Ni-Al系層状複水酸化物のイオン伝導性評価とアルカリ形燃料電池への応用 (2011)
  • Author(s): 窪大樹
  • Organizer: 第37回固体イオニクス討論会
  • Place of Presentation: 鳥取・白兎会館
• [Presentation] 温水処理を伴うゾル-ゲル法によるピラニンを含むZn-Al系層状複水酸化物薄膜の作製 (2010)
  • Author(s): 忠永清治
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学(大阪府)
  • Year and Date: 2010-03-26
• [Presentation] Novel Inorganic Materials for Polymer Electrolyte and Alkaline Fuel Cells(招待講演) (2010)
  • Author(s): K. Tadanaga
  • Organizer: 2nd ASEAN-APCTP Workshop on Advanced Materials Science and Nanotechnology
  • Place of Presentation: Penang, Malaysia
• [Presentation] Preparation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Anionic Dyes Having Sulfonic Groups through the Sol-Gel Process with Hot Water Treatment (2010)
  • Author(s): K. Tadanaga, R. Suezawa, T. Tamura, M. Tatsumisago
  • Organizer: 3rd International Congress on Ceramics
  • Place of Presentation: 大阪
• [Presentation] Preparation of Layered Double Hydroxide Nano-Crystals Precipitated Coatings by the Sol-Gel Method with Hot Water Treatment (2010)
  • Author(s): K. Tadanaga, N. Yamaguchi, T. Tamura, R. Suezawa, M. Tatsumisago
  • Organizer: XXII International Congress on Glass
  • Place of Presentation: Bahia, Brazil
• [Presentation] Zn-Al系層状複水酸化物のイオン伝導性の評価 (2010)
  • Author(s): 忠永清治、古川佳宏、林晃敏、辰巳砂昌弘
  • Organizer: 2010年電気化学秋季大会
  • Place of Presentation: 神奈川工科大学
• [Presentation] Ionic Conduction in Mg-Al and Zn-Al Layered Double Hydroxide Intercalated with Inorganic Anions (2010)
  • Author(s): K. Tadanaga, Y. Furukawa, A. Hayashi and M. Tatsumisago
  • Organizer: The 15th International Conference on Solid State Protonic Conductors
  • Place of Presentation: California, USA
• [Presentation] 温水処理によるピラニンがインターカレーションされたZn-Al系層状複水酸化物薄膜の作製 (2010)
  • Author(s): 末澤諒也、忠永清治、辰巳砂昌弘
  • Organizer: 日本ゾル-ゲル学会第8回討論会
  • Place of Presentation: 名古屋大学
• [Presentation] Preparation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Pyranine via Sol-Gel Process with Hot Water Treatment (2010)
  • Author(s): R. Suezawa, K. Tadanaga, M. Tatsumisago
  • Organizer: 2nd Japan-Korea Joint Forum on Sol-Gel Science and Technology
  • Place of Presentation: 大阪
• [Presentation] Preparation of Nano-Structured Oxide Thin Films by the Sol-Gel Method with Hot Water Treatment(招待講演) (2010)
  • Author(s): K. Tadanaga
  • Organizer: 2nd Japan-Korea Joint Forum on Sol-Gel Science and Technology
  • Place of Presentation: 大阪
• [Presentation] 温水処理を伴うゾル-ゲル法によるピラニンを含むZn-Al系層状複水酸化物薄膜の作製 (2010)
  • Author(s): 忠永清治、末澤諒也、辰巳砂昌弘
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
• [Presentation] Preparation of Nano-Structured Oxide Thin Films by the Sol-Gel Method with Hot Water Treatment (2010)
  • Author(s): K.Tadanaga
  • Organizer: 2nd Japan-Korea Joint Forum on Sol-Gel Science and Technology
  • Place of Presentation: 大阪府 大阪府大学(招待講演)
• [Presentation] Preparation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Pyranine via Sol-Gel Process with Hot Water Treatment (2010)
  • Author(s): R.Suezawa
  • Organizer: 2nd Japan-Korea Joint Forum on Sol-Gel Science and Technology
  • Place of Presentation: 大阪府 大阪府大学
• [Presentation] 温水処理によるピラニンがインターカレーションされたZn-Al系層状複水酸化物薄膜の作製 (2010)
  • Author(s): 末澤諒也
  • Organizer: 日本ゾルーゲル学会第8回討論会
  • Place of Presentation: 愛知県 名古屋大学
• [Presentation] Ionic Conduction in Mg-Al and Zn-Al Layered Double Hydroxide Intercalated with Inorganic Anions (2010)
  • Author(s): K.Tadanaga
  • Organizer: The 15th International Conference on Solid State Protonic Conductors
  • Place of Presentation: Santa Barbara, USA
• [Presentation] Zn-Al系層状複水酸化物のイオン伝導性の評価 (2010)
  • Author(s): 忠永清治
  • Organizer: 2010年電気化学秋季大会
  • Place of Presentation: 神奈川県 神奈川工科大学
• [Presentation] Preparation of Zn-Al Layered Double Hydroxide Thin Films Intercalated with Anionic Dyes Having Sulfonic Groups through the Sol-Gel Process with Hot Water Treatment (2010)
  • Author(s): K.Tadanaga
  • Organizer: 3rd International Congress on Ceramics
  • Place of Presentation: 大阪府 大阪国際会議場
• [Presentation] Novel Inorganic Materials for Polymer Electrolyte and Alkaline Fuel Cells (2010)
  • Author(s): K.Tadanaga
  • Organizer: 2nd ASEAN-APCTP Workshop on Advanced Materials Science and Nanotechnology
  • Place of Presentation: Penang, Malaysia(招待講演)
• [Presentation] Mg-Al系層状複水酸化物を電解質に用いたアルカリ形燃料電池 (2009)
  • Author(s): 古川佳宏
  • Organizer: 第50回電池討論会
  • Place of Presentation: 京都国際会議場(京都府)
  • Year and Date: 2009-11-30
• [Presentation] 水溶液からのBaTiO_3の合成におけるPVA添加の効果 (2009)
  • Author(s): 鈴木祥平
  • Organizer: 日本セラミックス協会第22回秋季シンポジウム
  • Place of Presentation: 愛媛大学(愛媛県)
  • Year and Date: 2009-09-17
• [Presentation] Mg-Al系層状複水酸化物のイオン伝導性と水素-酸素燃料電池への応用 (2009)
  • Author(s): 古川佳宏
  • Organizer: 2009年電気化学会秋季大会
  • Place of Presentation: 東京農工大学(東京都)
  • Year and Date: 2009-09-11
• [Presentation] Preparation of Layered Double Hydroxide Thin Films by Hot Water Treatment (2009)
  • Author(s): K.Tadanaga
  • Organizer: The 4th KIFEE Symposium on Environment, Energy, Materials and Education
  • Place of Presentation: ノルウェー科学技術大学(ノルウェー)
  • Year and Date: 2009-09-08
• [Presentation] Mg-Al系層状複水酸化物を電解質に用いたアルカリ形燃料電池 (2009)
  • Author(s): 古川佳宏、忠永清治、林晃敏、辰巳砂昌弘
  • Organizer: 第50回電池討論会
  • Place of Presentation: 京都
• [Presentation] Mg-Al系層状複水酸化物のイオン伝導性と水素-酸素燃料電池への応用 (2009)
  • Author(s): 古川佳宏、忠永清治、林晃敏、辰巳砂昌弘
  • Organizer: 2009年電気化学会秋季大会
  • Place of Presentation: 東京農工大
• [Presentation] Preparation of Layered Double Hydroxide Thin Films by Hot Water Treatment (2009)
  • Author(s): K. Tadanaga
  • Organizer: The 4th KIFEE Symposium on Environment, Energy, Materials and Education
  • Place of Presentation: Trondheim, Norway
• [Patent(Industrial Property Rights)] 金属-空気二次電池用空気極触媒層 (2012)
  • Inventor(s): 忠永清治、林晃敏、辰巳砂昌弘
  • Industrial Property Rights Holder: 大阪府立大学
  • Filing Date: 2012-03-26
• [Patent(Industrial Property Rights)] 金属-空気二次電池用空気極触媒層 (2012)
  • Inventor(s): 忠永清治, 他
  • Industrial Property Rights Holder: 大阪府立大学
  • Industrial Property Number: 2012-069432
  • Filing Date: 2012-03-26