Research on development and applications of new supramolecular gelators

• Project/Area Number: 21350122
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Shinshu University
• Principal Investigator: HANABUSA Kenji 信州大学, 総合工学系研究科, 教授 (60126696)
• Co-Investigator(Kenkyū-buntansha): SUZUKI Masahiro 信州大学, 大学院・総合工学系研究科, 准教授 (30334915)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000); Fiscal Year 2011: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000); Fiscal Year 2010: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000); Fiscal Year 2009: ¥10,010,000 (Direct Cost: ¥7,700,000、Indirect Cost: ¥2,310,000)
• Keywords: ゲル / ゲル化剤 / 物理ゲル / 超分子 / 水素結合

Research Abstract

New thickeners and gelators were developed from 5-aminoisophtalic acid which was a cheap industrial intermediate. The properties as thickeners and gelators were drastically affected by the kinds of alkyl amines which were introduced to carboxylic groups in 5-aminoisophtalic acid. New polymer type of gelators were developed by using cheap commercially available polycaprolactones. New hydrogelators were developed on the basis of a cyclic dipeptide prepared from artificial sweetener" Aspartame^(R)". New gelators based on the cyclic dipeptide containing functional segments were developed.

Research Products

• [Journal Article] Cyclo (L-aspartyl-L-phenylalanyl)-containing Poiy (dimethylsiloxane)-based Thixotropic Organogels (2011)
  • Author(s): Hiroko Hoshizawa, Masahiro Suzuki, Kenji Hanabusa
  • Journal Title: Chemistry Letters Volume: 40 Issue: 10 Pages: 1143-1145
  • DOI: 10.1246/cl.2011.1143
  • NAID: 130004426058
  • Peer Reviewed
• [Journal Article] ポリジメチルシロキサンを導入した環状ジペプチド誘導体を基盤とするオルガノゲル化剤の開発 (2011)
  • Author(s): 星沢裕子、鈴木正浩、英謙二
  • Journal Title: 高分子論文集 Volume: 68 Pages: 749-758
  • NAID: 10030170001
  • URL: http://www.spsj.or.jp/c5/koron/koron.htm
• [Journal Article] Cyclo(L-aspartyl-L-phenylalanyl)-containing Poly(dimethylsiloxane)-based Thixotropic Organogels (2011)
  • Author(s): Hoshizawa Hiroko; Suzuki Masahiro; Hanabusa Kenji
  • Journal Title: CHEMISTRY LETTERS Volume: 40 Pages: 1143-1145
  • NAID: 10029683376
  • Peer Reviewed
• [Journal Article] Development of Cyclo (dipeptide)-Based Organogelators Containing Poly (dimethylsiloxane) (2011)
  • Author(s): Hoshizawa Hiroko; Suzuki Masahiro; Hanabusa Kenji
  • Journal Title: KOBUNSHI RONBUNSHU Volume: 68 Pages: 749-758
  • NAID: 10030170001
  • Peer Reviewed
• [Journal Article] Polymer organogelators that make supramolecular organogels through physical cross-linking and self-assembly (2010)
  • Author(s): M. Suzuki and K. Hanabusa
  • Journal Title: Chem. Soc. Rev. Volume: 39 Issue: 2 Pages: 455-463
  • DOI: 10.1039/b910604a
• [Journal Article] Low-molecular-weight gelators based on N^α-acetyl-N^ε-dodecyl-L-lysine and their amphiphilic gelation properties (2010)
  • Author(s): M. Suzuki T. Abe, K. Hanabusa
  • Journal Title: J. Colloid Interface Sci. Volume: 341 Issue: 1 Pages: 69-74
  • DOI: 10.1016/j.jcis.2009.09.010
• [Journal Article] Polymer organogelators that make supramolecular organogels through physical cross-1inking and self-assembly (2010)
  • Author(s): M.Suzuki, K.Hanabusa
  • Journal Title: Chem.Soc.Rev. Volume: 39 Pages: 5067-5067
  • Peer Reviewed
• [Journal Article] 低分子ゲル化剤による溶媒のゲル化 (2010)
  • Author(s): 英謙二
  • Journal Title: 化学工学 Volume: 74 Pages: 341-343
  • Peer Reviewed
• [Journal Article] 新しい増粘剤およびゲル化剤の開発 (2010)
  • Author(s): 英謙二、星沢裕子
  • Journal Title: ネットワークポリマー Volume: 31 Pages: 308-316
  • NAID: 130004648243
  • Peer Reviewed
• [Journal Article] L-Lysine-based low-molecular-weight gelators (2009)
  • Author(s): M. Suzuki and K. Hanabusa
  • Journal Title: Chem. Soc. Rev Volume: 38 Issue: 4 Pages: 967-975
  • DOI: 10.1039/b816192e
• [Journal Article] Two-component organogelators based on two L-amino acids : effect of combination of L-lysine with various L-amino acids on organogelation behavior (2009)
  • Author(s): Masahiro Suzuki, Hiroaki Saito, Kenji Hanabusa
  • Journal Title: Langmuir Volume: 25 Issue: 15 Pages: 8579-8585
  • DOI: 10.1021/la8040924
• [Journal Article] Two-component organogelators based on two L-amino acids : effect of combination of L-lysine with various L-amino acids on organogelation behavior (2009)
  • Author(s): Masahiro Suzuki, Hiroaki Saito, Kenji Hanabusa
  • Journal Title: Langmuir 25 Pages: 8579-8585
  • Peer Reviewed
• [Journal Article] L-Lysine-based low-molecular-weight gelators (2009)
  • Author(s): Masahiro Suzuki, Kenji Hanabusa
  • Journal Title: Chem.Soc.Rev 38 Pages: 967-975
  • Peer Reviewed
• [Journal Article] Fabrication of Helical Mesoporous Silica Nanostructures Using Gelators and the Mixtures with CTAC (2009)
  • Author(s): Hiroko Hoshizawa, Masahiro Suzuki, Hirofusa, Shirai, Kenji Hanabusa, Yonggang Yang
  • Journal Title: 繊維学会誌 65 Pages: 80-87
  • NAID: 10024770270
  • Peer Reviewed
• [Journal Article] 低分子ゲル化駆動セグメントを導入したポリマー型ゲル化済の開発 (2009)
  • Author(s): 星沢裕子・小河睦・鈴木正浩・白井汪芳・英謙二・永井直・中井一宙
  • Journal Title: 繊維学会誌 65 Pages: 103-109
  • Peer Reviewed
• [Journal Article] ゲル化を惹き起こすゲル化済と増粘化を発現する増粘済 (2009)
  • Author(s): 英謙二、鈴木正浩
  • Journal Title: 繊維と工業 65 Pages: 159-165
• [Presentation] ゲル化剤の開発と応用に関する研究 (2011)
  • Author(s): 英謙二
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学(招待講演)
  • Year and Date: 2011-09-29
• [Presentation] ポリカプロラクトンセグメントを持つ高分子有機ゲル化剤の開発 (2011)
  • Author(s): 鈴木岳志、鈴木正浩、英謙二
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-29
• [Presentation] TNT化学センサーとしての蛍光性ゲル化剤の開発 (2011)
  • Author(s): 原野一樹、鈴木正浩、英謙二
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-28
• [Presentation] アゾベンゼンカルボン酸とアミノ酸エステルからなる有機塩型低分子ゲル化剤の開発と応答性 (2011)
  • Author(s): 中村和貴、鈴木正浩、英謙二
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-27
• [Presentation] 12-ヒドロキシステアロイル基を含むアミノ酸誘導体のゲル化剤における水酸基の効果 (2011)
  • Author(s): 金野仁子、鈴木正浩、英謙二
  • Organizer: 第60回高分子討論会
  • Place of Presentation: 岡山大学
  • Year and Date: 2011-09-27
• [Presentation] 環状ジペプチド誘導体から形成される新規ハイドロゲル化剤の開発 (2011)
  • Author(s): 星沢裕子・鈴木正浩・英謙二
  • Organizer: 日本化学会第90春季年会予稿集
• [Presentation] 環状ジペプチド型ハイドロゲル化剤の開発 (2010)
  • Author(s): 星沢裕子、鈴木正浩、英謙二
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: パシフィコ横浜
• [Presentation] ポリシロキサンを有する環状ジペプチド誘導体型ゲル化剤 (2009)
  • Author(s): 吉川勝教、鈴木正浩、英謙二
  • Organizer: 高分子討論会
  • Place of Presentation: 熊本大学
  • Year and Date: 2009-09-18
• [Presentation] Development of New Gelators Formed by Cyclic(dipeptide) Derivative (2009)
  • Author(s): H. Hoshizawa, M. Suzuki, K. Hanabusa
  • Organizer: The 10th Asian Textile Conference(ATC-10). The 5th International Conference on Advanced Fiber/Textile Materials 2009(ICAFM2009)
  • Place of Presentation: Ueda, Japan
• [Presentation] Development of New Gelators Formedby Cyclic(dipeptide) Derivative (2009)
  • Author(s): H. Hoshizawa, M. Suzuki, K. Hanabusa
  • Organizer: The 10th Asian Textile Conference(ATC-10). The 5th International Conference on Advanced Fiber/Textile Materials 2009(ICAFM2009)
  • Place of Presentation: Ueda, Japan
• [Presentation] Development of Supramolecular gels formed by cyclic(dipeptide) derivative (2009)
  • Author(s): Hiroko Hoshizawa, Masahiro Suzuki, Kenji Hanabusa.
  • Organizer: The 1st FAPS Polymer Congress
  • Place of Presentation: Nagoya, Japan
• [Book] 食品・化粧品・医療分野へのゲルの応用 (2010)
  • Author(s): 英謙二
  • Total Pages: 245
  • Publisher: (株)シーエムシー出版
• [Book] 食品・化粧品・医療分野へのゲルの応用 (2010)
  • Author(s): 英謙二(分担執筆)
  • Total Pages: 245
  • Publisher: (株)シーエムシー出版
• [Book] 自己組織化ハンドブック (2009)
  • Author(s): 英謙二
  • Total Pages: 265
  • Publisher: (株)エヌ・ティー・エス
• [Book] 機能性繊維の最新技術 (2009)
  • Author(s): 英謙二
  • Total Pages: 273
  • Publisher: (株)シーエムシー出版
• [Book] 自己組織化ハンドブック (2009)
  • Author(s): 英謙二(分担執筆)
  • Total Pages: 265
  • Publisher: (株)エヌ・ティー・エス
• [Book] 機能性繊維の最新技術 (2009)
  • Author(s): 英謙二(分担執筆)
  • Total Pages: 273
  • Publisher: (株)シーエムシー出版
• [Patent(Industrial Property Rights)] 活性光線硬化型インクジェットインクとそれを用いたインクジェット記録方法 (2011)
  • Inventor(s): 英謙二
  • Industrial Property Rights Holder: コニカミノルタホールディングス
  • Acquisition Date: 2011-06-24
• [Patent(Industrial Property Rights)] ホログラム記録材料及びホログラム記録媒体 (2010)
  • Inventor(s): 英謙二
  • Industrial Property Rights Holder: TDK株式会社
  • Filing Date: 2010-10-04
• [Patent(Industrial Property Rights)] 流動性有機物の粘度調整方法及びそのための粘度調整剤 (2010)
  • Inventor(s): 英謙二
  • Industrial Property Rights Holder: 独立行政法人産業技術総合研究所
  • Filing Date: 2010-10-01
• [Patent(Industrial Property Rights)] 塩基性アミノ酸誘導体 (2010)
  • Inventor(s): 英謙二
  • Industrial Property Rights Holder: 味の素
  • Acquisition Date: 2010-07-09
• [Patent(Industrial Property Rights)] アミノ酸誘導体セグメント含有シロキサンポリマー及びそれを含有する有機媒体のゲル化剤 (2010)
  • Inventor(s): 英謙二
  • Industrial Property Rights Holder: 東レ・ダウコーニング
  • Acquisition Date: 2010-07-02