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Study on New material with Multiferroic Properties by Means of Containerless Solidification

Research Project

Project/Area Number 21360365
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionShibaura Institute of Technology

Principal Investigator

KURIBAYASHI Kazuhiko  芝浦工業大学, 工学部, 教授 (70092195)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥18,330,000 (Direct Cost: ¥14,100,000、Indirect Cost: ¥4,230,000)
Fiscal Year 2011: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2010: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2009: ¥9,230,000 (Direct Cost: ¥7,100,000、Indirect Cost: ¥2,130,000)
Keywordsマルチフェロイック物質 / ガスダイナミック浮遊炉 / 過冷凝固 / 酸素ポテンシャル希土類・遷移金属酸化物 / 酸素ポテンシャル / 相選択 / 希土類・遷移金属酸化物
Research Abstract

Until now, we have reported that in LuFeO3 the containerless processing can facilitate the metastable hexagonal phase(h-LuFeO3) with multiferroic properties to be formed. However, the magnetic properties of h-LuFeO3, which are not ferromagnetic but antiferromagnetic, prevent the material to be used practically. In order to solve this problem, we examined the chemical composition and the processing condition which are suited for a nano-scaled composite, because the forming of a nano-scaled mixture of these two phases is one of the potential methods for the multiferroic properties. As a result, we reached the conclusion that Lu(FexMn1-x) 2+yO4+z is one of the potential materials, because the substitution of a small fraction of Fe3+to Mn2+stabilizes the metastable h-LuFeO3, and suppresses the precipitation of the equilibrium orthorhombic phase(o-LuFeO3).

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (52 results)

All 2012 2011 2010 2009 Other

All Journal Article (22 results) (of which Peer Reviewed: 15 results) Presentation (27 results) Book (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Real-time x-ray diffraction of metastable phases during solidification from the undercooled LuFeO3 melt by two-dimensional detector at 1 kHz2012

    • Author(s)
      Malahalli Vijaya Kumar, K. Kuribayashi, K. Nagashio, T. Ishikawa, J. Okada, J. Yu, S. Yoda and Y. Katayama
    • Journal Title

      Appl. Phys. Lett.

      Volume: 100 Issue: 19 Pages: 191905-191905

    • DOI

      10.1063/1.4712124

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystallographic Stability of Metastable Phase formed by Containerless Processing in REFeO3 (RE : Rare-earth Element)2012

    • Author(s)
      K.Kuribayashi, M.S.Vijaya Kumar
    • Journal Title

      Materials Research in Microgravity

      Volume: (印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Orthorhombic and Multiferroic Hexagonal Phases from an Undercooled RMnO3(R=Rare-Earth Element) Melt Using a Containerless Technique2011

    • Author(s)
      M. S. Vijaya Kumar, N. Higaki, K. Kuribayashi, T. Hibiya and S. Yoda
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 94 Issue: 1 Pages: 282-289

    • DOI

      10.1111/j.1551-2916.2010.04042.x

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Siの過冷凝固におけるTwin⇔Twin-free遷移2011

    • Author(s)
      渡邊一樹、永山勝久、栗林一彦
    • Journal Title

      日本金属学会誌

      Volume: 75 Pages: 188-192

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] Influence of Morphological Transition on Crystallization Process in Si2011

    • Author(s)
      Kazuki Watanabe, Katsuhisa Nagayama and Kazuhiko Kuribayashi
    • Journal Title

      J. Jpn. Soc. Microgravity Appl

      Volume: 28 Pages: 64-67

    • NAID

      10031143419

    • URL

      http://www.e-jasma.com/arc/paper/J1319434394

    • Related Report
      2011 Final Research Report
  • [Journal Article] Entropy-Undercooling Regime Criterion for Metastable Phase Formation in Compound Material2011

    • Author(s)
      Kazuhiko Kuribayashi and Vijaya Kumar
    • Journal Title

      J. Jpn. Soc. Microgravity Appl

      Volume: 28 Pages: 68-71

    • URL

      http://www.e-jasma.com/arc/paper/J1319434533

    • Related Report
      2011 Final Research Report
  • [Journal Article] Formation of Hexagonal Metastable Phases from an Undercooled R3Fe5O12 Melt Under Controlled Oxygen Partial Pressure2011

    • Author(s)
      Vijaya Kumar, Jianding Yu, M. Kaneko, T. Ishikawa, J. Okada, Y. Inatomi, T. Hibiya, K. Kuribayashi and S. Yoda
    • Journal Title

      J. Jpn. Soc. Microgravity Appl

      Volume: 28 Pages: 51-56

    • URL

      http://www.e-jasma.com/arc/paper/J1319434099

    • Related Report
      2011 Final Research Report
  • [Journal Article] Morphological Transition in Crystallization of Si from Undercooled Melt2011

    • Author(s)
      Kazuki Watanabe, Katsuhisa Nagayama and Kazuhiko Kuribayashi
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 327 Pages: 12018-12018

    • DOI

      10.1088/1742-6596/327/1/012018

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Entropy-Undercooling Regime Criterion for Metastable Phase Formation in Compound Material2011

    • Author(s)
      Kazuhiko Kuribayashi and Vijaya Kumar
    • Journal Title

      Journal of Physics : Conference Series

      Volume: 327 Pages: 12019-12019

    • DOI

      10.1088/1742-6596/327/1/012019

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Entropy-Undercooling Regime Criterion for Metastable Phase Formation in Oxide Material2011

    • Author(s)
      Kazuhiko Kuribayashi, M.S.Vijaya Kumar
    • Journal Title

      J.Jpn.Soc.Microgravity Appl.

      Volume: 28 Pages: 68-71

    • NAID

      10031143420

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influence of Morphological Transition on Crystallization Process in Si2011

    • Author(s)
      Kazuki Watanabe, Karsuhisa Nagayama, Kazuhiko Kuribayashi
    • Journal Title

      J.Jpn.Soc.Microgravity Appl.

      Volume: 28 Pages: 64-67

    • NAID

      10031143419

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase Selection in the Undercooled Melts of RMnO3 (R=rare earth) Using Containerless Solidification Technique2011

    • Author(s)
      Vijaya KUMAR, Kazuhiko KURIBAYASHI, Jianding YU, Masashi KANEKO, Takehiko ISHIKAWA, Shinichi YODA
    • Journal Title

      J.Jpn.Soc.Microgravity Appl.

      Volume: 28 Pages: 51-56

    • NAID

      130007972451

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Siの過冷凝固におけるTwin-related⇔Twin-free遷移2011

    • Author(s)
      渡邊一樹, 永山勝久, 栗林一彦
    • Journal Title

      日本金属学会誌

      Volume: 75 Pages: 188-192

    • NAID

      10027839743

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Orthorhombic and Multiferroic Hexagonal Phases from an Undercooled RMnO_3 (R=Rare-Earth Element) Melt Using a Containerless Technique2011

    • Author(s)
      M.S.Vijaya Kumar, N.Higaki, K.Kuribayashi, T.Hibiya, S.Yoda
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 94 Pages: 282-289

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 過冷メルトからの準安定相創製2010

    • Author(s)
      栗林一彦
    • Journal Title

      日本マイクログラビティ応用学会誌

      Volume: 27 Pages: 233-237

    • NAID

      10027646557

    • URL

      http://www.e-jasma.com/arc/paper/J1291457286

    • Related Report
      2011 Final Research Report
  • [Journal Article] 過冷メルトからの準安定相創製2010

    • Author(s)
      栗林一彦
    • Journal Title

      日本マイクログラどディ応用学会誌

      Volume: 27 Pages: 233-237

    • NAID

      10027646557

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] a-Tiにおける室温クリープの構成方程式2010

    • Author(s)
      亀山達也、松永哲也、上田章二、佐藤英一、栗林一彦
    • Journal Title

      軽金属

      Volume: 60 Pages: 111-116

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Single bubble growth during water electrolysis under microgravity2009

    • Author(s)
      H.Matsushima, D.Kiuchi, Y.Fukunaka, K.Kuribayashi
    • Journal Title

      Electrochemistry Communications 11

      Pages: 1721-1723

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transformation of RE_2Fe_<17>B_x(RE=Nd, Dy)Metastable Phase Crystallized from Undercooled Melt2009

    • Author(s)
      S.Ozawa, A.Ito, K.Kuribayashi, T.Miyoshi, S.Horosawa
    • Journal Title

      J.Jpn Soc.Microgravity Appl

      Pages: 122-125

    • NAID

      10025111078

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Suppression of ambient-temperature creep in CP-Ti by cold-rolling2009

    • Author(s)
      T.Kameyama, T.Matsunaga, E.Sato, K.Kuribayashi
    • Journal Title

      Materials Science and Engineering A 510-511

      Pages: 364-367

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] ドロップチューブ法を用いたNd-Fe系合金の準安定相生成と高保磁力発現2009

    • Author(s)
      米村寛, 東雲秀司, 永山勝久, 栗林一彦
    • Journal Title

      日本マイクログクビティ応用学会誌 26

      Pages: 117-121

    • NAID

      10025111063

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      K.Nagashio, K, Kuribayashi
    • Journal Title

      Crystal Growth of Si for Solar Cells(Springer)

      Pages: 121-134

    • Related Report
      2009 Annual Research Report
  • [Presentation] Crystallographic Stability of Metastable Phase Formed by Containerless Processing in REFeO3(RE : Rare-Earth Element)2012

    • Author(s)
      K. Kuribayashi and M. S. V. Kumar
    • Organizer
      TMS Annual Meeting & Exhibition(invited)
    • Place of Presentation
      Orlando, HL
    • Related Report
      2011 Final Research Report
  • [Presentation] Crystallographic Stability of Metastable Phase Formed by Containerless Processing in REFeO3 (RE : Rare-Earth Element)2012

    • Author(s)
      K.Kuribayashi, M.S.V.Kumar
    • Organizer
      2012 TMS Annual Meeting & Exhibition
    • Place of Presentation
      Orlando, FL(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 無容器浮遊溶融法によるGeの過冷却凝固2011

    • Author(s)
      石橋裕輔, 栗林一彦, 永山勝久
    • Organizer
      2011年日本金属学会秋季大会
    • Place of Presentation
      沖縄コンベンションセンター
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 無容器過冷凝固によるマルチフェロイック物質の探索2011

    • Author(s)
      大内良晃, 栗林一彦M. S. Vijaya Kumar永山勝久
    • Organizer
      2011年日本金属学会秋季大会
    • Place of Presentation
      沖縄コンベンションセンター
    • Year and Date
      2011-11-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 準安定六方晶REFeO3(RE:希土類元素)の構造安定性2011

    • Author(s)
      栗林一彦, M. S. Vijaya Kumar
    • Organizer
      2011年日本金属学会秋季大会
    • Place of Presentation
      沖縄コンベンションセンター
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Entropy-Undercooling Regime Criterion for Metastable Phase Formation in Compound Material2011

    • Author(s)
      Kazuhiko Kuribayashi and Vijaya Kumar
    • Organizer
      4th Int. Symposium on Physical Sciences in Space
    • Place of Presentation
      Bonn-Bad Godesberg
    • Related Report
      2011 Final Research Report
  • [Presentation] MorphologicalTransition in Crystallization of Si from Undercooled Melt2011

    • Author(s)
      Kazuki Watanabe, Katsuhisa Nagayama and Kazuhiko Kuribayashi
    • Organizer
      4th Int. Symposium on Physical Sciences in Space
    • Place of Presentation
      Bonn-Bad Godesberg
    • Related Report
      2011 Final Research Report
  • [Presentation] Influence of Oxygen Partial Pressure on the Formation of Metastable Phases in the R-Fe-O System,(R=rare-earth) by Levitation Technique2011

    • Author(s)
      M. S. V. Kumar, Ju Jianding, M. Kaneko, K. Kuribayashi and S. Yoda
    • Organizer
      4th Int. Symposium on Physical Sciences in Space
    • Place of Presentation
      Bonn-Bad Godesberg, Germany
    • Related Report
      2011 Final Research Report
  • [Presentation] Metastable Phase Formation from Undercooled Melt of Oxide Material2011

    • Author(s)
      K.Kuribayashi, M.S.V.Kumar
    • Organizer
      4th Int.Symposium on Physical Sciences in Space
    • Place of Presentation
      Bonn-Bad Godesberg, Germany
    • Related Report
      2011 Annual Research Report
  • [Presentation] Influence of Oxygen Partial Pressure on the Formation of Metastable Phases in the R-Fe-O System (R=rare-earth) by Levitation Technique2011

    • Author(s)
      M.S.V.Kumar, Ju Jianding, M.Kaneko, K.Kuribayashi, S.Yoda
    • Organizer
      4th Int.Symposium on Physical Sciences in Space
    • Place of Presentation
      Bonn-Bad Godesberg, Germany
    • Related Report
      2011 Annual Research Report
  • [Presentation] Morphological Transition in Crystallization of Si from Undercooled Melt2011

    • Author(s)
      K.Watanabe, K.Nagayama, K.Kuribayashi
    • Organizer
      4th Int.Symposium on Physical Sciences in Space
    • Place of Presentation
      Bonn-Bad Godesberg, Germany
    • Related Report
      2011 Annual Research Report
  • [Presentation] 過冷メルトからの準安定相創製2010

    • Author(s)
      栗林一彦
    • Organizer
      日本鉄鋼協会高温プロセス部会高温物性値フォーラム
    • Place of Presentation
      東北大学片平キャンパス
    • Year and Date
      2010-01-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] Phase selection in the undercooled melt of RMnO3(R=rare earth element) using containerless solidification technique2010

    • Author(s)
      Vijaya Kumar, Kazuhiko Kuribayashi, Jianding Yu1, Masashi Kaneko, Takehiko Ishikawa and Shinichi Yoda
    • Organizer
      8th Japan-China=Korea Workshop Microgravity Sciences for Asian Microgravity Sciences for Asian Microgravituy Pre-Symposium
    • Place of Presentation
      Akiu, Sendai Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] Entropy-Undercooling Regime Criterion for Metastable Phase Formation in Compound Material2010

    • Author(s)
      Kazuhiko Kuribayashi and Vijaya Kumar
    • Organizer
      8th Japan-China=Korea Workshop Microgravity Sciences for Asian Microgravituy Pre-Symposium
    • Place of Presentation
      Akiu, Sendai Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] Influence of Morphological Transition on Crystallization Process in Si2010

    • Author(s)
      Kazuki Watanabe, Katsuhisa Nagayama and Kazuhiko Kuribayashi
    • Organizer
      8th Japan-China=Korea Workshop Microgravity Sciences for Asian Microgravituy Pre-Symposium
    • Place of Presentation
      Akiu, Sendai Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] Influence of Morphological Transition on Crystallization Process in Si2010

    • Author(s)
      Kazuki Watanabe, Katsuhisa Nagayama, Kazuhiko Kuribayashi
    • Organizer
      8^<th> Japan-China=Korea Workshop Microgravity Sciences for Asian Microgravity Pre-Symposium
    • Place of Presentation
      Akiu, Sendai Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Entropy-Undercooling Regime Criterion for Metastable Phase Formation in Compound Material2010

    • Author(s)
      Kazuhiko Kuribayashi, Vijaya Kumar
    • Organizer
      8^<th> Japan-China=Korea Workshop Microgravity Sciences for Asian Microgravity Pre-Symposium
    • Place of Presentation
      Akiu, Sendai Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Phase selection in the undercooled melt of RMnO_3 (R=rare earth element) using containerless solidification technique2010

    • Author(s)
      Vijaya Kumar, Kazuhiko Kuribayashi, Jianding Yu1, Masashi Kaneko, Takehiko Ishikawa, Shinichi Yoda1
    • Organizer
      8^<th> Japan-China=Korea Workshop Microgravity Sciences for Asian Microgravity Pre-Symposium
    • Place of Presentation
      Akin, Sendai Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] In situ Observation of Spreading and Solidification Behavior of Zirconia Molten Drop Impinging on Solid Surface2009

    • Author(s)
      Kentaro Shinoda, Kosuke Nagashio, Hideyuki Murakami, Seiji Kuroda, Kazuhiko Kuribayashi
    • Organizer
      MRS 2009 Fall Meeting
    • Place of Presentation
      Boston, MA
    • Year and Date
      2009-12-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] Formation of Hexagonal Metastable Phases from an Undercooled R3Fe5O12 Melt Under Controlled Oxygen Partial Pressure2009

    • Author(s)
      Vijaya Kumar, Jianding Yu, M. Kaneko, T. Ishikawa, J. Okada, Y. Inatomi, T. Hibiya, K. Kuribayashi and S. Yoda
    • Organizer
      日本マイクログラビティ応用学会第24回学術講演会
    • Year and Date
      2009-10-20
    • Related Report
      2011 Final Research Report
  • [Presentation] Formation of Hexagonal Metastable Phases from an Undercooled R_3Fe_5O_<12> Melt Under Controlled Oxygen Partial Pressure2009

    • Author(s)
      Vijaya Kumar, Jianding Yu, M.Kaneko, T.Ishikawa, J.Okada, Y.Inatomi, T.Hibiya, K.Kuribayashi, S.Yoda
    • Organizer
      日本マイクログラビティ応用学会第24回学術講演会
    • Place of Presentation
      沖縄産業支援センター
    • Year and Date
      2009-10-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] 冷メルトからの準安定相創製2009

    • Author(s)
      栗林一彦, Malahalli S. Vijaya Kumar
    • Organizer
      日本鉄鋼協会第158回秋期講演大会
    • Year and Date
      2009-09-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 過冷メルトからの準安定相創製2009

    • Author(s)
      栗林一彦, Malahalli S.Vijaya Kumar
    • Organizer
      日本鉄鋼協会第158回秋期講演大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Metastable Phase Formation from an Undercooled Melt of Rare-earth Orthoferrite Under Reduced Po2009

    • Author(s)
      Malahalli S. Vijaya Kumar, 栗林一彦, 北薗幸一, 依田眞一
    • Organizer
      日本金属学会2009年秋期(第145回)大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Year and Date
      2009-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] AlP添加Siの球状結晶化2009

    • Author(s)
      栗林一彦, 長汐晃輔
    • Organizer
      日本金属学会2009年秋期(第145回)大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Year and Date
      2009-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] AIP添加Siの球状結晶化2009

    • Author(s)
      栗林一彦, 長汐晃輔
    • Organizer
      日本金属学会2009年秋期(第145回)大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Metastable Phase Formation from an Undercooled Melt of Rare-earth Orthoferrite Under Reduced Po_22009

    • Author(s)
      Malahalli S.Vijaya Kumar, 栗林一彦, 北薗幸一, 依田眞一
    • Organizer
      日本金属学会2009年秋期(第145回)大会
    • Place of Presentation
      京都大学吉田キャンパス
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Book] Crystal Growth of Si for Solar Cells, ed by K. Nakajima and N. Usami2009

    • Author(s)
      K. Nagashio and K, Kuribayashi
    • Publisher
      Springer
    • Related Report
      2011 Final Research Report
  • [Book] Solidification of Containerless Undercooled Melts (ed by Dieter M.Herlach and Douglas M.Matson)

    • Author(s)
      K.Kuribayashi
    • Publisher
      WILEY-VCH(in press)
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 球状シリコン結晶の製造方法2010

    • Inventor(s)
      栗林一彦, 長汐晃輔, 安藤等
    • Industrial Property Rights Holder
      宇宙航空研究開発機構
    • Acquisition Date
      2010-02-26
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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