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Ion beam near infrared-visible photo detachment spectroscopy of the solvated electron.

Research Project

Project/Area Number 21550018
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionKyushu University

Principal Investigator

HARADA Kensuke  九州大学, 理学研究院, 講師 (70165017)

Co-Investigator(Kenkyū-buntansha) TANAKA Keiichi  九州大学, 宙空環境研究センター, 学術研究者 (50037280)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywordsイオンビーム / イオン錯体 / 陰イオン / 溶媒和電子 / 光脱離 / 半導体レーザー / フーリエ変換分光 / クラスター / 分子構造 / 陰イオン錯体 / 近赤外分光 / 電子脱離分光
Research Abstract

Ion beam spectrometer coupled with a quadrupole mass spectrometer and an electro spray ion source has been developed. The ESI ion source is now being reconstructed for the perpendicular configuration of the ion source and mass spectrometer to avoid stream of the liquid droplets. The near infrared and visible diode laser spectrometer has been constructed. Tha laser diodes in the 405, 450, 512, 630, 650, 670, 780, 816, 838, 859, 1310, and 1550 nm have been tested. The Fourier transform absorption spectrometer with the near infrared and visible diode lasers as light sources has been developed to determine precise wavelength of the signals.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (24 results)

All 2011 2010 2009 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (10 results) Book (4 results) Remarks (4 results)

  • [Journal Article] Millimeter-wave spectroscopy of H2C=CD : Tunneling splitting and ortho-para mixing interaction2010

    • Author(s)
      M. Hayashi, K. Harada, R. Lavrich, T. Tanaka, and K. Tanaka
    • Journal Title

      J. Chem. Phys

      Volume: 133 Pages: 154303-154303

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Millimeter-wave spectroscopy of deuterated vinyl radicals, observation of the ortho-para mixing interaction and predicton of the fast ortho-para conversion rates2010

    • Author(s)
      K. Tanaka, M. Hayashi, M. Ohtsuki, K. Harada, and T. Tanaka
    • Journal Title

      Mol. Phys

      Volume: 108 Pages: 2289-2289

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Millimeter-wave spectroscopy of deuterated vinyl radicals, observation of the ortho-para mixing interaction and prediction of fast ortho-para conversion rates.2010

    • Author(s)
      K.Tanaka, M.Hayashi, M.Ohtsuki, K.Harada, T.Tanaka
    • Journal Title

      Mol.Phys.

      Volume: 108 Pages: 2289-2301

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Millimeter-wave spectroscopy of H_2C=CD : Tunneling splitting and ortho-para mixing interaction.2010

    • Author(s)
      M.Hayashi, K.Harada, R.Lavrich, T.Tanaka, K.Tanaka
    • Journal Title

      J.Chem.Phys.

      Volume: 133

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ortho-para mixing interaction in the vinyl radical detected by millimeter-wave spectroscopy2009

    • Author(s)
      K. Tanaka, M. Hayashi, M. Ohtsuki, K. Harada, and T. Tanaka
    • Journal Title

      J. Chem. Phys

      Volume: 131

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ortho-para mixing interaction in the vinyl radical detected by millimeter-wave spectroscopy2009

    • Author(s)
      K.Tanaka, M.Hayashi, M.Ohtsuki, K.Harada, T.Tanaka
    • Journal Title

      J.Chem.Phys. 131

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] He-HCNおよびH_2-HCNの分子間ポテンシャル2011

    • Author(s)
      原田賢介・山中里沙・萩健介・田中桂一
    • Organizer
      分子科学討論会2011
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2011-09-23
    • Related Report
      2011 Annual Research Report
  • [Presentation] He-DCNの解離限界付近の準位間の分子間振動遷移のミリ波ジェット分光2011

    • Author(s)
      原田賢介・高城正徳・田中桂一
    • Organizer
      第11回分子分光研究会
    • Place of Presentation
      広島市立大学
    • Year and Date
      2011-05-20
    • Related Report
      2011 Annual Research Report
  • [Presentation] Kensuke HARADA2011

    • Author(s)
      Spectroscopy and Reaction Dynamics of Reaction Intermediates and Molecular Complexes
    • Organizer
      The 6^<th> BK21 International Symposiumon on Materials Chemistry 2011
    • Place of Presentation
      Busan, Korea
    • Related Report
      2011 Final Research Report
  • [Presentation] REASSIGNMENT OF MILLIMETERWAVE SPECTRUM OF THE HCN INTERNAL ROTATION BANDS OF H_2-HCN2011

    • Author(s)
      K. HARADA, R. YAMANAKA, and K. TANAKA
    • Organizer
      The 66_<th> International Symposium on Molecular Spectroscopy
    • Place of Presentation
      Ohio State University
    • Related Report
      2011 Final Research Report
  • [Presentation] Spectroscopy and Reaction Dynamics of Reaction Intermediates and Molecular Complexes2011

    • Author(s)
      Kensuke HARADA
    • Organizer
      The 6^<th> BK21 International Symposiumon on Materials Chemistry 2011
    • Place of Presentation
      Busan, Korea(Invited Talk)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ORTHO-PARA MIXING INTERACTION AND FAST ORTHO-PARA CONVERSION RATE IN THE VINYL RADICAL2010

    • Author(s)
      K. TANAKA, M. HAYASHI, M. OHTSUKI, K. HARADA, and T. TANAKA
    • Organizer
      The 21_<st> International Conference on High-Resolution Molecular Spectroscopy
    • Place of Presentation
      Poznan, Poland
    • Year and Date
      2010-09-08
    • Related Report
      2011 Final Research Report
  • [Presentation] Kensuke HARADA2010

    • Author(s)
      High-resolution spectroscopy of weakly bound molecular complexes
    • Organizer
      The 21st International Conference on High-Resolution Molecular Spectroscopy
    • Place of Presentation
      Poznan, Poland
    • Year and Date
      2010-09-07
    • Related Report
      2011 Final Research Report
  • [Presentation] Millimeter wave spectroscopy of weakly bound molecular complexes.2010

    • Author(s)
      K.HARADA
    • Organizer
      The 21st International Conference on High Resolution Molecular Spectroscopy.
    • Place of Presentation
      Poznan, Poland
    • Year and Date
      2010-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] ORTHO-PARA MIXING INTERACTION IN THE VINYL RADICAL DETECTED BY MILLIMETER-WAVE SPECTROSCOPY AND PREDICTION OF FAST ORTHO-PARA CONVERSION RATE2010

    • Author(s)
      K. TANAKA, M. HAYASHI, M. OHTSUKI, K. HARADA AND T. TANAKA
    • Organizer
      The 65_<th> International Symposium on Molecular Spectroscopy
    • Place of Presentation
      Ohio State University
    • Related Report
      2011 Final Research Report
  • [Presentation] MILLIMETER-WAVE SPECTROSCOPY OF THE vdW BANDS OF He-HCN NEAR THE DISSOCIATION LIMIT2010

    • Author(s)
      K. HARADA AND K. TANAKA
    • Organizer
      The 65_<th> International Symposium on Molecular Spectroscopy
    • Place of Presentation
      Ohio State University
    • Related Report
      2011 Final Research Report
  • [Book] THz and submillimeter-wave spectroscopy of molecular complexes, HANDBOOK OF HIGHRESOLUTION SPECTROSCOPIES2011

    • Author(s)
      K. Tanaka, K. Harada, and K.M.T. Yamada
    • Total Pages
      44
    • Publisher
      John Wiley & Sons, Ltd
    • Related Report
      2011 Final Research Report
  • [Book] "THz and submillimeter-wave spectroscopy of molecular complexes" in "HANDBOOK OF HIGHRESOLUTION SPECTROSCOPIES", edited by M.Quack and F.Merkt2011

    • Author(s)
      K.Tanaka, K.Harada, K.M.T.Yamada
    • Total Pages
      44
    • Publisher
      John Wiley & Sons, Ltd
    • Related Report
      2011 Annual Research Report
  • [Book] THz and submillimeter-wave spectroscopy of molecular complexes(edited by M.Quack and F.Merkt)(HANDBOOK OF HIGHRESOLUTION SPECTROSCOPIES)2011

    • Author(s)
      K.Tanaka, K.Harada, K.M.T.Yamada
    • Total Pages
      44
    • Publisher
      John Wiley & Sons, Ltd
    • Related Report
      2010 Annual Research Report
  • [Book] THz and submillimeter-wave spectroscopy of molecular complexes. In "HANDBOOK OF HIGHRESOLUTION SPECTROSCOPIES"(edited by M.Quack and F.Merkt)2010

    • Author(s)
      K.Tanaka, K.Harada, K.M.T.Yamada
    • Total Pages
      44
    • Publisher
      John Wiley & Sons, Ltd
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://133.5.167.83/

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://133.5.167.83/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://133.5.167.83/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://133.5.167.83/

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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