Studies on Environment-Friendly Reactions by use of Soluble Polymer
| Project/Area Number |
21550051
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Meisei University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
MACHINAMI Tomoya 明星大学, 理工学部, 教授 (50247160)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
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| Keywords | ポリマー / 環境調和型反応 / PEG / 酸化反応 / 可溶性試薬 |
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| Research Abstract |
New soluble polymer-supported compounds were effectivelyprepared, and they were used as the recoverable and recyclable reagent in several organicreactions, which include oxidation of alcohols by PEG-supported TEMPO, enzyme-mediated enantioselective hydrolysis of PEG-supported carboxylic esters, scavenging alcohols by PEG-supported carboxylic acids. On the other hand, Mitsunobureaction using polystyrene-supported triphenylphosphine was established.
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Report
(4 results)
Research Products
(31 results)
