| Project/Area Number |
21550055
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Yamagata University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
KITAGAWA Hiroshi 京都大学, 理学研究科, 教授 (90234244)
YAMADA Teppei 京都大学, 理学研究科, 助教 (10404071)
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
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| Keywords | 配位高分子 / ナノ結晶 / 固体イオン伝導 / 配位空間 / プルシアンブルー / 表面修飾 / ゼータ電位 / 界面 |
|---|
| Research Abstract |
In this study, we succeeded in preparation of Cs^+-embedded (inner-modified) PB nanocrystals in their crystal lattice spaces and surface-modified PB nanocrystals by K^+, Na^+, and NH4^+ using their unsaturated coordination sites. Ion conductivities of the inner-and surface-modified PB nanocrystals were 10 or 100 times increased in the solid state (pellet), compared to that of the original PB. In higher relative humidity conditions, the ion conductivities were elevated, suggesting significant contribution of the proton transportation. Both hydration structures of interface among the PB nanocrystals and their inner lattice spaces play an important role in the solid-state ion conductivity mechanism.
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