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Development of heavy transition metal complexes showing new photophysical properties arising from cooperative effects between the transition elements

Research Project

Project/Area Number 21550062
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionNagasaki University

Principal Investigator

UMAKOSHI Keisuke  長崎大学, 大学院・工学研究科, 教授 (20213481)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords重遷移金属元素 / 白金 / 11族元素 / 多核錯体 / 発光 / 光物性 / ピラゾール / 混合金属錯体 / 金属間相互作用
Research Abstract

In this study, we have succeeded in the syntheses of luminescent heteropolynuclear complexes containing three transition elements, which exhibit synergetic effect of the three transition elements. Various(diimine) Pt complexes containing 3-t-butylpyrazole reacted with group 11 metal ions to give Z-shaped luminescent heteropolynuclear complexes. We have also succeeded in elucidating the influence of chloride ligands coordinated to Pt atom on the emission energy of heteropolynuclear complexes.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (44 results)

All 2012 2011 2010 2009 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (21 results) Remarks (4 results) Patent(Industrial Property Rights) (13 results) (of which Overseas: 5 results)

  • [Journal Article] Pyrazolato and 3, 5-dimethylpyrazolato bridged dinuclear platinum(II), palladium(II), and their mixed-metal complexes of 2, 2'-bipyrimidine. Syntheses, structures, and luminescent properties2010

    • Author(s)
      K. Umakoshi, K. Kimura, Y. H. Kim, Y. Tsukimoto, Y. Arikawa, M. Onishi, S. Ishizaka, N.
    • Journal Title

      Kitamura, Bull. Chem. Soc. Jpn

      Volume: 83 Pages: 1504-1510

    • NAID

      10027653695

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study of Excited States of Pyrazolate-and Pyridinethiolate-Bridged Dinuclear Platinum(II) Complexes : Relationship between Geometries of Excited States and Phosphorescence Spectra2010

    • Author(s)
      K. Saito, Y. Nakao, K. Umakoshi, S. Sakaki
    • Journal Title

      Inorg. Chem

      Volume: 49 Pages: 8977-8985

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pyrazolato and 3,5-dimethylpyrazolato bridged dinuclear platinum(II), palladium(II), and their mixed-metal complexes of 2,2'-bipyrimidine. Syntheses, structures, and luminescent properties2010

    • Author(s)
      K.Umakoshi, K.Kimura, Y.H.Kim, Y.Tsukimoto, Y.Arikawa, M.Onishi, S.Ishizaka, N.Kitamura
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 40 Pages: 1504-1510

    • NAID

      10027653695

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Study of Excited States of Pyrazolate- and Pyridinethiolate-Bridged Dinuclear Platinum(II) Complexes : Relationship between Geometries of Excited States and Phosphorescence Spectra2010

    • Author(s)
      K.Saito, Y.Nakao, K.Umakoshi, S.Sakaki
    • Journal Title

      Inorganic Chemistry

      Volume: 49 Pages: 8977-8985

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Luminescent Heteropolynuclear Complexes of 3, 5-Dimethylpyrazolate[ Pt_2Au_2M_2(Me_2pz)_8](M=Ag, Cu) Showing Synergistic Effect of Three Transition Elements in the Excited State2009

    • Author(s)
      K. Umakoshi, K. Saito, Y. Arikawa, M. Onishi, S. Ishizaka, N. Kitamura, Y. Nakao, S. Sakaki
    • Journal Title

      Chem. Eur. J

      Volume: 15 Pages: 4238-4242

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Luminescent Heteropolynuclear Complexes of 3,5-Dimethylpyrazolate [Pt_2Au_2M_2(Me_2pz)_8](M=Ag, Cu)Showing Synergistic Effect of Three Transition Elements in the Excited State2009

    • Author(s)
      K.Umakoshi, K.Saito, Y.Arikawa, M.Onishi, S.Ishizaka, N.Kitamura, Y.Nakao, S.Sakaki
    • Journal Title

      Chemistry A European Journal 15

      Pages: 4238-4242

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] ビス(ジフェニルホスフィノ)フェロセンを有するシクロメタル化白金錯体の合成と性質2012

    • Author(s)
      金松泰範・有川康弘・馬越啓介
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 種々の(ジイミン)白金ユニットと11族金属イオンからなる混合金属錯体の合成と発光特性2012

    • Author(s)
      東谷阿美・有川康弘・馬越啓介
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応義塾大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 白金-貨幣金属原子間の相互作用を利用した新規リン光材料の開発2011

    • Author(s)
      馬越啓介
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 白金-貨幣金属原子間の相互作用を利用した新規リン光材料の開発2011

    • Author(s)
      馬越啓介
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] 白金およびパラジウムに異なるジイミン配位子を有する混合金属錯体の合成と性質2011

    • Author(s)
      月元裕也・木村和豊・有川康弘・馬越啓介
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] ジフェニルピラゾラトがシクロメタル化した二核白金錯体の合成と性質2011

    • Author(s)
      金松泰範・有川康弘・馬越啓介・石坂昌司・喜多村昇
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] 強発光性白金(II)-銀(I)六核錯体におけるリン光状態と発光メカニズム2011

    • Author(s)
      河上寛明・野崎浩一・岩村崇高・馬越啓介
    • Organizer
      第61回錯体化学討論会
    • Place of Presentation
      岡山理科大学
    • Related Report
      2011 Annual Research Report
  • [Presentation] ジフェニルピラゾラトがシクロメタル化及び架橋した二核白金錯体の合成と性質特性2011

    • Author(s)
      金松泰範・馬越啓介・有川康弘・石坂昌司・喜多村昇
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] (ジイミン)白金ユニットと11族金属イオンからなる混合金属錯体の合成と発光特性2011

    • Author(s)
      東谷阿美・馬越啓介・有川康弘・石坂昌司・喜多村昇
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] Pyrazolate and 3,5-Dimethylpyrazolate Bridged Dinuclear Platinum(II), Palladium(II), and Their Mixed-Metal Complexes of Bipyrimidine. Syntheses, Structures, and Luminescent Properties2010

    • Author(s)
      K.Kimura, K.Umakoshi, Y.H.Kim, Y.Arikawa, M.Onishi, S.Ishazaka, N, Kitamnra
    • Organizer
      Nagasaki Symposium on Nano-Dynamics 2010
    • Place of Presentation
      長崎大学
    • Year and Date
      2010-01-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] ピラゾラト配位子が架橋した混合金属錯体の発光特性2010

    • Author(s)
      馬越啓介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学
    • Related Report
      2011 Final Research Report
  • [Presentation] 種々のジイミンがキレート配位した白金およびパラジウムユニットをピラゾラト配位子が架橋した二核錯体の合成と発光特性2010

    • Author(s)
      月元裕也・馬越啓介・有川康弘・大西正義・石坂昌司・喜多村昇
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪交流センター
    • Related Report
      2010 Annual Research Report
  • [Presentation] Pyrazolate Bridged Dinuclear Platinum(II), Palladium(II), and Their Mixed-metal Complexes of 2,2'-Bipyrimidine. Synthesis, Structures, and Luminescent Properties2010

    • Author(s)
      K.Umakoshi, K.Kimura, Y.H.Kim, Y.Tsukimoto, A.Higashitani, Y.Arikawa, M.Onishi, S.Ishizaka, N. Kitamura
    • Organizer
      60th Anniversary Conference on Coordination Chemistry
    • Place of Presentation
      大阪交流センター
    • Related Report
      2010 Annual Research Report
  • [Presentation] ピラゾラト配位子が架橋した混合金属錯体の発光特牲2010

    • Author(s)
      馬越啓介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] ジフェニルピラゾラトおよびアルキルピラゾラト配位子を有する白金-銀錯体の合成と発光特性2010

    • Author(s)
      馬越啓介・栗原嵩明・末吉翔太・有川康弘・大西正義・石坂昌司・喜多村昇
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] (ジメチルビピリミジン)白金ユニットをピリジンチオラト配位子が架橋した多核白金錯体の合成と性質2010

    • Author(s)
      月元裕也・木村和豊・馬越啓介・有川康弘・大西正義
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属間相互作用により発現する白金および混合金属錯体の興味深い物性2009

    • Author(s)
      馬越啓介
    • Organizer
      高分子学会09-1有機EL研究会
    • Place of Presentation
      東京大学
    • Year and Date
      2009-07-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 金属間相互作用により発現する白金および混合金属錯体の興味深い物性2009

    • Author(s)
      馬越啓介
    • Organizer
      高分子学会 09-1有機EL研究会
    • Place of Presentation
      東京大学
    • Year and Date
      2009-07-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Luminescent Heteropolynuclear Complexes of 3,5-Dimethylpyrazolate [Pt_2Au_2M_2(Me_2pz)_8](M=Ag, Cu) Showing Synergetic Effect of Three Transition Elements in the Excited State2009

    • Author(s)
      K.Umakoshi, K.Saito, Y.Arikawa, M.Onishi, S.Ishazaka, N.Kitamura, Y.Nakao, S.Sakaki
    • Organizer
      18th International Symposium on the Photochemistry and Photophysics of Coordination Compounds
    • Place of Presentation
      札幌
    • Related Report
      2009 Annual Research Report
  • [Presentation] ピラゾラト配位子とピリジンチオラト配位子が架橋した二核パラジウムおよび白金-パラジウム錯体の合成と性質2009

    • Author(s)
      木村和豊・馬越啓介・有川康弘・大西正義
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] インダゾールとジメチルピラゾールを架橋配位子とする白金-銅及び白金-銀錯体の合成と性質2009

    • Author(s)
      重田和輝・馬越啓介・有川康弘・大西正義・石坂昌司・喜多村昇・三上智司
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.ch.nagasaki-u.ac.jp/coo/

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.ch.nagasaki-u.ac.jp/coo/

    • Related Report
      2011 Annual Research Report
  • [Remarks]

    • URL

      http://www.ch.nagasaki-u.ac.jp/coo/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.ch.nagasaki-u.ac.jp/coo/

    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] PALLADIUM METAL COMPLEX2012

    • Inventor(s)
      馬越啓介,木村和豊,大西正義,石坂昌司,喜多村昇,三上智司
    • Industrial Property Rights Holder
      国立大学法人長崎大学/住友化学株式会社
    • Filing Date
      2012-02-28
    • Related Report
      2011 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 金属錯体,発光素子,表示装置2011

    • Inventor(s)
      馬越啓介,金松泰範,石坂昌司,喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Industrial Property Number
      2011-050726
    • Filing Date
      2011-03-08
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 金属錯体,発光素子,表示装置2011

    • Inventor(s)
      馬越啓介,金松泰範
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Industrial Property Number
      2010-179979
    • Filing Date
      2011-08-19
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 金属錯体,発光素子,表示装置2011

    • Inventor(s)
      馬越啓介,東谷阿美,木村和豊,石坂昌司,喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Filing Date
      2011-09-15
    • Related Report
      2011 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] METAL COMPLEX, LIGHT-EMITTING DEVICE AND DISPLAY2011

    • Inventor(s)
      馬越啓介,斉藤慶三,大西正義,石坂昌司,喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Filing Date
      2011-07-05
    • Related Report
      2011 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] METAL COMPLEX, LIGHT-EMITTING DEVICE AND DISPLAY2011

    • Inventor(s)
      馬越啓介,赤津誠二,大西正義,石坂昌司,喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Filing Date
      2011-02-22
    • Related Report
      2011 Final Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 金属錯体,発光素子,表示装置2011

    • Inventor(s)
      馬越啓介, 金松泰範
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Industrial Property Number
      2011-179979
    • Filing Date
      2011-08-19
    • Related Report
      2011 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属錯体,光素子,表示装置2011

    • Inventor(s)
      馬越啓介, 東谷阿美, 木村和豊, 石坂昌司, 喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Filing Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 金属錯体,発光素子,表示装置2011

    • Inventor(s)
      馬越啓介, 金松泰範, 石坂昌司, 喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Industrial Property Number
      2011-050726
    • Filing Date
      2011-03-08
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属錯体,発光素子,表示装置2011

    • Inventor(s)
      馬越啓介, 木村和豊, 東谷阿美, 石坂昌司, 喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Industrial Property Number
      2011-053216
    • Filing Date
      2011-03-10
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属錯体,発光素子,表示装置2010

    • Inventor(s)
      馬越啓介,栗原嵩明,大西正義,石坂昌司,喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学/住友化学株式会社
    • Industrial Property Number
      2010-054999
    • Filing Date
      2010-03-11
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 金属錯体,発光素子,表示装置2010

    • Inventor(s)
      馬越啓介, 木村和豊, 東谷阿美, 石坂昌司, 喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学
    • Industrial Property Number
      2010-211191
    • Filing Date
      2010-09-21
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 金属錯体, 発光素子, 表示装置2010

    • Inventor(s)
      馬越啓介, 栗原嵩明, 大西正義, 石坂昌司, 喜多村昇
    • Industrial Property Rights Holder
      国立大学法人長崎大学, 住友化学株式会社
    • Industrial Property Number
      2010-054999
    • Filing Date
      2010-03-11
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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