Development of heavy transition metal complexes showing new photophysical properties arising from cooperative effects between the transition elements
Project/Area Number |
21550062
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Nagasaki University |
Principal Investigator |
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Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
Keywords | 重遷移金属元素 / 白金 / 11族元素 / 多核錯体 / 発光 / 光物性 / ピラゾール / 混合金属錯体 / 金属間相互作用 |
Research Abstract |
In this study, we have succeeded in the syntheses of luminescent heteropolynuclear complexes containing three transition elements, which exhibit synergetic effect of the three transition elements. Various(diimine) Pt complexes containing 3-t-butylpyrazole reacted with group 11 metal ions to give Z-shaped luminescent heteropolynuclear complexes. We have also succeeded in elucidating the influence of chloride ligands coordinated to Pt atom on the emission energy of heteropolynuclear complexes.
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Report
(4 results)
Research Products
(44 results)
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[Journal Article] Pyrazolato and 3, 5-dimethylpyrazolato bridged dinuclear platinum(II), palladium(II), and their mixed-metal complexes of 2, 2'-bipyrimidine. Syntheses, structures, and luminescent properties2010
Author(s)
K. Umakoshi, K. Kimura, Y. H. Kim, Y. Tsukimoto, Y. Arikawa, M. Onishi, S. Ishizaka, N.
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Journal Title
Kitamura, Bull. Chem. Soc. Jpn
Volume: 83
Pages: 1504-1510
NAID
Related Report
Peer Reviewed
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[Journal Article] Pyrazolato and 3,5-dimethylpyrazolato bridged dinuclear platinum(II), palladium(II), and their mixed-metal complexes of 2,2'-bipyrimidine. Syntheses, structures, and luminescent properties2010
Author(s)
K.Umakoshi, K.Kimura, Y.H.Kim, Y.Tsukimoto, Y.Arikawa, M.Onishi, S.Ishizaka, N.Kitamura
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Journal Title
Bulletin of the Chemical Society of Japan
Volume: 40
Pages: 1504-1510
NAID
Related Report
Peer Reviewed
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[Presentation] Pyrazolate and 3,5-Dimethylpyrazolate Bridged Dinuclear Platinum(II), Palladium(II), and Their Mixed-Metal Complexes of Bipyrimidine. Syntheses, Structures, and Luminescent Properties2010
Author(s)
K.Kimura, K.Umakoshi, Y.H.Kim, Y.Arikawa, M.Onishi, S.Ishazaka, N, Kitamnra
Organizer
Nagasaki Symposium on Nano-Dynamics 2010
Place of Presentation
長崎大学
Year and Date
2010-01-21
Related Report
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[Presentation] Pyrazolate Bridged Dinuclear Platinum(II), Palladium(II), and Their Mixed-metal Complexes of 2,2'-Bipyrimidine. Synthesis, Structures, and Luminescent Properties2010
Author(s)
K.Umakoshi, K.Kimura, Y.H.Kim, Y.Tsukimoto, A.Higashitani, Y.Arikawa, M.Onishi, S.Ishizaka, N. Kitamura
Organizer
60th Anniversary Conference on Coordination Chemistry
Place of Presentation
大阪交流センター
Related Report
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