Synthesis and Function of New Cluster Complexes with Platinum to Metal Dative Bond
| Project/Area Number |
21550072
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Waseda University |
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Principal Investigator |
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| Project Period (FY) |
2009 – 2011
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| Project Status |
Completed (Fiscal Year 2011)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | 金属錯体化学 / クラスター錯体 / 供与型金属-金属間結合 / 白金-金結合 |
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| Research Abstract |
In this study, novel cluster complexes containing platinum to metal dative bond were synthesized. With use of gold(I) ion as an acceptor, new Pt-> Au dimer complexes with platinum to gold dative bond were synthesized and firstly characterized by X-ray crystallography. With use of mercury as an acceptor, novel type of isomer involving type of metal-metal bond, Pt(III)-Hg(0)-Pt(III) and Pt(II)-> Hg(I)-Pt(III) were synthesized.
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Report
(4 results)
Research Products
(6 results)
