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Development of Luminescent Chemosensors Displaying Switching of Analyte-sensitivity

Research Project

Project/Area Number 21550134
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionOkayama University

Principal Investigator

OKAMOTO Hideki  岡山大学, 大学院・自然科学研究科, 准教授 (30204043)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Keywordsセンサー / 蛍光 / 化学発光 / スイッチング / アミノフタルイミド / カルボヒドラジド / イオンペア / 金属イオン / アミノキノリン / アントラセンジカルボキシイミド / フルオロフォア
Research Abstract

Luminescent material displaying a specific response, such as changes in luminescence intensity and color, toward an analyte is useful to detect the analyte(referenced as chemosensor). Most conventional chemosensors respond to one analyte. Thus, when we detect two(or more) analytes, we need to use plural receptors responding to each analyte. In the present study, we have developed intelligent chemosensors which display switching of responses to analytes. By utilizing amide functionalities, which shows amide. amidate equilibrium, analyte sensitivity of luminescent sensors to various ionic species and ion pairs were able to be controlled.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (40 results)

All 2012 2011 2010 2009

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (27 results)

  • [Journal Article] Fluorescence response of 3-trifluoroacetylaminophthalimide to Li+. I. ion pair induced by 254 nm photolysis in acetonitrile2012

    • Author(s)
      Hideki Okamoto, Hiroyuki Konishi, and Kyosuke Satake
    • Journal Title

      Chem. Commun.

      Volume: 48 Pages: 23462-2348

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photochemical synthesis and electronic spectra of fulminene([6] phenacene)2012

    • Author(s)
      Hideki Okamoto, Minoru Yamaji, Shin Gohda, Kaori Sato, Hisako Sugino, and Kyosuke Satake
    • Journal Title

      Res. Chem. Intermed.

      Volume: (in press)

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Studies on interactions of excited cadmium and mercury atoms with secondary and tertiary alkyl-and silylamines in gas phase2012

    • Author(s)
      Shunzo Yamamoto, Eriko Kainaga, Omar Ahmed, Hideki Okamoto, and Yoshimi Sueishi
    • Journal Title

      J. Photochem. Photobiol. A : Chem.

      Volume: 228 Pages: 38-43

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fluorescence response of 3-trifluoroacetylaminophthalimide to Li^+-I^- ion pair induced by 254 nm photolysis in acetonitrile2012

    • Author(s)
      Hideki Okamoto
    • Journal Title

      Chemical Communications

      Volume: 48 Issue: 17 Pages: 2346-2348

    • DOI

      10.1039/c2cc17502a

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Studies on interactions of excited cadmium and mercury atoms with secondary and tertiary alkyl- and silylamines in gas phase2012

    • Author(s)
      Shunzo Yamamoto
    • Journal Title

      Journal of Photochemistry and Photobiology A : Chemistry

      Volume: 228 Issue: 1 Pages: 38-43

    • DOI

      10.1016/j.jphotochem.2011.11.010

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phthalide-derived novel fluoroionophores incorporating picolylamino receptors : Synthesis and response to metal cations2011

    • Author(s)
      Hideki Okamoto, Ayako Matsui, and Kyosuke Satake
    • Journal Title

      Analyst

      Volume: 136 Pages: 3164-3169

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthesis of picene from 1, 2-di(1-naphthyl) ethane by 9-fluorenone-sensitized photolysis2011

    • Author(s)
      Hideki Okamoto, Minoru Yamaji, Shin Gohda, Kaori Sato, Hisako Sugino, and Kyosuke Satake
    • Journal Title

      Org. Lett.

      Volume: 13 Pages: 2758-2761

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile synthesis of picene from 1,2-di(1-naphthyl)ethane by 9-fluorenone-sensitized photolysis2011

    • Author(s)
      Hideki Okamoto
    • Journal Title

      Organic Letters

      Volume: 13 Issue: 10 Pages: 2758-2761

    • DOI

      10.1021/ol200874q

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Linear response of multiphoton reaction : three-photon cycloreversion of anthracene biplanemer in solution by intense femtosecond laser pulses2010

    • Author(s)
      Tomoyuki Yatsuhashi, Yuki Nakahagi, Hideki Okamoto, Nobuaki Nakashima
    • Journal Title

      J.Phys.Chem.A

      Volume: 114 Pages: 10475-10480

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superconductivity in alkali-metal-doped picene2010

    • Author(s)
      Ryoji Mitsuhashi, (他11名)
    • Journal Title

      Nature 464

      Pages: 77-79

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Trap states and transport characteristics in picene thin film field effect transistor2009

    • Author(s)
      Naoko Kawasaki, (他4名)
    • Journal Title

      Appl. Phys. Lett. 94

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High performance C_<60> and picene field -effect transistors with conducting polymer electrodes in bottom contact structure2009

    • Author(s)
      Yumiko Kaj, (他9名)
    • Journal Title

      Organic Electronics 10

      Pages: 432-436

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low voltage operation in picene thin film field effect transistor and its physical characteristics2009

    • Author(s)
      Yumiko Kaji, (他10名)
    • Journal Title

      Appl. Phys. Lett. 95

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 分子内電荷移動型蛍光色素を用いるマルチセンシングプローブの構築(依頼講演)2011

    • Author(s)
      岡本秀毅
    • Organizer
      第5回有機π電子系シンポジウム
    • Place of Presentation
      大阪
    • Related Report
      2011 Final Research Report
  • [Presentation] ジピコリルアミノメチルレセプターを有するアントラセンジカルボヒドラジドの合成および金属イオン種に対する化学発光応答2011

    • Author(s)
      岡本秀毅, 山崎奈緒美, 松井絢子, 佐竹恭介
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Related Report
      2011 Final Research Report
  • [Presentation] Preparation of Anthracenedicarboxylic-acid-derived Fluorescence and Chemiluminescence Probes Incorporating Dipicolylaminomethyl Receptors and Their Luminescence Responses to Metal Cations2011

    • Author(s)
      Hideki Okamoto, Ayako Matsui, Naomi Yamasaki, and Kyosuke Satake
    • Organizer
      XXV^<th> International Conference on Photochemistry
    • Place of Presentation
      Beijing, China
    • Related Report
      2011 Final Research Report
  • [Presentation] ジピコリルアミノレセプターで修飾されたアントラセンジカルボン酸類縁体をルミノフォアとして用いるPETプローブの構築と発光特性2011

    • Author(s)
      岡本秀毅, 松井絢子, 山崎奈緒実, 佐竹恭介
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Related Report
      2011 Final Research Report
  • [Presentation] 分子内電荷移動型蛍光色素を用いるマルチセンシングプローブの構築2011

    • Author(s)
      岡本秀毅
    • Organizer
      第5回有機π電子系シンポジウム
    • Place of Presentation
      ホテルアウィーナ大阪(大阪府)(依頼講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ジピコリルアミノメチルレセプターを有するアントラセンジカルボヒドラジドの合成および金属イオン種に対する化学発光応答2011

    • Author(s)
      岡本秀毅
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎市河畔コンベンションエリア(宮崎県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ベンゼン環上にメチル基を有するジアザ[3.3]パラシクロファン類の合成と光化学反応2011

    • Author(s)
      岡本秀毅
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎市河畔コンベンションエリア(宮崎県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Preparation of Anthracenedicarboxylic-acid-derived Fluorescence and Chemiluminescence Probes Incorporating Dipicolylaminomethyl Receptors and Their Luminescence Responses to Metal Cations2011

    • Author(s)
      Hideki Okamoto
    • Organizer
      XXV^<th> International Conference on Photochemistry
    • Place of Presentation
      Beijing Friendship Hotel (Beijing, China)
    • Related Report
      2011 Annual Research Report
  • [Presentation] ジピコリルアミノレセプターで修飾されたアントラセンジカルボン酸類縁体をルミノフォアとして用いるPETプローブの構築と発光特性2011

    • Author(s)
      岡本秀毅, 松井絢子, 山崎奈緒実, 佐竹恭介
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス(神奈川県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] アミンおよびアルコール存在下でのo-アルキルフェニルナイトレンの反応における温度依存性2011

    • Author(s)
      シティマリヤウルファ, 岡本秀毅, 佐竹恭介
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス(神奈川県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] トリフルオロアセトアミド置換キノリンの蛍光挙動:アミド-アミデート平衡を利用した金属イオン応答スイッチング2010

    • Author(s)
      岡本秀毅, 佐藤温子, 佐竹恭介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本
    • Related Report
      2011 Final Research Report
  • [Presentation] トリフルオロアセトアミド置換キノリン誘導体の亜鉛イオン及び銅イオンに対する蛍光応答性スイッチング2010

    • Author(s)
      岡本秀毅, 佐藤温子, 佐竹恭介
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Related Report
      2011 Final Research Report
  • [Presentation] ジナフチルエタンの光化学反応:芳香族カルボニル化合物存在下での光照射によるピセン骨格生成2010

    • Author(s)
      岡本秀毅, 山路稔, 古村紀子, 久保園芳博, 佐竹恭介
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉大学西千葉キャンパス(千葉県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] トリフルオロアセトアミド置換キノリンの蛍光挙動:アミドーアミデート平衡を利用した金属イオン応答スイッチング2010

    • Author(s)
      岡本秀毅, 佐藤温子, 佐竹恭介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学黒髪南キャンパス(熊本県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] アントラセンジカルボキシイミドフルオロフォアを用いたPETセンサーの合成と発光挙動2010

    • Author(s)
      岡本秀毅, 松井絢子, 山崎奈緒美, 佐竹恭介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学黒髪南キャンパス(熊本県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 2-置換2H-アゼピン誘導体の光および熱反応性2010

    • Author(s)
      安達希美, 岡本秀毅, 佐竹恭介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学黒髪南キャンパス(熊本県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] トロベンゼン誘導体から5-ホルミルペンタジェン酸の簡便合成法の開発2010

    • Author(s)
      菊池恭兵, 岡本秀毅, 佐竹恭介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学黒髪南キャンパス(熊本県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] 3-メチル-3H-アゼピン誘導体の合成および理論計算と核磁気共鳴スペクトルよる配座解析2010

    • Author(s)
      Siti Mariyah Ulfa, 岡本秀毅, 佐竹恭介
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学黒髪南キャンパス(熊本県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] ジナフチルエタンの光増感反応によるピセン骨格生成2010

    • Author(s)
      岡本秀毅, 山路稔, 古村紀子, 久保園芳博, 佐竹恭介
    • Organizer
      第4回有機π電子系シンポジウム
    • Place of Presentation
      シーパル須磨(兵庫県)
    • Related Report
      2010 Annual Research Report
  • [Presentation] トリフルオロアセトアミド置換キノリン誘導体の亜鉛イオン及び銅イオンに対する蛍光応答性スイッチング2010

    • Author(s)
      岡本秀毅, (他2名)
    • Organizer
      日本化学会第90春期年会
    • Place of Presentation
      東大阪
    • Related Report
      2009 Annual Research Report
  • [Presentation] ひかる色素の話2009

    • Author(s)
      岡本秀毅
    • Organizer
      岡山県高等学校教育研究会理科部会総会講演会
    • Place of Presentation
      岡山
    • Year and Date
      2009-05-13
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] トリフルオロアセタミド置換フタルイミドの蛍光挙動:ハロゲン化物イオン及びイオンペアへの光応答2009

    • Author(s)
      岡本秀毅, 小西廣幸, 佐竹恭介
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生
    • Related Report
      2011 Final Research Report
  • [Presentation] Fluorescence behavior of 3-trifluoroacetylamino derivative of phthalimide : Photochemically induced response to Li^+/I^-ion pair2009

    • Author(s)
      Hideki Okamoto, Hiroyuki Konishi, Kyosuke Satake
    • Organizer
      XXIV^<th> International Conference on Photochemistry
    • Place of Presentation
      Toledo, Spain
    • Related Report
      2011 Final Research Report
  • [Presentation] Fluorescence behavior of 3 trifluoroacetylamino derivative of phthalimide : Photochemically induced response to Li+/I- ion pair2009

    • Author(s)
      Hideki Okamoto, (他2名)
    • Organizer
      XXIVth International Conference on Photochemistry
    • Place of Presentation
      Toledo, Spain
    • Related Report
      2009 Annual Research Report
  • [Presentation] トリフルオロアセタミド置換フタルイミドの蛍光挙動 : ハロゲン化物イオン及びイオンペアへの光応答2009

    • Author(s)
      岡本秀毅, (他2名)
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生
    • Related Report
      2009 Annual Research Report
  • [Presentation] フェムト秒レーザーパルスによるアントラセン光二量体の3光子分解反応2009

    • Author(s)
      八ッ橋知幸, (他3名)
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      桐生
    • Related Report
      2009 Annual Research Report
  • [Presentation] [3. 3]パラシクロファンの光化学反応2009

    • Author(s)
      岡本秀毅, (他2名)
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      松山
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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