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New Synthetic Utilization of Carbon Resources Stemmmed from Biomass

Research Project

Project/Area Number 21550147
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionNara Institute of Science and Technology

Principal Investigator

MORIMOTO Tsumoru  奈良先端科学技術大学院大学, 物質創成科学研究科, 准教授 (10324972)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords有機合成 / 触媒反応 / カルボニル化 / 糖 / 糖アルコール / ホルムアルデヒド / 単糖類 / 糖類 / グルコース
Research Abstract

In this study, we have aimed to develop a new synthetic utilization of readily available carbon resources, such as sugars, sugar alcohols, and formaldehyde, which are easily stemmed from biomass. We found that, under transition metal-catalysis, such carbon resources can be used as a carbonyl source in carbonylation reactions.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (54 results)

All 2012 2011 2010 2009 Other

All Journal Article (8 results) (of which Peer Reviewed: 7 results) Presentation (44 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Rh(I)-Catalyzed Asymmetrci Synthesis of 3-Substituted Isoindolinones through CO Gas-Free Aminocarbonylation2012

    • Author(s)
      藤岡正彦, 森本積, 津曲貴幸, 谷本裕樹, 西山靖浩, 垣内喜代三
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 77巻 Pages: 2911-2923

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rh(I)-Catalyzed Cyclocarbonylation of Enynes with Glyceraldehyde : An Available Carbonyl Source Derived from Sugar Alcohols2012

    • Author(s)
      池田圭一, 森本積, 津曲貴幸, 谷本裕樹, 西山靖浩, 垣内喜代三
    • Journal Title

      Synlett

      Volume: 23巻 Pages: 393-396

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Rh(I)-Catalyzed Cyclocarbonylation of Enynes with Glyceraldehyde : An Available Carbonyl Source Derived from Sugar Alcohols2012

    • Author(s)
      池田圭一、森本積、津曲貴幸、谷本裕樹、西山靖浩、垣内喜代三
    • Journal Title

      Synlett

      Volume: 23 Issue: 03 Pages: 393-396

    • DOI

      10.1055/s-0031-1290311

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Utilization of Aldoses as a Carbonyl Source in Cyclocarbonylation of Enynes2010

    • Author(s)
      池田圭一, 森本積, 垣内喜代三
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 75巻 Pages: 6279-6282

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Highly Linear-Selective Hydroformylation of 1-Alkynes Using Formaldehyde as a Syngas Substitute2010

    • Author(s)
      真門剛毅, 森本積, 杉本泰子, 堤健, 加川夏子, 垣内喜代三
    • Journal Title

      Advanced Synthesis and Catalysis

      Volume: 352巻 Pages: 299-304

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Utilization of Aldoses as a Carbonyl Source in Cyclocarbonylation of Enynes2010

    • Author(s)
      T.Morimoto
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 75 Pages: 6279-6282

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Linear-Selective Hydroformylation of 1-Alkenes Using Formaldehyde as a Syngas-Substitute2010

    • Author(s)
      G.Makado
    • Journal Title

      Advanced Synthesis and Catalysis 352

      Pages: 299-304

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Rh(I)-Catalyzed CO Gas-Free Carbonylative Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde2009

    • Author(s)
      森本積, 山崎香枝, 平野暁久, 堤健, 加川夏子, 垣内喜代三, 原田恭行, 福本能也, 茶谷直人, 西岡孝徳
    • Journal Title

      Organic Letters

      Volume: 11巻 Pages: 1777-1780

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] A Novel Transformation of Formaldehyde by Homogeneous Catalysis2011

    • Author(s)
      森本積
    • Organizer
      International Meeting on Novel Catalyst Design and Surface Science
    • Place of Presentation
      姫路
    • Year and Date
      2011-12-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Rh(I)-Catalyzed Stereoselective Hydroformylation Using Formaldehyde2011

    • Author(s)
      森本積, 三好浩太, 真門剛毅, 垣内喜代三
    • Organizer
      International Meeting on Novel Catalyst Design and Surface Science
    • Place of Presentation
      姫路
    • Year and Date
      2011-12-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Rh(I)-Catalyzed Asymmetric Synthesis of 3-Substituted Isoindolinones through CO Gas-Free Aminocarbonylation2011

    • Author(s)
      森本積, 藤岡正彦, 津曲貴幸, 垣内喜代三
    • Organizer
      InternationalSymposium on Catalysis and Fine Chemicals 2011
    • Place of Presentation
      奈良
    • Year and Date
      2011-12-06
    • Related Report
      2011 Final Research Report
  • [Presentation] Rh(I)-Catalyzed Stereoselective Hydroformylation Using Formaldehyde2011

    • Author(s)
      森本積, 三好浩太, 真門剛毅, 垣内喜代三
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2011
    • Place of Presentation
      奈良
    • Year and Date
      2011-12-06
    • Related Report
      2011 Final Research Report
  • [Presentation] 一酸化炭素を用いない新カルボニル化反応2011

    • Author(s)
      森本積
    • Organizer
      第55回香料・テルペンおよび精油化学に関する討論会
    • Place of Presentation
      筑波
    • Year and Date
      2011-11-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 一酸化炭素を用いない新カルボニル化法2011

    • Author(s)
      森本積
    • Organizer
      第55回香料・テルペンおよび精油化学に関する討論会
    • Place of Presentation
      筑波市(招待講演)
    • Year and Date
      2011-11-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] アルデヒド代替アミノカルボニル化反応を基軸とした3位置換イソインドリノンの不斉合成2011

    • Author(s)
      森本積, 藤岡正彦, 津曲貴幸, 垣内喜代三
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-08
    • Related Report
      2011 Final Research Report
  • [Presentation] グリセルアルデヒドをカルボニル源としたエンイン類のロジウム触媒環化カルボニル化反応2011

    • Author(s)
      森本積, 池田圭一, 垣内喜代三
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-08
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム触媒によるホルムアルデヒドを用いたスチレン類の不斉ヒドロホルミル化反応2011

    • Author(s)
      森本積, 三好浩太, 垣内喜代三
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋
    • Year and Date
      2011-09-08
    • Related Report
      2011 Final Research Report
  • [Presentation] Rhodium(I)-Catalyzed Selective Hydroformylation Using Formaldehyde as the Syngas-Substitute2011

    • Author(s)
      森本積
    • Organizer
      14th Asian Chemical Congress(14ACC)
    • Place of Presentation
      バンコク(タイ)
    • Year and Date
      2011-09-07
    • Related Report
      2011 Final Research Report
  • [Presentation] グリセルアルデヒドをカルボニル源としたエンイン類のロジウム触媒環化カルボニル化反応2011

    • Author(s)
      森本積、池田圭一、垣内喜代三
    • Organizer
      第58回有機金属化学討論会
    • Place of Presentation
      名古屋市
    • Year and Date
      2011-09-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] Rh(I)-Catalyzed Selective Hydroformylation Using Formaldehyde2011

    • Author(s)
      森本積
    • Organizer
      Aachen-Osaka Joint Symposium
    • Place of Presentation
      アーヘン(ドイツ)
    • Year and Date
      2011-09-01
    • Related Report
      2011 Final Research Report
  • [Presentation] New Methods for Catalytic Asymmetric Carbonylation Reactions2011

    • Author(s)
      森本積
    • Organizer
      2nd Annual World Congress of Catalytic Asymmetric Synthesis-2011 (WCCAS-2011)
    • Place of Presentation
      中国・北京(招待講演)
    • Year and Date
      2011-08-10
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Methods for Catalytic Asymmetric Carbonylation Reactions2011

    • Author(s)
      森本積
    • Organizer
      2nd Annual World Congress of Catalytic Asymmetric Synthesis-2011
    • Place of Presentation
      北京(中国)
    • Year and Date
      2011-08-09
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム触媒によるホルムアルデヒドを用いたスチレン類の不斉ヒドロホルミル化反応2011

    • Author(s)
      森本積, 三好浩太, 真門剛毅, 垣内喜代三
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム触媒によるグリセルアルデヒドをカルボニル源としたエンイン類の環化カルボニル化2011

    • Author(s)
      森本積, 池田圭一, 津曲貴幸, 垣内喜代三
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム触媒による非一酸化炭素型アミノカルボニル化反応を基軸としたキラルな3位置換イソインドリノン合成法2011

    • Author(s)
      森本積, 津曲貴幸, 藤岡正彦, 垣内喜代三
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      横浜
    • Year and Date
      2011-03-26
    • Related Report
      2011 Final Research Report
  • [Presentation] Highly Regio-and Enantioselective Hydroformylation Using Formaldehyde2010

    • Author(s)
      森本積, 真門剛毅, 垣内喜代三
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイ(米国)
    • Year and Date
      2010-12-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Rhodium(I)-Catalyzed Cyclocarbonylation Reaction of Enynes with Sugars2010

    • Author(s)
      森本積, 池田圭一, 垣内喜代三
    • Organizer
      International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ハワイ(米国)
    • Year and Date
      2010-12-18
    • Related Report
      2011 Final Research Report
  • [Presentation] Highly Regio- and Enantioselective Hydroformylation Using Formaldehyde2010

    • Author(s)
      Tsumoru Morimoto
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (PACIFICHEM 2010)
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] アルデヒドの脱カルボニル化を基軸としたカルボニル化反応2010

    • Author(s)
      森本積
    • Organizer
      第38回オルガノメタリックセミナー
    • Place of Presentation
      吹田
    • Year and Date
      2010-11-22
    • Related Report
      2011 Final Research Report
  • [Presentation] アルデヒドの脱カルボニル化を基軸としたカルボニル化反応2010

    • Author(s)
      森本積
    • Organizer
      第38回オルガノメタリックセミナー
    • Place of Presentation
      大阪大学理工学図書館(大阪府)
    • Year and Date
      2010-11-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] 非一酸化炭素型アミノカルボニル化反応を基軸としたキラルな3-置換イソインドリノンの簡便な合成法の開発2010

    • Author(s)
      森本積, 津曲貴幸, 藤岡正彦, 垣内喜代三
    • Organizer
      第30回有機合成若手セミナー
    • Place of Presentation
      堺
    • Year and Date
      2010-11-10
    • Related Report
      2011 Final Research Report
  • [Presentation] Asymmetric Synthesis of 3-Substituted Isoindolinones via Rh(I)-Catalyzed CO gas-Free Aminocarbonylative Cyclyzation2010

    • Author(s)
      森本積, 藤岡正彦, 津曲貴幸, 垣内喜代三
    • Organizer
      The Sixth International Symposium on Integrated Synthesis
    • Place of Presentation
      神戸
    • Year and Date
      2010-10-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Rhodium-Catalyzed Carbonylative Arylation of Alkynes with Arylboronic Acids Using Formaldehyde2010

    • Author(s)
      森本積, 金城弘幸, 垣内喜代三, Levent Artok
    • Organizer
      The Sixth International Symposium on Integrated Synthesis
    • Place of Presentation
      神戸
    • Year and Date
      2010-10-24
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム錯体によるアルデヒド類の脱カルボニル化を利用した新カルボニル化反応2010

    • Author(s)
      森本積
    • Organizer
      第60回錯体化学討論会シンポジウム「遷移金属錯体を利用する小分子の反応制御」
    • Place of Presentation
      吹田
    • Year and Date
      2010-09-27
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム錯体によるアルデヒド類の脱カルボニル化を利用した新カルボニル化反応2010

    • Author(s)
      森本積
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪国際交流センター(大阪府)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rh(I)-Catalyzed Carbonylation Reactions Using Formaldehyde as the Carbonyla Source2010

    • Author(s)
      森本積
    • Organizer
      China-Japan Joint Symposium on Catalytic Organic Synthesis
    • Place of Presentation
      天津(中国)
    • Year and Date
      2010-09-25
    • Related Report
      2011 Final Research Report
  • [Presentation] Rh(I)-Catalyzed Carbonylation Reactions Using Formaldehyde as the Carbonyl Source2010

    • Author(s)
      Tsumoru Morimoto
    • Organizer
      China-Japan Symposium on Catalytic Organic Synthesis
    • Place of Presentation
      Tianjin, China
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] アルドースをカルボニル源としたエンイン類の環化カルボニル化反応2010

    • Author(s)
      森本積, 池田圭一, 垣内喜代三
    • Organizer
      第27回有機合成化学セミナー
    • Place of Presentation
      神戸
    • Year and Date
      2010-09-03
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム触媒によるアルコールを用いたエンイン類の環化カルボニル化反応2010

    • Author(s)
      森本積, 吉田かりん, 津曲貴幸, 池田圭一, 垣内喜代三
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Year and Date
      2010-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム触媒によるホルムアルデヒドを用いたアルキンとアリールボロン酸とのカルボニル化アリール化反応2010

    • Author(s)
      森本積, 金城弘幸, 垣内喜代三, Levent Artok
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      東大阪
    • Year and Date
      2010-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] Rh(I)-Catalyzed Cyclocarbonylation Reaction of Enynes with Sugars2009

    • Author(s)
      森本積, 池田圭一, 垣内喜代三
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2009
    • Place of Presentation
      ソウル(韓国)
    • Year and Date
      2009-12-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Highly Linear-Selective Syngas-Free Hydroformylation Using Formaldehyde2009

    • Author(s)
      森本積
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2009
    • Place of Presentation
      ソウル(韓国)
    • Year and Date
      2009-12-15
    • Related Report
      2011 Final Research Report
  • [Presentation] Highly Linear-Selective Hydroformylation Using Formaldehyde as the Syngas-Substitute2009

    • Author(s)
      森本積, 真門剛毅, 杉本泰子, 垣内喜代三
    • Organizer
      The Eleventh International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2009-11-13
    • Related Report
      2011 Final Research Report
  • [Presentation] Rh(I)-Catalyzed Cyclocarbonylation Reaction of Enynes with Sugars2009

    • Author(s)
      森本積, 池田圭一
    • Organizer
      The Eleventh International Kyoto Conference on New Aspects of Organic Chemistry
    • Place of Presentation
      京都
    • Year and Date
      2009-11-11
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム触媒による、糖類をカルボニル源としたエンイン類の環化カルボニル化2009

    • Author(s)
      森本積, 池田圭一, 垣内喜代三
    • Organizer
      第53回香料・テルペンおよび精油化学に関する討論会
    • Place of Presentation
      奈良
    • Year and Date
      2009-11-08
    • Related Report
      2011 Final Research Report
  • [Presentation] ロジウム触媒によるグルコースを用いたエンイン類の環化カルボニル化反応2009

    • Author(s)
      森本積, 池田圭一, 垣内喜代三
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      京都
    • Year and Date
      2009-09-11
    • Related Report
      2011 Final Research Report
  • [Presentation] Rh(I)-Catalyzed Carbonylative CO Gas-Free Cyclization Reactions of Alkynes with 2-Bromophenylboronic Acids Using Formaldehyde2009

    • Author(s)
      森本積, 山崎香枝, 平野暁久, 垣内喜代三, 西岡孝徳, 茶谷直人
    • Organizer
      15th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      グラスゴー(スコットランド)
    • Related Report
      2011 Final Research Report
  • [Presentation] Highly Linear-SelectiveHydorofromylation using Formaldehyde as the Substitute for Syngas2009

    • Author(s)
      森本積, 真門剛毅, 杉本泰子, 垣内喜代三
    • Organizer
      15th IUPAC International Symposium on Organometallic Chemistry Directed Towards Organic Synthesis
    • Place of Presentation
      グラスゴー(スコットランド)
    • Related Report
      2011 Final Research Report
  • [Presentation] Rhodium(I)-Catalyzed Carbonylative CO Gas-Free Cyclization of Reactions of Alkynes with 2-Bromoarylboronic Acids Using Formaldehyde2009

    • Author(s)
      T.Morimoto
    • Organizer
      15th IUPAC Symposium on Organometallic Chemistry Directed towards Organic Synthesis (OMCOS 15)
    • Place of Presentation
      Glasgow, UK
    • Related Report
      2009 Annual Research Report
  • [Presentation] Rh(I)-Catalyzed Cyclocarbonylation Reaction of Enynes with Glucose2009

    • Author(s)
      T.Morimoto
    • Organizer
      第56回有機金属化学討論会
    • Place of Presentation
      京都
    • Related Report
      2009 Annual Research Report
  • [Presentation] Rh(I)-Catalyzed Cyclocarbonylation Reaction of Enynes with Sugars2009

    • Author(s)
      T.Morimoto
    • Organizer
      The 11th International Kyoto Conference on New Aspects of Organic Chemistry (IKCOC-11)
    • Place of Presentation
      京都
    • Related Report
      2009 Annual Research Report
  • [Presentation] Highly Linear-Selective Syngas-Free Hydroformylation Using Formaldehyde2009

    • Author(s)
      T.Morimoto
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2009 (C&FC 2009)
    • Place of Presentation
      Seoul, Korea
    • Related Report
      2009 Annual Research Report
  • [Book] 使える!有機合成反応241実践ガイド2010

    • Author(s)
      森本積
    • Publisher
      化学同人
    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://mswebs.naist.jp/LABs/kakiuchi/index-j.html

    • Related Report
      2011 Final Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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