Development of Porous Multi-Component Oxide Nanohybrid Materials Using Assymmetric Organic Linkers

• Project/Area Number: 21550186
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Tokyo University of Agriculture and Technology
• Principal Investigator: MAEDA Kazuyuki 東京農工大学, 大学院・工学研究院, 准教授 (60343159)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2011: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
• Keywords: ナノ材料 / 多孔性材料 / 無機有機ハイブリッド材料 / 多孔体 / ハイブリッド材料

Research Abstract

Inorganic-organic nanohybrid structures, 2D hexagonal in Al system and 2D hexagonal and lamellar in Zr system, by using linker molecules asymmetrically substituted with both phosphonate and siliconate groups. Especially in the lamellar materials the lamellar structure was retained even after the removal of the surfactant differently from any known lamellar mesostructures. All of the materials are found to be composed of multiple oxide domains linked with organic linkers

Research Products

• [Journal Article] Preparation of hybrid ordered inorganic organic mesostructures from an asymmetrically bridged organic precursor containing both silanolate and phosphonate (2010)
  • Author(s): M. Otsu, T. Yamazaki, Y. Sasaki, K. Maeda
  • Journal Title: Chem. Lett. Volume: 39 Pages: 496-497
  • NAID: 10027180557
  • Peer Reviewed
• [Journal Article] Preparation of Hybrid Ordered Inorganic Organic Mesostructures from an Asymmetrically Bridged Organic Precursor Containing Both Silanolate and Phosphonate (2010)
  • Author(s): M.Otsu, T.Yamazaki, Y.Sasaki, K.Maeda
  • Journal Title: Chemistry Letters 39 Pages: 496-497
  • NAID: 10027180557
  • Peer Reviewed
• [Presentation] O_3P-C_6H_4-SiO_3架橋構造を有するジルコニア系多孔性層状ナノ構造体 (2012)
  • Author(s): 小林大記、小黒かく、近藤篤、前田和之
  • Organizer: 日本セラミックス協会2012年年会
  • Place of Presentation: 京都・京都大学吉田キャンパス
  • Year and Date: 2012-03-19
• [Presentation] (OEt)_2OP-C_6H_4-Si(OEt)_3を原料とする無機-有機ハイブリッドメソ構造体の合成 (2010)
  • Author(s): 小林大記、大津理人、近藤篤、前田和之
  • Organizer: ゼオライト学会第26回ゼオライト研究発表会
  • Place of Presentation: 東京・タワーホール船堀
  • Year and Date: 2010-12-03
• [Presentation] Preparation of ordered mesostructures composed of zirconium and O_3P-C_6H_4-SiO_3 units (2010)
  • Author(s): K. Maeda, M. Otsu, T. Yamazaki
  • Organizer: 16th International Zeolite Conference
  • Place of Presentation: イタリア・ソレント
  • Year and Date: 2010-07-09
• [Presentation] Preparation of ordered mesostructures composed of zirconium and O_3P-C_6H_4-SiO_3 units (2010)
  • Author(s): K.Maeda, M.Otsu, T.Yamazaki
  • Organizer: 16^<th> International Zeolite Conference
  • Place of Presentation: イタリア・ソレント
  • Year and Date: 2010-07-09