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Development of photo-excited dielectric relaxation method : selective and quantitative analyses of excitation and relaxation processes of photoactive sites.

Research Project

Project/Area Number 21560037
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionNational Institute for Materials Science

Principal Investigator

ISHII Masashi  独立行政法人物質・材料研究機構, 表界面構造・物性ユニット, 主任研究員 (90281667)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Keywords薄膜・表面界面物性(A)薄膜 / 光物性 / 半導体物性 / 誘電体物性 / 誘電緩和 / 希土類添加 / 電荷移動 / 発光デバイス
Research Abstract

Rare-earth doped semiconductors are one of topical materials for opto-electric devices. I proposed a new analytical technique of luminescence mechanisms of the materials by using an electronic technique, namely, photo excited dielectric relaxation(PEDR). An experimental setup for PEDR was developed. Selective and quantitative analyses of elementary processes for luminescence of Sm doped TiO2 were successfully realized with the setup. Moreover, charge dissipation processes that cause quenching were identified. Interface states of TiO2 microcrystals which induce luminescence and quenching were characterized.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (42 results)

All 2012 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (29 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Effects of oxidization and deoxidization on charge-propagation dynamics in rare-earth-doped titanium dioxide with room-temperature luminescence2012

    • Author(s)
      M. Ishii, B. Towlson, N. Poolton, S. Harako, X. Zhao, S. Komuro, and B. Hamilton
    • Journal Title

      Journal of Applied Physics

      Volume: 111

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Observation of charge transfer process for optical emission of rare-earth dopant using electric probing technique2012

    • Author(s)
      M. Ishii, S. Harako, X. Zhao, S. Komuro, and B. Hamilton
    • Journal Title

      Journal of Luminescence

      Volume: 132 Issue: 12 Pages: 3129-3132

    • DOI

      10.1016/j.jlumin.2011.12.041

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The roles of electrons and holes in luminescence of rare-earth doped semiconductors2012

    • Author(s)
      M.Ishii, B.Towlson, S.Harako, X.Zhao, S.Komuro, B.Hamilton
    • Journal Title

      IEEJ Transactions on Electronics, Information and Systems

      Volume: 132(印刷中)

    • NAID

      210000174588

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of surface dielectric relaxation measurement technique and its application to precise and non-destructive evaluation of oil degraded commercial rubber2012

    • Author(s)
      M.Ishii
    • Journal Title

      Bunseki Kagaku

      Volume: 61(印刷中)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of oxidization and deoxidization on charge-propagation dynamics in rare-earth-doped titanium dioxide with room-temperature luminescence2012

    • Author(s)
      M.Ishii, B.Towlson, N.Poolton, S.Harako, X.Zhao, S.Komuro, B.Hamilton
    • Journal Title

      Journal of Applied Physics

      Volume: 111

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Charge propagation dynamics at trapping centers that induce the luminescence of rare-earth dopants in wide-gap materials2011

    • Author(s)
      M. Ishii, S. Harako, X. Zhao, S. Komuro, and B. Hamilton
    • Journal Title

      Applied Physics Letters

      Volume: 99

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 誘電緩和を用いた高分子表面の動力学分析2011

    • Author(s)
      石井真史
    • Journal Title

      The Electronic Journal Edition of IEEJ Transactions A

      Volume: 131 Pages: 185-191

    • NAID

      10027803205

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface dielectric relaxation : probing technique and its application to thermal activation dynamics of polymer surface2010

    • Author(s)
      M.Ishii
    • Journal Title

      Review of Scientific Instruments

      Volume: 81

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Static states and dynamic behaviour of charges : observation and control by scanning probe microscopy2010

    • Author(s)
      Masashi Ishii
    • Journal Title

      JOURNAL OF PHYSICS-CONDENSED MATTER Vol.22

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Confinement, overflow, and emission of holes on SiGe surface with Gedots : Heterogeneous hole redistribution and its application to virtual dot manipulation2009

    • Author(s)
      Masashi Ishii, Sarnjeet S.Dhesi, Bruce Hamilton
    • Journal Title

      APPLIED PHYSICS LETTERS Vol.91

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Thermal quenching mechanism of Sm doped TiO_2 revealed from charge propagation analyses with electric measurement techniques2012

    • Author(s)
      M. Ishii, S. Harako, X. Zhao, S. Komuro, and B. Hamilton
    • Organizer
      4th International Workshop on Photoluminescence in Rare-earth : Photonic Materials and Devices
    • Place of Presentation
      Kyoto University(京都府)
    • Year and Date
      2012-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] Thermal Quenching mechanism of Sm doped TiO2 revealed from charg propagation analyses with electric measurement techniques2012

    • Author(s)
      M.Ishii, S.Harako, X.Zhao, S.Komuro, B.Hamilton
    • Organizer
      4th International Workshop on Photoluminescence in Rare-earth : Photonic Materials and Devices
    • Place of Presentation
      Kyoto University(京都府)
    • Year and Date
      2012-03-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光励起誘電緩和法(5): TiO_2 : Smの温度消光における電荷の散逸過程2012

    • Author(s)
      石井真史, Brian Towlson,原子進,趙新為,小室修二, Bruce Hamilton
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 光励起誘電緩和法(7):電荷伝搬分析を使ったnc-Si発光におけるEr添加効果の検討2012

    • Author(s)
      石井真史, Iain Crowe, Matthew Halsall, Andrew Knights, Russell Gwilliam, Bruce Hamilton
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光励起誘電緩和法(6):電荷伝搬分析を使ったnc-Si:Erの発光機構の検討2012

    • Author(s)
      石井真史, Iain Crowe, Matthew Halsall, Andrew Knights, Russell Gwilliam, Bruce Hamilton
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光励起誘電緩和法(5):TiO2:Smの温度消光における電荷の散逸過程2012

    • Author(s)
      石井真史, Brian Towlson, 原子進, 趙新為, 小室修二, Bruce Hamilton
    • Organizer
      第59回応用物理学関係連合講演会
    • Place of Presentation
      早稲田大学(東京都)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Charge propagation dynamics in rare-earth doped semiconductors : Photo-excitation, trapping and recombination for dopant luminescence2011

    • Author(s)
      M. Ishii
    • Organizer
      ISSP Special Seminar
    • Place of Presentation
      Latvia University(ラトビア)
    • Year and Date
      2011-10-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Charge propagation dynamics in rare-earth doped semiconductors : Photo-excitation, trapping and recombination for dopant luminescence2011

    • Author(s)
      M.Ishii
    • Organizer
      ISSP Special Seminar
    • Place of Presentation
      Latvia University(ラトビア、リガ)(招待講演)
    • Year and Date
      2011-10-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] Observation of charge transfer process for optical emission of rare-earth dopant by using electric probing technique2011

    • Author(s)
      M. Ishii, S. Harako, X. Zhao, S. Komuro, and B. Hamilton
    • Organizer
      E-MRS 2011 Fall Meeting
    • Place of Presentation
      Warsaw University of Technology(ポーランド)
    • Year and Date
      2011-09-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Observation of charge transfer process for optical emission of rare-earth dopant by using electric probing technique2011

    • Author(s)
      M.Ishii, S.Harako, X.Zhao, S.Komuro, B.Hamilton
    • Organizer
      E-MRS 2011 Fall Meeting
    • Place of Presentation
      Warsaw University of Technology(ポーランド、ワルシャワ)
    • Year and Date
      2011-09-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面誘電緩和法による天然ゴムの油劣化評価2011

    • Author(s)
      石井真史
    • Organizer
      日本ゴム協会2011年年次大会
    • Place of Presentation
      東京理科大学(東京都)
    • Year and Date
      2011-05-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 表面誘電緩和法(2):複素インピーダンスによる表面状態分析と複素誘電率による状態遷移分析2011

    • Author(s)
      石井真史
    • Organizer
      日本レオロジー学会第38年会
    • Place of Presentation
      京都リサーチパーク(京都府)
    • Year and Date
      2011-05-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 希土類添加半導体の電荷伝搬ダイナミクスの光励起誘電緩和法による分析:励起から発光まで2011

    • Author(s)
      石井真史
    • Organizer
      Global COE Seminar
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2011-05-16
    • Related Report
      2011 Final Research Report
  • [Presentation] 希土類添加半導体の電荷伝搬ダイナミクスの光励起誘電緩和法による分析:励起から発光まで2011

    • Author(s)
      石井真史
    • Organizer
      Global COE Seminar
    • Place of Presentation
      大阪大学(大阪府)(招待講演)
    • Year and Date
      2011-05-16
    • Related Report
      2011 Annual Research Report
  • [Presentation] 希土類添加半導体の電荷伝搬・発光過程の光励起誘電緩和法による分析2011

    • Author(s)
      石井真史, 原子進, 趙新為, 小室修二, B.Hamilton
    • Organizer
      第28回希土類討論会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2011-05-12
    • Related Report
      2011 Annual Research Report
  • [Presentation] 光励起誘電緩和法(4):TiO2:Sm2O3中の電荷捕獲によるPL発光増強2011

    • Author(s)
      石井真史, 原子進, 趙新為, 小室修二, ブルースハミルトン
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      (震災のため講演中止(予稿集))
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光励起誘緩和法(3):TiO2:Sm2O3の熱活性化に対応する電荷捕獲位の存在2011

    • Author(s)
      石井真史, 原子進, 趙新為, 小室修二
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      (震災のため講演中止(予稿集))
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 表面誘電緩和法原理・応用例とこれから2011

    • Author(s)
      石井真史
    • Organizer
      材料フォーラムソフトマテリアル分科会
    • Place of Presentation
      産業技術総合研究所(茨城県)
    • Year and Date
      2011-01-14
    • Related Report
      2011 Final Research Report
  • [Presentation] 表面誘電緩和法 原理・応用例とこれから2011

    • Author(s)
      石井真史
    • Organizer
      材料フォーラムソフトマテリアル分科会
    • Place of Presentation
      産業技術総合研究所(茨城県)
    • Year and Date
      2011-01-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Novel nanoscience in the Soft-X-ray region with SR-SPM technique : Strategy for micro-spectroscopy of active nano-structures2010

    • Author(s)
      M.Ishii
    • Organizer
      VERSOX Proposal Workshop
    • Place of Presentation
      Diamond Light Source(英国)
    • Year and Date
      2010-12-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] 表面誘電緩和法:高分子表面の動力学のための誘電緩和測定法の開発2010

    • Author(s)
      石井真史
    • Organizer
      第58回レオロジー討論会
    • Place of Presentation
      仙台国際センター(宮城県)
    • Year and Date
      2010-10-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光励起誘電緩和法(2):紫外光を使ったステップ応答特性と電荷移動過程との相関2010

    • Author(s)
      石井真史, 原子進, 趙新為, 小室修二, ブルースハミルトン
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学(長崎県)
    • Year and Date
      2010-09-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] 光励起誘電緩和法:手法開発とSm2O3添加TiO2への応用2010

    • Author(s)
      石井真史,原子進,趙新為,小室修二
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川県)
    • Year and Date
      2010-03-17
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 時分割EFMによるSiGeドットからの光誘起正孔移動過程の分析:界面捕獲を考慮したシミュレーション解析2010

    • Author(s)
      石井真史, Bruce Hamilton, Sarnjeet S.Dhesi
    • Organizer
      第57回応用物理学関係連合講演会
    • Place of Presentation
      東海大学(神奈川県)
    • Year and Date
      2010-03-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 放射光アシストプローブ顕微鏡:静電容量・静電気力を使った化学マッピングと吸収分光2010

    • Author(s)
      石井真史
    • Organizer
      物性研短期研究会「顕微分光とナノサイエンスの発展」
    • Place of Presentation
      東京大学物性研究所(千葉県)
    • Year and Date
      2010-02-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] 固体最表面の誘電特性の測定2010

    • Author(s)
      石井真史
    • Organizer
      光・量子デバイス研究会先端量子ビームとナノ応用
    • Place of Presentation
      東京工業大学(東京都)
    • Year and Date
      2010-02-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] Photon pumped electric force microscopy of Ge quantum dots2009

    • Author(s)
      Masashi Ishii
    • Organizer
      Photon Probes for Nanoscience
    • Place of Presentation
      University of Manchester(イギリス)
    • Year and Date
      2009-12-08
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 極微構造の元素イメージングのための二光子照射による内殻励起光イオン化制御2009

    • Author(s)
      石井真史, B.Towlson, E.Whittaker, S.S.Dhesi, B.Hamilton
    • Organizer
      Photon Probes for Nanoscience
    • Place of Presentation
      大阪市立大学(大阪府)
    • Year and Date
      2009-11-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] 静電気力プローブ顕微鏡による電荷移動の動的観測:SiGeドット閉込め正孔の光誘起移動2009

    • Author(s)
      石井真史, Sarnjeet S.Dhesi, Bruce Hamilton
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2009-09-08
    • Related Report
      2009 Annual Research Report
  • [Remarks] 石井真史,「光励起-誘電緩和測定法の開発:光活性種の励起・脱励起過程の選択定量分析」報告書(頒布用冊子)

    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 誘電特性の温度依存性測定方法と測定装置2009

    • Inventor(s)
      石井真史
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Industrial Property Number
      2009-268185
    • Filing Date
      2009-11-26
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 試料表面の誘電特性測定方法と測定装置2009

    • Inventor(s)
      石井真史
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Industrial Property Number
      2009-232222
    • Filing Date
      2009-10-06
    • Related Report
      2011 Final Research Report 2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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