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Long-term Deterioration Mechanisms of Hardened Cement Pastes due to High Concentration Alkali Salt Solution in Radioactive Waste Materials and Its Proposal for Mitigation Countermesure

Research Project

Project/Area Number 21560483
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Civil engineering materials/Construction/Construction management
Research InstitutionKanazawa University

Principal Investigator

TORII Kazuyuki  金沢大学, 環境デザイン学系, 教授 (50115250)

Co-Investigator(Kenkyū-buntansha) MIHARA Morihiro  独立行政法人日本原子力研究開発機構, 地層処分研究開発部門, 副主任研究員 (00421652)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords放射性廃棄物 / ASR抑制対策 / ナトリウム塩 / 膨張機構 / ポゾラン材料 / アルカリシリカ反応(ASR) / 膨張発生機構 / 鉱物質混和材 / 拡散セル法 / 偏光顕微鏡観察 / 酢酸ウラニル蛍光法 / EPMA / DSC / 発生機構 / フリーデル氏塩
Research Abstract

In this research, the mechanisms of alkali-silica reaction(ASR) in concrete induced by high concentration solutions of sodium salts were investigated. For this purpose, the expansion behavior of mortar bars immersed in various sodium salts was experimentally compared. In sodium nitrate and sodium sulfate solutions, the process of formation of complex compound hydrates and thereby the rise in the concentration of hydroxide ion was the main reason of ASR. Furthermore, the addition of large amounts of fly ash and blast-furnace slag was very effective in controlling the expansion of mortar bars.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (28 results)

All 2011 2010 2009

All Journal Article (16 results) (of which Peer Reviewed: 16 results) Presentation (10 results) Book (2 results)

  • [Journal Article] The Chloride Ionic Diffusivity of Hardened Low alkaline Pozzolanic Cement2011

    • Author(s)
      Osvaldo, A., Torii, K.
    • Journal Title

      Sympo. on High Performance Concrete

      Volume: (CD-ROM) Pages: 8-8

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Mechanisms of ASR in Concrete Exposed to Deicers and its Preventive Measures by Pozzolans2011

    • Author(s)
      Osvaldo, A., Torii, K.
    • Journal Title

      Conf. on Cement Chemistry

      Volume: (CD-ROM) Pages: 8-8

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Mechanisms of Alkali Silica Reaction in Mortars Immersed in Sodium Sulphate and Phosphate Solutions2011

    • Author(s)
      Osvaldo, A., Nomura, M., Yamato. A., Torii, K.
    • Journal Title

      Proceedings of Japan Concrete Institute

      Volume: Vol.33, No.1 Pages: 1025-1030

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Mechanisms of ASR in Concrete Exposed to Deicers and its Preventive Measures by Pozzolans2011

    • Author(s)
      Osvaldo, A., Torii, K.
    • Journal Title

      Proceedings of 13^<th> Inter.Conf.on Cement Chemistry

      Volume: (CD-R) Pages: 8-8

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Chloride Ionic Diffusivjty of Hardened Low alkaline Pozzolanic Cement2011

    • Author(s)
      Osvaldo, A., Torii, K.
    • Journal Title

      Proceedings of 9^<th> Inter.Sympo.on High Performance Concrete

      Volume: (CD-R) Pages: 8-8

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Cracking of Prestressed and Precast Concrete Members Deteriorated by Alkali-Silica Reaction2011

    • Author(s)
      Torii, K., Minato, T., Nakajima, Y., Yamato, H.
    • Journal Title

      Proceedings of 9^<th> Inter.Sympo.on High Performance Concrete

      Volume: (CD-R) Pages: 8-8

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Mechanisima of Alkali-silica Reaction Induced by Sodium Salts Released from Radioactive WASTE mATERIALS2011

    • Author(s)
      Andrada Osvalda, Kazuyuki Torii
    • Journal Title

      Advances in Concrete Structural Durability

      Pages: 439-448

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Mechanisms of Alkali Silica Reaction Induced by Sodium Salts Released from Radioactive Waste Materials2010

    • Author(s)
      Osvaldo, A., Torii, K.
    • Journal Title

      Conf. on Durability of Concrete Structures

      Pages: 439-448

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 放射性廃棄物からのナトリウム塩によるアルカリシリカ反応の発生機構2010

    • Author(s)
      山戸博晃, 小村知美, アンドラード・オスバルド, 鳥居和之
    • Journal Title

      コンクリート工学年次論文集

      Volume: Vol.32, No.1 Pages: 911-916

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 融氷剤によるコンクリートのASR発生機構とその防止対策2010

    • Author(s)
      小村知美, 山戸博晃, アンドラード・オスバルド, 鳥居和之
    • Journal Title

      コンクリート工学年次論文集

      Volume: Vol.32, No.1 Pages: 905-910

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 放射性廃棄物からのナトリウム塩によるアルカリシリカ反応の発生機構2010

    • Author(s)
      山戸博晃、小村知美、Andrade Osvaldo, 鳥居和之
    • Journal Title

      コンクリート工学年次論文集

      Volume: 32,1 Pages: 911-916

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 融氷剤によるコンクリートのASR発生機構とその防止対策2010

    • Author(s)
      小村知美、山戸博晃、Andrade Osvaldo, 鳥居和之
    • Journal Title

      コンクリート工学年次論文集

      Volume: 32,1 Pages: 905-910

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 高濃度のアルカリ塩によるアルカリシリカ反応の発生機構2010

    • Author(s)
      山戸博晃、劉大丞、小村知美、鳥居和之
    • Journal Title

      セメント・コンクリート論文集 63

      Pages: 393-399

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 放射性廃棄物からのナトリウム塩によるアルカリシリカ反応の発生機構2010

    • Author(s)
      山戸博晃、小村知美、Andrade Osvaldo, 鳥居和之
    • Journal Title

      コンクリート工学年次論文集 32(掲載確定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Sodium and Chloride Ion Diffusivity of Hardened high Volume Pozzolanic Cement Pastes2009

    • Author(s)
      Osvaldo, A., Mihara, M., Torii, K.
    • Journal Title

      Proc. of 4^<th> International Conference on Construction Materials : Performance Innovations and Structural Implications

      Pages: 1088-1095

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Comparison of Cl^-and I^-ion Diffusivity Through Hardened Pozzolanic Cement Pastes2009

    • Author(s)
      Osvaldo, A., Mihara, M., Torii, K.
    • Journal Title

      Proceedings of Japan Concrete Institute

      Volume: Vol.31, No.1 Pages: 217-212

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] The Severely Damaged ASR-affected Bridge Piers and its Countermeasures in Japan2011

    • Author(s)
      K.Torii
    • Organizer
      Annual Conference of Thailand Concrete Institute
    • Place of Presentation
      Thailand, Bangkok(招待講演)
    • Year and Date
      2011-10-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] The Chloride Ionic Diffusivity of Hardened Low alkaline Pozzolanic Cement, 9^<th> Inter2011

    • Author(s)
      Osvaldo, A., Torii, K.
    • Organizer
      Sympo. on High Performance Concrete
    • Place of Presentation
      Ratorua Energy Congress Center, New Zealand
    • Year and Date
      2011-08-17
    • Related Report
      2011 Final Research Report
  • [Presentation] The Mechanisms of Alkali Silica Reaction in Mortars Immersed in Sodium Sulphate and Phosphate Solutions2011

    • Author(s)
      Osvaldo, A., Nomura, M., Yamato. A., Torii, K.
    • Organizer
      JCI年次大会
    • Place of Presentation
      大阪国際会議場,大阪府
    • Year and Date
      2011-07-14
    • Related Report
      2011 Final Research Report
  • [Presentation] The Mechanisms of ASR in Concrete Exposed to Deicers and its Preventive Measures by Pozzolans, 13^<th> Inter2011

    • Author(s)
      Osvaldo, A., Torii, K.
    • Organizer
      Conf. on Cement Chemistry
    • Place of Presentation
      Madrid International Congress Center, Spain
    • Year and Date
      2011-07-05
    • Related Report
      2011 Final Research Report
  • [Presentation] The Mechanisms of Alkali Silica Reaction Induced by Sodium Salts Released from Radioactive Waste Materials, 2^<nd> Inter2010

    • Author(s)
      Osvaldo, A., Torii, K.
    • Organizer
      Conf. on Durability of Concrete Structures
    • Place of Presentation
      Hokkaido University Congress Center, Hokkaido
    • Year and Date
      2010-11-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 融氷剤によるコンクリートのASR発生機構とその防止対策2010

    • Author(s)
      小村知美,山戸博晃,アンドラード・オスバルド,鳥居和之
    • Organizer
      JCI年次大会
    • Place of Presentation
      大宮ソニックシティ,埼玉県
    • Year and Date
      2010-07-09
    • Related Report
      2011 Final Research Report
  • [Presentation] 放射性廃棄物からのナトリウム塩によるアルカリシリカ反応の発生機構2010

    • Author(s)
      山戸博晃,小村知美,アンドラード・オスバルド,鳥居和之
    • Organizer
      JCI年次大会
    • Place of Presentation
      大宮ソニックシティ,埼玉県
    • Year and Date
      2010-07-09
    • Related Report
      2011 Final Research Report
  • [Presentation] The Mechanisms of Brittle Fracture of Steel Bar due to Excessive ASR Expansion of Concrete2009

    • Author(s)
      Kazuyuki Torii
    • Organizer
      International Conference on CONMAT'09
    • Place of Presentation
      名古屋白鳥国際会議場(愛知県)
    • Year and Date
      2009-08-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] The Sodium and Chloride Ion Diffusivity ofHardened high Volume Pozzolanic Cement Pastes2009

    • Author(s)
      Osvaldo, A., Mihara, M., Torii, K.
    • Organizer
      4^<th> International Conference on Construction Materials : Performance Innovations and Structural Implications
    • Place of Presentation
      Shiratori International Congress Center, Aichi
    • Year and Date
      2009-08-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Comparison of Cl^-and I^-ion Diffusivity Through Hardened Pozzolanic Cement Pastes2009

    • Author(s)
      Osvaldo, A., Mihara, M., Torii, K.
    • Organizer
      JCI年次大会
    • Place of Presentation
      札幌コンベンションセンター,北海道
    • Year and Date
      2009-07-10
    • Related Report
      2011 Final Research Report
  • [Book] コンクリートの補修・補強ハンドブック2011

    • Author(s)
      鳥居和之,宮川豊章, 他
    • Publisher
      朝倉書店
    • Related Report
      2011 Final Research Report
  • [Book] コンクリートの補修・補強ハンドブック2011

    • Author(s)
      鳥居和之, 他多数
    • Total Pages
      625
    • Publisher
      朝倉書店
    • Related Report
      2011 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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