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Synthesis, Morphology, and Application of New Compound with Srilankite-like Structure and Solid Solution Nanoparticles

Research Project

Project/Area Number 21560703
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionAichi Institute of Technology

Principal Investigator

HIRANO Masanori  愛知工業大学, 工学部, 教授 (60267888)

Co-Investigator(Kenkyū-buntansha) KOBAYASHI Yuichi  愛知工業大学, 工学部, 教授 (40234851)
HATTORI Tadashi  愛知工業大学, 工学部, 教授 (50023172)
Co-Investigator(Renkei-kenkyūsha) YOSIDA Toshio  名古屋大学, 工学研究科, 准教授 (80273267)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords水熱合成 / スリランカイト / チタニア / 固溶体 / 光触媒 / アナターゼ / ルチル / ニオブ / スカンジウム / 相安定性
Research Abstract

T he effect of processing parameters, e. g. hydrothermal treatment temperature, pH of the solution, and precursor materials on the formation, properties, and morphology of metastable and new nano-sized compounds such as srilankite-like(α-PbO_2 related), anatase-type, and rutile-type structure was investigated using hydrothermal synthesis techniques. The phase stability, structure, and characteristics of their new and metastable compounds were estimated. The applications of their nanostructured materials to the functional materials, e. g. photocatalyst and photoluminescent materials were also investigated.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (55 results)

All 2012 2011 2010 2009

All Journal Article (27 results) (of which Peer Reviewed: 22 results) Presentation (28 results)

  • [Journal Article] Effect of Co-Dopant on the Formation and Properties of Anatase-Type Titania Solid Solutions Doped with Niobium2011

    • Author(s)
      M. Hirano and T. Ito
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 72 Pages: 661-666

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis of Yttrium and Niobium Co-Doped Anatase-Type Titania Nanoparticles2011

    • Author(s)
      M. Hirano and S. Sato
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 119 Pages: 464-469

    • NAID

      130000784612

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis and Properties of Solid Solutions and Composite Nanoparticles in the TiO_2-SnO_2 System2011

    • Author(s)
      M. Hirano, H. Dozono, and T. Kono
    • Journal Title

      Materials Research Bulletin

      Volume: 46 Pages: 1384-1390

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation and Characteristics of Anatase-Type Titania Solid Solution Nanoparticles Doped with Nb^<5+> and M(M=Ga^<3+>, Al^<3+>, Sc^<3+>)2011

    • Author(s)
      M. Hirano and T. Ito
    • Journal Title

      IOP Conference Series : Materials Science and Engineering

      Volume: Vol.18 Pages: 062010-4

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Rutile-Type TiO_2-SnO_2 Solid Solution Nanoparticles by "Forced Co-Hydrolysis" under Hydrothermal Conditions2011

    • Author(s)
      M. Hirano and T. Kono
    • Journal Title

      IOP Conference Series : Materials Science and Engineering

      Volume: Vol.18 Pages: 062015-4

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis of Rutile-Type Complete Solid Solution Nanoparticles in the TiO_2-SnO_2 System under Acidic Conditions2011

    • Author(s)
      M. Hirano and T. Kono
    • Journal Title

      Journal of the American Ceramic Society

      Volume: 94 Pages: 3319-3326

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation and Characteristics of Anatase-Type Titania Solid Solution Nanoparticles Doped with Nb^<5+> and M (M-Ga^<3+>, Al^<3+>, Sc^<3+>)2011

    • Author(s)
      M.Hirano, T.Ito
    • Journal Title

      IOP Conference Series : Materials Science and Engineerins

      Volume: 18 Issue: 6 Pages: 062010-062010

    • DOI

      10.1088/1757-899x/18/6/062010

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Rutile-Type TiO_2-SnO_2 Solid Solution Nanoparticles by "Forced Co-Hydrolysis" under Hydrothermal Conditions2011

    • Author(s)
      M.Hirano, T.Kono
    • Journal Title

      IOP Conference Series : Materials Science and Engineering

      Volume: 18 Issue: 6 Pages: 062015-062015

    • DOI

      10.1088/1757-899x/18/6/062015

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anatase-Type T_<i1-2X> Nb_XAl_XO_2 Solid Solution/Silica(SiO_2) Composite Nanoparticles : Synthesis, Phase Stability, and Photocatalytic Performance2010

    • Author(s)
      M. Hirano and N. Kuno
    • Journal Title

      Materials Science Forum

      Volume: 654-656 Pages: 2735-3738

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Properties of Titania/Silica Composite Nanoparticles and Gels2010

    • Author(s)
      M. Hirano, K. Ota, and S. Oya
    • Journal Title

      Ceramic Transactions

      Volume: 219 Pages: 99-104

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Titania Solid Solution Nanoparticles Co-Doped with Niobium and Gallium2010

    • Author(s)
      M. Hirano and T. Ito
    • Journal Title

      Journal of the Ceramic Society of Japan

      Volume: 118 Pages: 1170-1175

    • NAID

      130000420810

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] アナターゼ型チタニア固溶体ナノ粒子の性質に及ぼす調製条件の影響2010

    • Author(s)
      平野正典, 久野規雄
    • Journal Title

      愛知工業大学総合技術研究所報告

      Volume: 12 Pages: 53-55

    • NAID

      40017292694

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Journal Article] Anatase-Type Ti_<1-2X>Nb_XAl_XO_2 Solid Solution/Silica (SiO_2) Composite Nanoparticles : Synthesis, Phase Stability, and Photocatalytic Performance2010

    • Author(s)
      M.Hirano, N.Kuno
    • Journal Title

      Mater.Sci.Forum

      Volume: 654-656 Pages: 2735-2738

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Properties of Titania/Silica Composite Nanoparticles and Gels2010

    • Author(s)
      M.Hirano, K.Ota, S.Oya
    • Journal Title

      Ceram.Trans

      Volume: 219 Pages: 99-104

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Titania Solid Solution Nanoparticles Co-Doped with Niobium and Gallium2010

    • Author(s)
      M.Hirano, T.Ito
    • Journal Title

      J.Ceram.Soc.Japan

      Volume: 118 Pages: 1170-1175

    • NAID

      130000420810

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] New compound ScTiNbO_6 synthesized via phase transformation from anatase to srilankite-like structure2009

    • Author(s)
      M. Hirano and T. Ito
    • Journal Title

      Materials Letters

      Volume: 163 Pages: 1508-1510

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Anatase Nanoparticles with Extremely Wide Solid Solution Range and ScTiNbO_6 with a-PbO_2 Structure2009

    • Author(s)
      M. Hirano and T. Ito
    • Journal Title

      Journal of Solid State Chemistry

      Volume: 182 Pages: 1581-1586

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phase Transformation and Precipitation Behavior of Niobium Component out of Niobium-Doped Anatase-Type TiO_2 Nanoparticles Synthesized via Hydrothermal Crystallization2009

    • Author(s)
      M. Hirano and Y. Ichihashi
    • Journal Title

      Journal of Materials Science

      Volume: 44 Pages: 6135-6143

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis of Anatase-type Solid Solution/Silica Composite Nanoparticles2009

    • Author(s)
      Journal of Materials Science
    • Journal Title

      Journal of the Australian Ceramic Society

      Volume: 45 Pages: 13-18

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 水溶液プロセスの特徴と応用展開2009

    • Author(s)
      平野正典
    • Journal Title

      セラミックス

      Volume: 43 Pages: 598-601

    • NAID

      10026239781

    • Related Report
      2011 Final Research Report
  • [Journal Article] Hydrothermal Synthesis of Anatase-type ScTiNbO_6 Nanoparticles2009

    • Author(s)
      M. Hirano and T. Ito
    • Journal Title

      愛知工業大学総合技術研究所報告

      Volume: 11 Pages: 51-54

    • Related Report
      2011 Final Research Report
  • [Journal Article] New compound ScTiNbO_6 synthesized via phase transformation from anatase to srilankite-like structure2009

    • Author(s)
      M.Hirano, T.Ito
    • Journal Title

      Mater.Lett. 163

      Pages: 1508-1510

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Anatase Nanoparticles with Extremely Wide Solid Solution Range and ScTiNbO_6 with α-PbO_2 Structure2009

    • Author(s)
      M.Hirano, T.Ito
    • Journal Title

      J.Solid State Chem. 182

      Pages: 1581-1586

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase Transformation and Precipitation Behavior of Niobium Component out of Niobium-Doped Anatase-Type TiO_2 Nanoparticles Synthesized via Hydrothermal Crystallization2009

    • Author(s)
      M.Hirano, Y.Ichihashi
    • Journal Title

      J.Mater.Sci. 44

      Pages: 6135-6143

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrothermal Synthesis of Anatase-type Solid Solution/Silica Composite Nanoparticles2009

    • Author(s)
      M.Hirano, M.Kozawa
    • Journal Title

      J.Aust.Ceram.Soc. 45

      Pages: 13-18

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 水溶液プロセスの特徴と応用展開2009

    • Author(s)
      平野正典
    • Journal Title

      セラミックス 43

      Pages: 598-601

    • NAID

      10026239781

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Hydrothermal Synthesis of Anatase-type ScTiNbO_6 Nanoparticles2009

    • Author(s)
      M.Hirano, T.Ito
    • Journal Title

      愛知工業大学総合技術研究所報告 11

      Pages: 51-54

    • Related Report
      2009 Annual Research Report
  • [Presentation] アナクーゼ型チタニア固溶体微粒子の水熱合成とその性質2012

    • Author(s)
      平野正典, 佐藤信吾
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都
    • Year and Date
      2012-03-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] アナターゼ型チタニア固溶体微粒子の水熱合成とその性質2012

    • Author(s)
      平野正典, 佐藤信吾
    • Organizer
      日本セラミックス協会2012年年会
    • Place of Presentation
      京都
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of Composite Nanoparticles in the TiO_2-SnO_2 System under Hydrothermal Conditions2011

    • Author(s)
      M. Hirano and T. Kono
    • Organizer
      18^<th> International Conference of Composite Materials
    • Place of Presentation
      Jeju Island, Korea
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 加水分解による酸化チタン-酸化スズ系微粒子の調製2011

    • Author(s)
      平野正典, 河野健
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      札幌
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 水熱法による酸化チタン-酸化スズ系微粒子の調製2011

    • Author(s)
      平野正典, 堂園隼人, 河野健
    • Organizer
      日本セラミックス協会第24回秋季シンポジウム
    • Place of Presentation
      札幌
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 水熱法によるCeO_2-TiO_2系微粒子の合成と性質2011

    • Author(s)
      市橋弘樹, 平野正典
    • Organizer
      平成23年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 水熱法によるスピネル型固溶体微粒子の合成2011

    • Author(s)
      布目佑介, 平野正典
    • Organizer
      平成23年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 水熱法によるニオブ含有複酸化物系微粒子の調製2011

    • Author(s)
      堂園隼人, 平野正典
    • Organizer
      平成23年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Anatase-Type Ti_<1-2X> Nb_XAl_XO_2 Solid Solution/Silica(SiO_2) Composite Nanoparticles : Synthesis, Phase Stability, and Photocatalytic Performance2010

    • Author(s)
      M. Hirano and N. Kuno
    • Organizer
      The 7th Pacific Rim
    • Place of Presentation
      Cairns, Australia
    • Related Report
      2011 Final Research Report
  • [Presentation] Formation and Characteristics of Anatase-Type Titania Solid Solution Nanoparticles Doped with Nb^<5+> and M(M=Ga^<3+>, Al^<3+>, Sc^<3+>)2010

    • Author(s)
      M. Hirano and T. Ito
    • Organizer
      3^<rd> International Congress on Ceramics
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] Applicability Test of Neural Network to Analysis of Factors Controlling Catalytic Activity by Using Model Data2010

    • Author(s)
      M. Hirano and T. Kono
    • Organizer
      3^<rd> International Congress on Ceramics
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] 遷移元素を含むチタニア微粒子の水熱合成2010

    • Author(s)
      佐藤信吾, 平野正典
    • Organizer
      平成22年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2011 Final Research Report
  • [Presentation] CeO_2-TiO_2系微粒子の水熱合成と性質2010

    • Author(s)
      市橋弘樹, 平野正典
    • Organizer
      平成22年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2011 Final Research Report
  • [Presentation] Anatase-Type Ti_<1-2X>Nb_XAl_XO_2 Solid Solution/Silica (SiO_2) Composite Nanoparticles : Synthesis, Phase Stability, and Photocatalytic Performance2010

    • Author(s)
      M.Hirano, N.Kuno
    • Organizer
      The 7th Pacific Rim International Conference on Advanced Materials and Processing
    • Place of Presentation
      Cairns, Australia
    • Related Report
      2010 Annual Research Report
  • [Presentation] Formation and Charactedstics of Anatase-Type Titania Solid Solution Nanoparticles Doped with Nb^<5+> and M (M=Ga^<3+>, Al^<3+>, Sc^<3+>)2010

    • Author(s)
      M.Hirano, T.Ito
    • Organizer
      3^<rd> International Congress on Ceramics
    • Place of Presentation
      Osaka, Japa
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis of Rutile-Type TiO_2-SnO_2 Solid Solution Nanoparticles by "Forced Co-Hydrolysis" under Hydrothermal Conditions2010

    • Author(s)
      M.Hirano, T.Kono
    • Organizer
      3^<rd> International Congress on Ceramics
    • Place of Presentation
      Osaka, Japa
    • Related Report
      2010 Annual Research Report
  • [Presentation] 遷移元素を含むチタニア微粒子の水熱合成2010

    • Author(s)
      佐藤信吾, 平野正典
    • Organizer
      平成22年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋市
    • Related Report
      2010 Annual Research Report
  • [Presentation] CeO_2-TiO_2系微粒子の水熱合成と性質2010

    • Author(s)
      市橋弘樹, 平野正典
    • Organizer
      平成22年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋市
    • Related Report
      2010 Annual Research Report
  • [Presentation] New Anatase-Type Solid Solution/Silica Composite Nanoparticles2009

    • Author(s)
      M. Hirano and M. Kozawa
    • Organizer
      The International Conference and Exhibition on Materials and AustCeram 2009(MA2009)
    • Place of Presentation
      Gold Coast, Australia
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Characteristics of Titania/Silica Composite Nanoparticles and Gels2009

    • Author(s)
      M. Hirano K. Ota, and S. Oya
    • Organizer
      The Third International Conference on the Characterization and Control of Interfaces for High Quality Advanced Materials, and Joining Technology for New Metallic Glasses and Inorganic Materials(ICCCI 2009)
    • Place of Presentation
      Kurashiki, Japan
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 広範な固溶領域をもつアナターゼ型ナノ粒子の調製2009

    • Author(s)
      平野正典, 伊藤貴晴
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      松山
    • Related Report
      2011 Final Research Report
  • [Presentation] Ti_2-SnO_2系固溶体ナノ粒子の水熱合成2009

    • Author(s)
      平野正典, 河野健
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      松山
    • Related Report
      2011 Final Research Report
  • [Presentation] NbとAlを固溶したチタニア微粒子の調製2009

    • Author(s)
      久野規雄, 平野正典
    • Organizer
      平成21年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe_2O_3-TiO_2-Nb_2O_5系微粒子の水熱合成2009

    • Author(s)
      佐藤信吾, 平野正典
    • Organizer
      平成21年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋
    • Related Report
      2011 Final Research Report
  • [Presentation] 広範な固溶領域をもつアナターゼ型ナノ粒子の調製2009

    • Author(s)
      平野正典, 伊藤貴晴
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      松山市
    • Related Report
      2009 Annual Research Report
  • [Presentation] TiO_2-SnO_2系固溶体ナノ粒子の水熱合成2009

    • Author(s)
      平野正典, 河野健
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      松山市
    • Related Report
      2009 Annual Research Report
  • [Presentation] NbとAlを固溶したチタニア微粒子の調製2009

    • Author(s)
      久野規雄, 平野正典
    • Organizer
      平成21年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋市
    • Related Report
      2009 Annual Research Report
  • [Presentation] Fe2O_3-TiO_2-Nb_2O_5系微粒子の水熱合成2009

    • Author(s)
      佐藤信吾, 平野正典
    • Organizer
      平成21年度日本セラミックス協会東海支部学術研究発表会
    • Place of Presentation
      名古屋市
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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