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Preparation of high nitrogen hard duplex steel with nanometer grain size and its thermal stability

Research Project

Project/Area Number 21560739
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Material processing/treatments
Research InstitutionUniversity of Tsukuba

Principal Investigator

KOYANO Tamotsu  筑波大学, 数理物質系, 講師 (00215419)

Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords熱処理 / 窒化 / 高窒素 / オーステナイト / 二相鋼 / 丸棒 / ボイド
Research Abstract

A new technique for surface treatment of steel is studied, where soft high nitrogen austenite layer is initially formed and is decomposed into a mixture of equilibrium phases, i. e. α-Fe and γ'-Fe_4N, by low temperature aging. Because of the small grain size of several dozens of nanometers, the surface layer becomes as hard as martensite steel. It was found that nitrogen atoms taken up from nitriding atmosphere recombine at internal grain boundaries and turn out to be nitrogen gas bubbles, which embrittle the surface layer. With proper nitriding condition and improvement of quenching technique, the surface layer of 130 μm in thickness and as hard as 900 Hv was formed on a mild steel bar with a size of φ10mm x 100mm. Four patent proposals were submitted.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (23 results)

All 2011 2010 2009

All Journal Article (9 results) (of which Peer Reviewed: 3 results) Presentation (10 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] SS400丸棒表面の高窒素オーステナイト層生成と低温時効2011

    • Author(s)
      古谷野有, 土山聡宏, 高木節雄, 大森靖浩
    • Journal Title

      日本鉄鋼協会講演論文集

      Volume: 24巻 Pages: 1018-1018

    • Related Report
      2011 Final Research Report
  • [Journal Article] Fe-N二元系オーステナイトの恒温変態組織に及ぼす変態温度の影響2011

    • Author(s)
      福澤範英, 中田伸生, 土山聡宏, 高木節雄, 古谷野有, 大森靖浩
    • Journal Title

      日本鉄鋼協会講演論文集

      Volume: 24巻 Pages: 1017-1017

    • Related Report
      2011 Final Research Report
  • [Journal Article] Anormalous temperature dependence of the superelastic behaviour of Ti-Nb-Mo alloys2011

    • Author(s)
      Al-Zain Yazan, H. Y. Kim, T. Koyano, H. Hosoda, T. H Nam, S. Miyazaki
    • Journal Title

      Acta Materiarlia

      Volume: 59 Issue: 4 Pages: 1464-1473

    • DOI

      10.1016/j.actamat.2010.11.008

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fe-N二元系オーステナイトの恒温変態組織に及ぼす変態温度の影響2011

    • Author(s)
      福澤範英, 他5名
    • Journal Title

      日本鉄鋼協会講演論文集

      Volume: 24 Pages: 1017-1017

    • Related Report
      2011 Annual Research Report
  • [Journal Article] SS400丸棒表面の高窒素オーステナイト層生成と低温時効2011

    • Author(s)
      古谷野有, 他3名
    • Journal Title

      日本鉄鋼協会講演論文集

      Volume: 24 Pages: 1018-1018

    • Related Report
      2011 Annual Research Report
  • [Journal Article] 高窒素オーステナイトの473K等温時効2010

    • Author(s)
      古谷野有, 川野祐輔, 土山聡宏, 高木節雄
    • Journal Title

      日本鉄鋼協会講演論文集

      Volume: 23巻 Pages: 317-317

    • Related Report
      2011 Final Research Report
  • [Journal Article] 高窒素オーステナイトの473K等温時効2010

    • Author(s)
      古谷野有, 他3名
    • Journal Title

      日本鉄鋼協会講演論文集

      Volume: 23 Pages: 317-317

    • Related Report
      2010 Annual Research Report
  • [Journal Article] Comprehensive studies for the crystal strucutres and electronice properties of the superconducting system Fe_<1+δ>Se_<1-x>Te_x with δ≒0.037 and x≒0.552010

    • Author(s)
      M.Onoda, 他3名
    • Journal Title

      J.Phys. : Condens.Matter

      Volume: 22 Pages: 505702-505702

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fe-N合金ラスマルテンサイトの組織と結晶学2009

    • Author(s)
      森戸茂一、岩見祐貴、古谷野有、大庭卓也
    • Journal Title

      熱処理

      Volume: 49巻 Pages: 89-90

    • NAID

      10025193530

    • URL

      http://wwwsoc.nii.ac.jp/jsht/journal/img/allcont.pdf

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] SS400丸棒表面の高窒素オーステナイト層生成と低温時効2011

    • Author(s)
      古谷野有, 土山聡宏, 高木節雄, 大森靖浩
    • Organizer
      日本鉄鋼協会第162回秋期講演大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe-N二元系オーステナイトの恒温変態組織に及ぼす変態温度の影響2011

    • Author(s)
      福澤範英, 中田伸生, 土山聡宏, 高木節雄, 古谷野有, 大森靖浩
    • Organizer
      日本鉄鋼協会第162回秋期講演大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2011-09-21
    • Related Report
      2011 Final Research Report
  • [Presentation] Fe-N二元系オーステナイトの恒温変態組織に及ぼす変態温度の影響2011

    • Author(s)
      福澤範英, 他5名
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] SS400丸棒表面の高窒素オーステチイト層生成と低温時効2011

    • Author(s)
      古谷野有, 他3名
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] Isothermal martensitic transformation of binary nitrogen austenite2011

    • Author(s)
      T. Koyano
    • Organizer
      International conference on martensitic transformations
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2011-09-06
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 高窒素オーステナイトの473K等温時効2011

    • Author(s)
      古谷野有, 川野祐輔, 土山聡宏, 高木節雄
    • Organizer
      日本鉄鋼協会第159回春期講演大会
    • Place of Presentation
      筑波大学
    • Year and Date
      2011-03-28
    • Related Report
      2011 Final Research Report
  • [Presentation] 高窒素オーステナイトの等温マルテンサイト変態2010

    • Author(s)
      古谷野有
    • Organizer
      日本金属学会秋期大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-27
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Cu-Al-Mn合金の極低温環境下におけるマルテンサイト変態2010

    • Author(s)
      井誠一郎, 他2名
    • Organizer
      日本金属学会秋期大会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Temperature Dependence of the Shape Memory Properties of Ti-Nb-Mo Alloys2010

    • Author(s)
      Al-Zain Yazan
    • Organizer
      日本金属学会
    • Place of Presentation
      筑波大学
    • Year and Date
      2010-03-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高窒素オーステナイトの473K等温時効2010

    • Author(s)
      古谷野有
    • Organizer
      日本鉄鋼協会
    • Place of Presentation
      筑波大学
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 鉄系材料およびその製造方法2011

    • Inventor(s)
      大森靖浩, 他3名
    • Industrial Property Rights Holder
      JFEスチール(株)、筑波大学
    • Industrial Property Number
      2011-184124
    • Filing Date
      2011-08-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Patent(Industrial Property Rights)] 鉄系材料の製造方法2011

    • Inventor(s)
      大森靖浩, 他3名
    • Industrial Property Rights Holder
      JFEスチール(株)、筑波大学
    • Industrial Property Number
      2011-184110
    • Filing Date
      2011-08-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Patent(Industrial Property Rights)] 鉄系材料およびその製造方法2011

    • Inventor(s)
      大森靖浩, 他3名
    • Industrial Property Rights Holder
      JFEスチール(株)、筑波大学
    • Industrial Property Number
      2011-085464
    • Filing Date
      2011-04-07
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Patent(Industrial Property Rights)] 鉄系材料およびその製造方法2010

    • Inventor(s)
      岩本隆, 他3名
    • Industrial Property Rights Holder
      JFEスチール(株)、筑波大学
    • Industrial Property Number
      2010-117429
    • Filing Date
      2010-05-21
    • Related Report
      2011 Final Research Report 2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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