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The next-generation lead acid battery using a composite of nano-particles from hydrolysis and a conductive polymer

Research Project

Project/Area Number 21560768
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionAkita University

Principal Investigator

TAGUCHI Masami  秋田大学, 大学院・工学資源学研究科, 教授 (90143073)

Co-Investigator(Kenkyū-buntansha) TADA Eiji  秋田大学, 大学院・工学資源学研究科, 准教授 (40302260)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords各種製造プロセス / 鉛蓄電池 / 二酸化鉛 / ナノ粒子 / 二次電池 / 導電性ポリマー / コンポジット電極
Research Abstract

A series of PbO_2 nanoparticles prepared by hydrolysis of lead acetate in various mixtures of water and alcohol were characterized, and the properties of the novel lead acid battery using the nanoparticles as the active materials for positive electrode were examined by discharge-charge cycling. All the nanoparticles, which were identified as β-PbO_2 single phase, ranged from about 9 to 13 nm in diameter. In comparison with the PbO_2 powder prepared by the conventional method in lead acid battery industry, namely the electrolytic oxidation of lead powder, the PbO_2 nanoparticles had remarkably high performance in both utilization of the active materials for positive electrode and the current efficiency during discharge-charge cycling

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (26 results)

All 2012 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 3 results) Presentation (11 results) Remarks (2 results) Patent(Industrial Property Rights) (3 results)

  • [Journal Article] 水素還元されたPt Oxide Blackのメタノール酸化特性2012

    • Author(s)
      田口正美, 川端泰弘, 小坂勇樹
    • Journal Title

      J. MMIJ

      Volume: Vol.128,No.1 Pages: 40-46

    • NAID

      10030172289

    • Related Report
      2011 Final Research Report
  • [Journal Article] Methanol Oxidation Activity of Pt Oxide Black Treated by Electrochemical Reduction2012

    • Author(s)
      Masami Taguchi, Yasuhiro Kawahashi, Yuuki Kosaka
    • Journal Title

      Int. J. Soc. Mater. Eng. Resor

      Volume: Vol.18,No.2 Pages: 64-70

    • NAID

      130003377331

    • Related Report
      2011 Final Research Report
  • [Journal Article] 水素還元されたPt Oxide Blackのメタノール酸化特性2012

    • Author(s)
      田口正美, 川端泰弘, 小坂勇樹
    • Journal Title

      J.MMIJ

      Volume: Vol.128 Pages: 40-46

    • NAID

      10030172289

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ analysis of creep behavior of pure Pb using electrochemical creep system2011

    • Author(s)
      M. Taguchi, J. Tanaka, T. Bundo, R. Itou, K. Shirai
    • Journal Title

      J. Power Sources

      Volume: Vol.196 Pages: 470-474

    • Related Report
      2011 Final Research Report
  • [Journal Article] 鉛蓄電池格子材料としてのPb-Ca系合金のクリープ挙動2011

    • Author(s)
      田口正美, 白井健太, 田中順朗, 分銅徹
    • Journal Title

      J. MMIJ

      Volume: Vol.127 Pages: 32-38

    • NAID

      10027624650

    • Related Report
      2011 Final Research Report
  • [Journal Article] 粉末圧延法で作製した鉛蓄電池用Pb基合金格子材料のクリープ挙動2011

    • Author(s)
      田口正美, 白井健太, 町山美昭, 箕浦敏, 酒井政則
    • Journal Title

      日本金属学会誌

      Volume: 75巻,5号 Pages: 302-309

    • NAID

      10028253451

    • Related Report
      2011 Final Research Report
  • [Journal Article] 鉛蓄電池格子材料としてのPb-Ca系合金のクリープ挙動2011

    • Author(s)
      田口正美, 白井健太, 田中順朗, 分銅徹
    • Journal Title

      J.MMIJ

      Volume: Vol.127 Pages: 32-38

    • NAID

      10027624650

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 粉末圧延法で作製した鉛蓄電池用Pb基合金格子のクリープ挙動2011

    • Author(s)
      田口正美, 白井健太, 町山美照, 箕浦敏, 酒井政則
    • Journal Title

      日本金属学会誌

      Volume: 75巻 Pages: 302-309

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Methanol Oxidation Activities of Pt Oxide Thin Films Prepared by Reactive Sputtering2010

    • Author(s)
      M. Taguchi, J. Nakayama, K. Itou, N. Nagai
    • Journal Title

      Int. J. Soc. Mater. Eng. Resor

      Volume: Vol.17,No.1 Pages: 15-19

    • NAID

      110007554358

    • Related Report
      2011 Final Research Report
  • [Journal Article] Effect of Partial Reduction on Methanol Oxidation Activities of Pt Oxide Catalyst,Proceedings of the sixth international Conference on Materials Engineering for Resources2009

    • Author(s)
      M. Taguchi, J. Nakayama
    • Journal Title

      Akita, Japan

      Pages: 386-391

    • Related Report
      2011 Final Research Report
  • [Presentation] ナノスケールPbO_2を複合化した鉛蓄電池正極の充放電特性2011

    • Author(s)
      佐々木利裕, 田口正美
    • Organizer
      日本金属学会東北支部2011年講演会
    • Place of Presentation
      秋田市,秋田大学
    • Year and Date
      2011-11-25
    • Related Report
      2011 Annual Research Report
  • [Presentation] ナノスケールPbO_2を活物質とした鉛蓄電池正極の充放電特性2011

    • Author(s)
      佐々木利裕, 田口正美
    • Organizer
      日本金属学会2011年秋期講演大会
    • Place of Presentation
      宜野湾市,沖縄コンベンションセンター
    • Year and Date
      2011-11-07
    • Related Report
      2011 Annual Research Report
  • [Presentation] ナノスケールPbO_2を用いた鉛蓄電池正極活物質の充放電特性2011

    • Author(s)
      佐々木利裕, 田口正美
    • Organizer
      日本素材物性学会平成23年度(第21回)年会
    • Place of Presentation
      秋田市,秋田ビューホテル
    • Year and Date
      2011-06-28
    • Related Report
      2011 Annual Research Report
  • [Presentation] (PbO_2ナノ粒子・高導電性PANI)コンポジットを用いた新型鉛蓄電池の開発2010

    • Author(s)
      佐々木利裕, 田口正美
    • Organizer
      日本素材物性学会平成22年度(第20回)年会
    • Place of Presentation
      秋田ビューホテル
    • Year and Date
      2010-06-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] ナノスケールPbO_2を用いた鉛蓄電池正極活物質の充放電特性

    • Author(s)
      佐々木利裕, 田口正美
    • Organizer
      日本素材物性学会平成23年度(第21回)年会
    • Related Report
      2011 Final Research Report
  • [Presentation] ナノスケールPbO_2を活物質とした鉛蓄電池正極の充放電特性

    • Author(s)
      佐々木利裕, 田口正美
    • Organizer
      日本金属学会2011年秋期講演大会集
    • Related Report
      2011 Final Research Report
  • [Presentation] ナノスケールPbO_2を複合化した鉛蓄電池正極の充放電特性

    • Author(s)
      佐々木利裕, 田口正美
    • Organizer
      日本金属学会東北支部2011年講演会
    • Related Report
      2011 Final Research Report
  • [Presentation] (PbO_2ナノ粒子・高導電性PANI)コンポジットを用いた新型鉛蓄電池の開発

    • Author(s)
      佐々木利裕, 田口正美
    • Organizer
      日本素材物性学会平成22年度(第20回)年会
    • Related Report
      2011 Final Research Report
  • [Presentation] b基合金グリッドのグロース挙動に及ぼす合金元素ならびに結晶組織の影響

    • Author(s)
      白井健太, 田口正美
    • Organizer
      2010年春期(第146回)日本金属学会講演概要
    • Related Report
      2011 Final Research Report
  • [Presentation] ナノスケール二酸化鉛・高導電性ポリマーを用いた高電流・高容量バッテリー

    • Author(s)
      田口正美
    • Organizer
      nano tech2009国際ナノテクノロジー総合展・技術会議JST展示案内
    • Place of Presentation
      東京ビックサイト
    • Related Report
      2011 Final Research Report
  • [Presentation] ナノスケール二酸化鉛と高導電性ポリマーの複合体を用いた新型鉛蓄電池

    • Author(s)
      田口正美
    • Organizer
      JST・秋田大学新技術説明会配付資料
    • Place of Presentation
      東京,JSTホール
    • Related Report
      2011 Final Research Report
  • [Remarks] フジサンケイビジネス,2009/3/18掲載,秋田大高容量の鉛蓄電池開発,高容量鉛蓄電池

    • Related Report
      2011 Final Research Report
  • [Remarks] 化学工業日報,2009/3/25掲載,鉛バッテリー正極利用率2.2倍に,高容量鉛蓄電池

    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 鉛蓄電池正極,鉛蓄電池および鉛蓄電池用正極の製造法2010

    • Inventor(s)
      田口正美
    • Industrial Property Rights Holder
      国立大学法人秋田大学
    • Patent Publication Number
      2010-170918
    • Filing Date
      2010-08-05
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 鉛蓄電池正極, 鉛蓄電池および鉛蓄電池用正極の製造法2010

    • Inventor(s)
      田口正美
    • Industrial Property Rights Holder
      国立大学法人秋田大学
    • Patent Publication Number
      2010-170918
    • Filing Date
      2010-08-05
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 燃料電池用白金系酸化物触媒2009

    • Inventor(s)
      田口正美
    • Industrial Property Rights Holder
      国立大学法人秋田大学
    • Industrial Property Number
      2009-065306
    • Filing Date
      2009-03-17
    • Related Report
      2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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