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Development of microcapsule-type separation material containing biological and functional molecules with interconnected spherical holes

Research Project

Project/Area Number 21560780
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionUniversity of Miyazaki

Principal Investigator

SHIOMORI Koichiro  宮崎大学, 工学部, 准教授 (80235506)

Co-Investigator(Kenkyū-buntansha) KIYOYAMA Shiro  都城工業高等専門学校, 物質工学科, 教授 (90300665)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywordsマイクロカプセル / リサイクルプロセス / 分離材 / 多孔質材料 / 抽出剤 / 生体分子 / 金属結合タンパク質 / リン脂質 / 金属リサイクルプロセス
Research Abstract

The microcapsules with interconnected spherical holes from the surface to the inside parts which contains biological and functional molecules, such as proteins binding selectively with metal ions or environmental hormones, DNA and liposome, were prepared. The microcapsules prepared have high surface area and easy accessibility of the outer aqueous solution to the inside of the microcapsules, which achieve high extraction rate. The effective separation processes with easy operation for the recovery of valuable resources and the removal of hazardous substances from wastewater were developed using the porous microcapsules developed.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (41 results)

All 2012 2011 2010 2009

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (31 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Preparation of Microcapsules Containing PC-88A with Interconnected Spherical Pores and Their Extraction Properties of Zn(II)2011

    • Author(s)
      A. Matsushita, T. Sana, S. Kiyoyama, M. Yoshida, K. Shiomori
    • Journal Title

      Solvent Extraction Research and Development

      Volume: 18 Pages: 123-135

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Properties of microcapsules containingPC-88A with connected spherical pores for Zn(II) extraction2011

    • Author(s)
      K. Shiomori, A. Matsushita, S. Kiyoyama, T. Sana, M. Yoshida
    • Journal Title

      International Solvent Extraction Conference 2011

      Pages: 206-206

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Properties of microcapsules containingPC-88A with connected spherical pores for Zn(II) extraction2011

    • Author(s)
      K.Shiomori, A.Matsushita, S.Kiyoyama, T.Sana, M.Yoshida
    • Journal Title

      Proc.International Solvent Extraction Conference 2011

      Volume: (CD-ROM) Pages: 206-206

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Microcapsules Containing PC-88A with Interconnected Spherical Pores and Their Extraction Properties of Zn(II)2011

    • Author(s)
      A.Matsushita, T.Sana, S.Kiyoyama, M.Yoshida, K.Shiomori
    • Journal Title

      Solvent Extraction Research and Development, Japan

      Volume: 18 Pages: 123-135

    • Related Report
      2011 Annual Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Large Size Microcapsules Containing Tri-n-octylamine by In situ Polymerization Combined with a Gel Inclusion Method and Their Extraction Behavior2010

    • Author(s)
      K. Shiomori, K. Saeki, T. Sana, S. Kiyoyama, M. Yoshida, Y. Hatate
    • Journal Title

      Solvent Extraction Research and Development

      Volume: 17 Pages: 215-224

    • NAID

      130005056894

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Extraction of Palladium(II) with Through-hole Type Microcapsules Containing Trioctylamine2010

    • Author(s)
      S. Kiyoyama, K. Shiomori, M. Yoshida
    • Journal Title

      Ars Separetoria Acta

      Volume: 7 Pages: 45-56

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Extraction of Palladium (II) with Through-hole Type Microcapsules Containing Trioctylamine2010

    • Author(s)
      S.Kiyoyama, K.Shiomori, M.Yoshida
    • Journal Title

      Ars Separetoria Acta

      Volume: 7 Pages: 45-56

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Large Size Microcapsules Containing Tri-n-octylamine by In situ Polymerization Combined with a Gel Inclusion Method and Their Extraction Behavior2010

    • Author(s)
      K.Shiomori, K.Saeki, T.Sana, S.Kiyoyama, M.Yoshida, Y.Hatate
    • Journal Title

      Solvent Extraction Research and Development, Japan 17(掲載決定)

    • NAID

      130005056894

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 強誘電性液晶を認識部位として導入したミクロスフェアのアミノ酸誘導体のキラル分離能評価2012

    • Author(s)
      菅原聡一郎, 吉田昌弘, 愛甲涼子, 大角義浩, 塩盛弘一郎, 清山史朗
    • Organizer
      化学工学会第77年会
    • Place of Presentation
      工学院大学(東京都)
    • Year and Date
      2012-03-15
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Extraction of ethanol from aqueous solution using phenolic extractants and their microcapsules2011

    • Author(s)
      S. Inoue, S. Kiyoyama, M. Yoshida, K. Shiomori
    • Organizer
      The 24th International Symposium on Chemical Engineering
    • Place of Presentation
      慶州現代ホテル(韓国・慶州市)
    • Year and Date
      2011-12-03
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Preparation of large porous polymeric particles impregnated LIX84-I and their extraction property of nickel(II)2011

    • Author(s)
      T. Kitabayashi, S. Kiyoyama, M. Yoshida, K. Shiomori
    • Organizer
      The 24th International Symposium on Chemical Engineering
    • Place of Presentation
      慶州現代ホテル(韓国・慶州市)
    • Year and Date
      2011-12-03
    • Related Report
      2011 Final Research Report
  • [Presentation] Preparation of large porous polymeric particles impregnated LIX84-I and their extraction property of nickel (II)2011

    • Author(s)
      T.Kitabayashi,, S.Kiyoyama, M.Yoshida, K.Shiomori
    • Organizer
      The 24th International Symposium on Chemical Engineering
    • Place of Presentation
      慶州現代ホテル(韓国・慶州市)
    • Year and Date
      2011-12-03
    • Related Report
      2011 Annual Research Report
  • [Presentation] LIX-84Iを含浸担持させた連結球状多孔質ポリマー粒子によるニッケルの抽出挙動2011

    • Author(s)
      北林卓朗, 真隆志, 清山史朗, 吉田昌弘, 塩盛弘一郎
    • Organizer
      第30回溶媒抽出討論会
    • Place of Presentation
      シーガイアコンベンションセンター(宮崎県)
    • Year and Date
      2011-11-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 連結球状孔を有するPC-88A内包マイクロカプセルによる亜鉛のカラム分離2011

    • Author(s)
      塩盛弘一郎, 松下明日香, 真隆志, 清山史朗, 吉田昌弘
    • Organizer
      第30回溶媒抽出討論会
    • Place of Presentation
      シーガイアコンベンションセンター(宮崎県)
    • Year and Date
      2011-11-25
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 連結球状多孔質を有するポリマー粒子を用いる抽出剤含浸樹脂の調製と吸着挙動2011

    • Author(s)
      塩盛弘一郎, 北林卓朗, 清山史朗, 吉田昌弘
    • Organizer
      化学工学会第43回秋季大会
    • Place of Presentation
      名古屋工業大学(愛知県)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Preparation of TOA Entrapped Microcapsules and Their Morphology Control for Rapid Extraction of Metal Ion2011

    • Author(s)
      S. Kiyayama, K. Shiomori, M. Yoshida
    • Organizer
      The 8th World Surfactant Congress
    • Place of Presentation
      オーストリアセンター(ウィーン)
    • Year and Date
      2011-06-06
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Microencapsulation of Lipase In Polymer Nano-Capsules Prepared Using Reverse Micellar System2011

    • Author(s)
      K. Shiomori, S. Kiyayama, M. Yoshida
    • Organizer
      The 8th World Surfactant Congress
    • Place of Presentation
      オーストリアセンター(ウィーン)
    • Year and Date
      2011-06-06
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Column extraction properties of Zn(II) using microcapsules containing PC-88A with interconnected spherical pores2011

    • Author(s)
      K. Shiomori, A. Matsushita, S. Kiyoyama, M. Yoshida
    • Organizer
      The 9th Japan/Korea International Symposium on Resources Recycling and Materials Science
    • Place of Presentation
      関西大学(大阪府)
    • Year and Date
      2011-05-31
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] 連結球状孔を有する抽出剤内包マイクロカプセルを用いる亜鉛のカラム分離特性2011

    • Author(s)
      塩盛弘一郎, 松下明日香, 真隆志, 清山史朗, 吉田昌弘
    • Organizer
      化学工学会第76年会
    • Place of Presentation
      東京農工大学(小金井市)
    • Year and Date
      2011-03-22
    • Related Report
      2011 Final Research Report
  • [Presentation] 連結球状孔を有する抽出剤内包マイクロカプセルを用いる亜鉛のカラム分離特性2011

    • Author(s)
      塩盛弘一郎, 松下明日香, 真隆志, 清山史朗, 吉田昌弘
    • Organizer
      化学工学会 第76年会
    • Place of Presentation
      東京農工大学(小金井市)
    • Year and Date
      2011-03-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of microcapsules containing PC-88A with interconnected spherical pores and their extraction behavior of Zn(II)2010

    • Author(s)
      A. Matsushita, T. Sana, K. Shiomori, S. Kiyoyama, M. Yoshida
    • Organizer
      The 23rd International Symposium on Chemical Engineering
    • Place of Presentation
      九州産業大学(福岡市)
    • Year and Date
      2010-12-04
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 連結球状孔を有するマイクロカプセルへの抽出剤の内包とその亜鉛抽出機構の解析2010

    • Author(s)
      塩盛弘一郎, 松下明日香, 清山史朗, 吉田昌弘
    • Organizer
      第29回溶媒抽出討論会
    • Place of Presentation
      広島大学(東広島市)
    • Year and Date
      2010-11-27
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Preparation of Microcapsules with Interconnected Spherical Pores Containing 2-Ethylhexyl Phosphonic Acid Mono-2-ethylhexyl ester2010

    • Author(s)
      K. Shiomori, A. Matsushita, S. Kiyoyama, M. Yoshida
    • Organizer
      9th Korea-Japan Symposium on Materials & Interfaces
    • Place of Presentation
      Yoesu Convention Center(韓国麗水市)
    • Year and Date
      2010-11-01
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 連結球状孔を有するPC-88A内包マイクロカプセルによる亜鉛の抽出機構2010

    • Author(s)
      松下明日香, 塩盛弘一郎, 真隆志, 清山史朗, 吉田昌弘
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学(京都市)
    • Year and Date
      2010-09-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 連結球状孔を有するPC-88A内包マイクロカプセルによる亜鉛の抽出機構2010

    • Author(s)
      松下明日香, 塩盛弘一郎, 真隆志, 清山史朗, 吉田昌弘
    • Organizer
      化学工学会 第42回秋季大会
    • Place of Presentation
      同志社大学(京都市)
    • Year and Date
      2010-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of Through-Holed Microcapsules Entrapped Tri-n-octylamine and Extraction of Pd(II)2010

    • Author(s)
      S. Kiyoyama, K. Shiomori, M. Yoshid, Y. Hatate
    • Organizer
      The 5th International Conference on Ion Exchange
    • Place of Presentation
      メルボルン大学(オーストラリア・メルボルン市)
    • Year and Date
      2010-07-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Preparation of Porous Microcapsules Containing PC-88A and their Extraction Property of Zn(II)2010

    • Author(s)
      A. Matsushita, S. Kiyoyama, T. Sana, M. Yoshida, Y. Hatate, K. Shiomori
    • Organizer
      The 5th International Conference on Ion Exchange
    • Place of Presentation
      メルボルン大学(オーストラリア・メルボルン市)
    • Year and Date
      2010-07-19
    • Related Report
      2011 Final Research Report
  • [Presentation] Preparation of Through-Holed Microcapsules Entrapped Tri-n-octylamine and Extraction of Pd(II)2010

    • Author(s)
      S.Kiyoyama, K.Shiomori, M.Yoshid, Y.Hatate
    • Organizer
      The 5th International Conference on Ion Exchange
    • Place of Presentation
      メルボルン大学(オーストラリア.・メルボ'ルン市)
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation of Porous Microcapsules Containing PC-88A and their Extraction Property of Zn(II)2010

    • Author(s)
      A.Matsushita, S.Kiyoyama, T.Sana, M.Yoshida, Y.Hatate, K.Shiomori
    • Organizer
      The 5th International Conference on Ion Exchange
    • Place of Presentation
      メルボルン大学(オーストラリア.・メルボルン市)
    • Year and Date
      2010-07-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] Microcapsules with Interconnected-Spherical Pores Containing Extractant for Zn(II)2010

    • Author(s)
      K. Shiomori, A. Matsushita, S. Kiyoyama M. Yoshida
    • Organizer
      The 8th Japan/Korea International Symposium on Resources Recycling and Materials Science
    • Place of Presentation
      ラマダホテルソウル(韓国ソウル市)
    • Year and Date
      2010-06-25
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] 連結球状孔を有するPC-88A内包マイクロカプセルによる亜鉛の抽出特性2010

    • Author(s)
      松下明日香, 塩盛弘一郎, 清山史朗, 真隆志, 吉田昌弘, 幡手泰雄
    • Organizer
      化学工学会第75年会
    • Place of Presentation
      鹿児島大学(鹿児島市)
    • Year and Date
      2010-03-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 連結球状孔を有するPC-88A内包マイクロカプセルによる亜鉛の抽出特性2010

    • Author(s)
      松下明日香・塩盛弘一郎・清山史朗・真隆志・吉田昌弘・幡手泰雄
    • Organizer
      化学工学会 第75年会
    • Place of Presentation
      鹿児島大学(鹿児島市)
    • Year and Date
      2010-03-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] Preparation of Porous Microcapsules Containing PC-88A and their Extraction Property of Zn(II)2009

    • Author(s)
      A. Matsushita, S. Kiyoyama, T. Sana, M. Yoshida, Y. Hatate, K. Shiomori
    • Organizer
      The 22th Symposium on Chemical Engineering Daejeon/Chungnam(Korea)-Kyushu(Japan)
    • Place of Presentation
      Daejon Convention Center(韓国大田市)
    • Year and Date
      2009-12-05
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 連結球状孔を有する抽出剤内包マイクロカプセルによる亜鉛の抽出分離2009

    • Author(s)
      塩盛弘一郎, 松下明日香, 清山史朗, 真隆志, 吉田昌弘, 幡手泰雄
    • Organizer
      第28回溶媒抽出討論会
    • Place of Presentation
      大阪大学基礎工学部Σホール(豊中市)
    • Year and Date
      2009-11-20
    • Related Report
      2011 Final Research Report
  • [Presentation] 連結球状孔を有する抽出剤内包マイクロカプセルによる亜鉛の抽出分離2009

    • Author(s)
      塩盛弘一郎, 松下明日香, 清山史朗, 真隆志, 吉田昌弘, 幡手泰雄
    • Organizer
      第28回 溶媒抽出討論会
    • Place of Presentation
      大阪大学基礎工学部Σホール(豊中市)
    • Year and Date
      2009-11-20
    • Related Report
      2009 Annual Research Report
  • [Presentation] 貫通孔を形成させたマイクロカプセルによるPd(II)の抽出速度2009

    • Author(s)
      清山史朗, 塩盛弘一郎, 吉田昌弘, 幡手泰雄
    • Organizer
      第2回化学工学3支部合同北九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Year and Date
      2009-10-30
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 抽出剤内包多孔質マイクロカプセルの調製および亜鉛の抽出特性2009

    • Author(s)
      松下明日香, 塩盛弘一郎, 清山史朗, 吉田昌弘, 幡手泰雄
    • Organizer
      第2回化学工学3支部合同北九州大会
    • Place of Presentation
      北九州国際会議場(北九州市)
    • Year and Date
      2009-10-30
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] 貫通孔保持マイクロカプセルによる貴金属の抽出2009

    • Author(s)
      清山史朗, 塩盛弘一郎, 吉田昌弘, 幡手泰雄
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学(東広島市)
    • Year and Date
      2009-09-25
    • Related Report
      2011 Final Research Report
  • [Presentation] 貫通孔保持マイクロカプセルによる貴金属の抽出2009

    • Author(s)
      清山史朗, 塩盛弘一郎, 吉田昌弘, 幡手泰雄
    • Organizer
      化学工学会 第41回秋季大会
    • Place of Presentation
      広島大学(東広島市)
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Patent(Industrial Property Rights)] 無電解ニッケルめっき廃液の再生処理方法2010

    • Inventor(s)
      塩盛弘一郎,清山史朗,福永克明,真隆志
    • Industrial Property Rights Holder
      宮崎大学,都城高専
    • Industrial Property Number
      2010-286875
    • Filing Date
      2010-12-21
    • Related Report
      2011 Final Research Report
  • [Patent(Industrial Property Rights)] 無電解ニッケルめっき廃液の再生処理方法2010

    • Inventor(s)
      塩盛弘一郎, 清山史朗, 福永克明, 真隆志
    • Industrial Property Rights Holder
      宮崎大学, 都城高専
    • Industrial Property Number
      2010-286875
    • Filing Date
      2010-12-21
    • Related Report
      2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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