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Development of column type dye-sensitized solar cell using carbon/TiO_2 hybrid spherical microbeads

Research Project

Project/Area Number 21560804
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionKumamoto Industrial Research Institute

Principal Investigator

NAGATA Masanori  熊本県産業技術センター, 材料・地域資源室, 研究参事 (60399673)

Co-Investigator(Kenkyū-buntansha) NAGAOKA Shoji  熊本県産業技術センター, 材料・地域資源室, 研究主幹 (10227994)
SHIROSAKI Tomohiro  熊本県産業技術センター, 材料・地域資源室, 研究員 (70554054)
Co-Investigator(Renkei-kenkyūsha) IHARA Hirotaka  熊本大学, 大学院・自然科学研究科, 教授 (10151648)
SAGAWA Takashi  京都大学, エネルギー理工学研究所, 准教授 (20225832)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsチタン / 色素 / 多糖類 / 微粒子 / 太陽電池 / 色素増感太陽電池 / カーボン / 酸化チタン / セルロース / 酸化亜鉛 / カラム / 透明フィルム / ヨウ素
Research Abstract

Cellulose/TiO_2 hybrid spherical microbeads were made by a phase-separation method using viscose. And the carbon/TiO2 hybrid spherical microbeads prepared by carbonization of the cellulose/TiO_2 composite. Dye-sensitized solar cells were fabricated using ZnO nanoparticles. The conversion efficiency value was virtually constant under 200°C, but decreased significantly over 200℃. A model of column type dye-sensitized solar cell was fabricated using a plastic substrate.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (17 results)

All 2012 2011 2010 2009

All Journal Article (7 results) (of which Peer Reviewed: 7 results) Presentation (7 results) Book (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Preparation and characterization of dispersible chitosan particles with borate crosslinking and their antimicrobial and antifungal activity2012

    • Author(s)
      K. Saita, S. Nagaoka, T. Shirosaki, M. Horikawa, S. Matsuda, H. Ihara
    • Journal Title

      Carbohydrate Research

      Volume: Vol.349 Pages: 52-58

    • DOI

      10.1016/j.carres.2011.12.017

    • NAID

      40019514142

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chitosan sub-micron particles prepared using sulfate ion salt as bacteriostatic materials in neutral pH condition2011

    • Author(s)
      K. Saita, S. Nagaoka, T. Shirosaki, M. Horikawa, S. Matsuda, H. Ihara
    • Journal Title

      Journal of Biomaterials and Nanobiotechnology

      Volume: Vol.2 Issue: 04 Pages: 347-352

    • DOI

      10.4236/jbnb.2011.24043

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Facile and versatile method for preparing core-shell microspheres with controlled surface structures based on silica particles-monolayer2011

    • Author(s)
      A. Uchimura, S. Kubota, S. Yamada, T. Wakiya, M. Takafuji, T. Shirosaki, S. Nagaoka, H. Ihara
    • Journal Title

      Materials Chemistry and Physics

      Volume: Vol.129 Issue: 3 Pages: 871-880

    • DOI

      10.1016/j.matchemphys.2011.05.029

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of dispersible chitosan particles with boratecrosslinking and antimicrobial and antifungal application2010

    • Author(s)
      S. Nagaoka, K. Saita, S. Kobayashi, M. Horikawa, T. Shirosaki, M. Takafuji, H. Ihara
    • Journal Title

      Chemistry Letters

      Volume: No.9 Issue: 9 Pages: 935-937

    • DOI

      10.1246/cl.2010.935

    • NAID

      10027184564

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of dispersible chitosan particles with borate-crosslinking and antimicrobial and antifungal application.2010

    • Author(s)
      S.Nagaoka, K.Saita, S.Kobayashi, M.Horikawa, T.Shirosaki, M.Takafuji, H.Ihara.
    • Journal Title

      Chemistry Letters

      Pages: 935-937

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A facile preparation method for self-assembled monolayers with silica particles on polystyrene-based microspheres2009

    • Author(s)
      H. Ihara, S. Kubota, A. Uchimura, Y. Sakai, T. Wakiya, M. M. Rahman, S. Nagaoka, M. Takafuj
    • Journal Title

      Materials Chemistry and Physics

      Volume: Vol.114 Issue: 1 Pages: 1-5

    • DOI

      10.1016/j.matchemphys.2008.09.043

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A facile preparation method for self-assembled monolayers with silica particles on polystyrene-based microspheres.2009

    • Author(s)
      H.Ihara, S.Kubota, A.Uchimura, Y.Sakai, T.Wakiya, M.M.Rahman, S.Nagaoka, M.Takafuj
    • Journal Title

      Materials Chemistry and Physics 114

      Pages: 1-5

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Annealing Temperature Dependence of the Photoelectrochemical Properties of Dye-Sensitized Solar Cells Fabricated with ZnO Nanoparticles2011

    • Author(s)
      Hiroki Yonekawa, Tomohiro Shirosaki, Maki Horikawa, Shoji Nagaoka, Masanori Nagata, Hirokuni Jintoku, Makoto Takafuji, Hirotaka Ihara
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜情報文化文化センター(神奈川県)
    • Year and Date
      2011-12-09
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] Dye-Sensitized Solar Cells Fabricated with ZnO Nanoparticles for High Conversion Efficiency2011

    • Author(s)
      Hiroki Yonekawa, Tomohiro Shirosaki, Maki Horikawa, Shoji Nagaoka, Makoto Takafuji, Hirotaka Ihara
    • Organizer
      3rd Asian Symposium on Advanced Materials
    • Place of Presentation
      九州大学(福岡県)
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] ZnOナノスフェアを用いた色素増感太陽電池の作製とその評価2011

    • Author(s)
      米川裕基,城崎智洋,堀川真希,永岡昭二,高藤誠,伊原博隆
    • Organizer
      第48回化学関連支部合同大会
    • Place of Presentation
      北九州国際会議場(福岡県)
    • Year and Date
      2011-07-09
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Presentation] エチレングリコールユニットを有するフラーレン誘導体によるバルクへテロ接合構造の制御2010

    • Author(s)
      針崎良太,馬場玲輔,城崎智洋,堀川真希,永岡昭二,佐川尚,吉川進,高藤誠,伊原博隆
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学(熊本県)
    • Year and Date
      2010-11-07
    • Related Report
      2011 Final Research Report
  • [Presentation] エチレングリコールユニットを有するフラーレン誘導体によるバルクヘテロ接合構造の制御2010

    • Author(s)
      針崎良太, 馬場玲輔, 城崎智洋, 堀川真希, 永岡昭二, 佐川尚, 吉川進, 高藤誠, 伊原博隆
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本市
    • Year and Date
      2010-11-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] ビニル基含有フラーレン誘導体による有機薄膜太陽電池のバルクへテロ接合構造の制御2010

    • Author(s)
      城崎智洋,馬場怜輔,堀川真希,永岡昭二,櫻井英夫,佐川尚,伊原博隆
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎大学(長崎県)
    • Year and Date
      2010-09-16
    • Related Report
      2011 Final Research Report
  • [Presentation] ビニル基含有フラーレン誘導体による有機薄膜太陽電池のバルクヘテロ接合構造の制御2010

    • Author(s)
      城崎智洋, 馬場怜輔, 堀川真希, 永岡昭二, 櫻井英夫, 佐川尚, 伊原博隆
    • Organizer
      第71回応用物理学会学術講演会
    • Place of Presentation
      長崎市
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Book] コアシェル微粒子の設計・合成技術・応用の展開2010

    • Author(s)
      永岡昭二,伊原博隆
    • Total Pages
      13
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Final Research Report
  • [Book] コアシェル微粒子の設計・合成技術・応用の展開2010

    • Author(s)
      永岡昭二, 伊原博隆
    • Total Pages
      13
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Annual Research Report
  • [Patent(Industrial Property Rights)] 色素増感太陽電池の製造方法2011

    • Inventor(s)
      城崎智洋、永岡昭二、堀川真希、伊原博隆、高藤誠、田中巧、後藤武弘
    • Industrial Property Rights Holder
      熊本県、国立大学法人熊本大学、大東化成工業株式会社
    • Industrial Property Number
      2011-235486
    • Filing Date
      2011-10-26
    • Related Report
      2011 Annual Research Report 2011 Final Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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