Molecular Chemical Strategy for Rare-Metal Materials Containing Platinum Which Contribute to Create Green Energy Systems

• Project/Area Number: 21605008
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Element strategy
• Research Institution: Nara Women's University
• Principal Investigator: TANASE Tomoaki 奈良女子大学, 理学部, 教授 (50207156)
• Co-Investigator(Kenkyū-buntansha): NAKAJIMA Takayuki 奈良女子大学, 理学部, 准教授 (80322676)
• Project Period (FY): 2009 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2011: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
• Keywords: 金属クラスター / 貴金属代替材料 / 元素戦略 / 多座ホスフィン / 触媒電極 / 白金 / パラジウム / 銅

Research Abstract

Reactions of linear Pt and Pd clusters constrained by tri-and tetraphosphines with H^+and Lewis acidic Hg^<2+> were investigated, and copper-hydride clusters were synthesized as base metallic materials by using tetraphosphine ligands.

Research Products

• [Journal Article] Cyclic Trinuclear Rh_2M Complexes(M=Rh, Pt, Pd, Ni) Supported by meso-1, 3-Bis-{(diphenylphosphinomethyl) phenylphosphino} pr opane (2012)
  • Author(s): T. Nakajima, S. Kurai, S. Noda, M. Zouda, B. Kure, and T. Tanase
  • Journal Title: Organometallics Volume: (in press) Issue: 11 Pages: 4283-4294
  • DOI: 10.1021/om300278k
  • Peer Reviewed
• [Journal Article] Structural, Photo physical, and Mesomorphic Properties of Luminescent Platinum(II)-salen Schiff Base Complexes (2012)
  • Author(s): Y. Abe, Y. Takagi, M. Nakamura, T. Takeuchi, T. Tanase, M. Yokokawa, H. Mukai, T. Megumi, A. Hachisuga, and K. Ohta
  • Journal Title: Inorg. Chim. Acta Volume: (in press) Pages: 254-260
  • DOI: 10.1016/j.ica.2012.02.041
  • Peer Reviewed
• [Journal Article] Heterotrinuclear Complexes with Pd, Rh, and Ir Ions Assembled by Conformational Switch of a Tetraphosphine Ligand around Pd Center (2012)
  • Author(s): A. Yoshii, H. Takenaka, H. Nagata, S. Noda, K. Nakamae, B. Kure, T. Nakajima, and T. Tanase
  • Journal Title: Organometallics Volume: 31 Issue: 1 Pages: 133-143
  • DOI: 10.1021/om2006744
  • Peer Reviewed
• [Journal Article] Cyclic Trinuclear Rh_2M Complexes (M=Rh, Pt, Pd, Ni) Supported by meso-1,3-Bis{(diphenylphos-phinomethyl)phenylphosphino}propane (2012)
  • Author(s): T.Nakajima, S.Kurai, S.Noda, M.Zouda, B.Kure, T.Tanase
  • Journal Title: Organometallics Volume: (in press)
  • Peer Reviewed
• [Journal Article] Tetrapalladium Complex with Bridging Germylene Ligands [Pd{Pd(dmpe)}_3(μ_3-GePh_2)_3]. Structural Change of the Planar Pd_4Ge_3 Core (2011)
  • Author(s): Makoto Tanabe, Naoko Ishikawa, Mai Chiba, Tomohito Ide, Kohtaro Osakada, Tomoaki Tanase
  • Journal Title: Journal of American Chemical Society Volume: 133 Issue: 46 Pages: 18598-18601
  • DOI: 10.1021/ja208565q
  • Peer Reviewed
• [Journal Article] Intramolecular Metal-Metal Bond Rearrangement in a Pt_2PdHg Heterometallic Cluster Forming a Hg^I-Pd^I Covalent Bond (2011)
  • Author(s): A. Hosokawa, B. Kure, T. Nakajima, K. Nakamae, and T. Tanase
  • Journal Title: Organometallics Volume: 30 Issue: 22 Pages: 6063-6066
  • DOI: 10.1021/om2008524
  • Peer Reviewed
• [Journal Article] Octanuclear Iron(III) Complexes Supported by Kemp's Tricarboxylate Ligands (2011)
  • Author(s): Y. Takemura, Y. Okui, B. Kure, T. Nakajima, T. Tanase, M. Mikuriya, and M. Takahashi
  • Journal Title: Inorg. Chim. Acta Volume: 379 Issue: 1 Pages: 100-108
  • DOI: 10.1016/j.ica.2011.09.028
  • Peer Reviewed
• [Journal Article] Systematic Expansion of Supercubane Cores in Manganese Oxo Clusters with Tricarboxylate Ligands (2011)
  • Author(s): Yayoi Okui, et al
  • Journal Title: Eur.J.Inorg.Chem. Volume: 2011 Issue: 28 Pages: 4325-4330
  • DOI: 10.1002/ejic.201100781
  • Peer Reviewed
• [Journal Article] Stepwise Construction of Au_4Ag_2Cu_2 Coinage Rings Supported by Tetraphophine Ligands (2011)
  • Author(s): Y. Takemura, T. Nishida, B. Kure, T. Nakajima, M. Iida, and T. Tanase
  • Journal Title: Chem. Eur. J Volume: 17 Issue: 38 Pages: 10528-10532
  • DOI: 10.1002/chem.201101232
  • Peer Reviewed
• [Journal Article] Development of Molecular Metal Chains Supported by Multidentate Phosphines (2010)
  • Author(s): T. Tanase
  • Journal Title: Bulletin of Japan Society of Coordination Chemistry Volume: 55 Pages: 52-70
  • DOI: 10.4019/bjscc.55.52
  • NAID: 130000322470
  • ISSN: 1882-6954, 1883-1737
  • Peer Reviewed
• [Journal Article] Development of Molecular Metal Chains Supported by Multidentate Phosphines (2010)
  • Author(s): T.Tanase
  • Journal Title: Bull.Jpn.Soc.Coord.Chem. Volume: 55 Pages: 52-70
  • NAID: 130000322470
  • Peer Reviewed
• [Journal Article] Hexa-and Octagold Chains from Flexible Tetra gold Molecular Units Supported by Linear Tetraphosphine Ligand (2009)
  • Author(s): Y. Takemura, H. Takenaka, T. Nakajima, and T. Tanase
  • Journal Title: Angew. Chem. Int. Ed Volume: 48 Issue: 12 Pages: 2157-2161
  • DOI: 10.1002/anie.200806012
  • Peer Reviewed
• [Journal Article] Planar Tetra nuclear and Dumbbell-shaped Octanuclear Pd Complexes with Bridging Silylene Ligands (2009)
  • Author(s): T. Yamada, A. Mawatari, M. Tanabe, K. Osakada, and T. Tanase
  • Journal Title: Angew. Chem. Int. Ed. Volume: 48 Issue: 3 Pages: 568-571
  • DOI: 10.1002/anie.200804728
  • Peer Reviewed
• [Journal Article] Dynamic Structural Changes of Pentacopper(II) Chains Supported by N_6-donor Ligands (2009)
  • Author(s): Y. Takemura, T. Nakajima, T. Tanase, M. Usuki, H. Takenaka, E. Goto, and M. Mikuriya
  • Journal Title: Chem. Commun. Issue: 13 Pages: 1664-1666
  • DOI: 10.1039/b817237d
  • Peer Reviewed
• [Journal Article] Chemically Modified Electrode with a Film of Nano Ruthenium Oxides Stabilizing High Valent RuO_4-Species and Its Redox-Selective Sequential Transformation to Polynuclear Ruthenium Oxide-Metallocyanates (2009)
  • Author(s): A. S. Kumar, T. Tanase, and J. M. Zen
  • Journal Title: Langmuir Volume: 25 Issue: 23 Pages: 10231-20243
  • DOI: 10.1021/la902228h
  • Peer Reviewed
• [Journal Article] Interconversion between Ladder-type Octanuclear and Linear Tetra nuclear Copper(I) Complexes Supported by Tetraphosphine Ligands (2009)
  • Author(s): Y. Takemura, T. Nakajima, and T. Tanase
  • Journal Title: Dalton Trans. Issue: 46 Pages: 10231-10243
  • DOI: 10.1039/b909252h
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of Linear Tetra nuclear Silver(I) Complexes Bridged by Tetraphosphine Ligands (2009)
  • Author(s): Y. Takemura, T. Nakajima, and T. Tanase
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2009 Issue: 32 Pages: 4820-4829
  • DOI: 10.1002/ejic.200900652
  • Peer Reviewed
• [Journal Article] Hexa- and Octagold Chains from Flexible Tetragold Molecular Units Supported by Linear Tetraphosphine Ligand (2009)
  • Author(s): Y.Takemura, H.Takenaka, T.Nakajima, T.Tanase
  • Journal Title: Angew.Chem. Int.Ed. 48 Pages: 2157-2161
  • Peer Reviewed
• [Journal Article] Planar Tetranuclear and Dumbbell-shaped Octanuclear Pd Complexes with Bridging Silylene Ligands (2009)
  • Author(s): T.Yamada, A.Mawatari, M.Tanabe, K.Osakada, T.Tanase
  • Journal Title: Angew.Chem.Int.Ed 48 Pages: 568-571
  • Peer Reviewed
• [Journal Article] Chemically Modified Electrode with a Film of Nano Ruthenium Oxides Stabilizing High Valent RuO_4- Species and Its Redox-Selective Sequential Transformation to Polynuclear Ruthenium ?Oxide-Metallo-Cyanates (2009)
  • Author(s): A.S.Kumar, T.Tanase, J.-M.Zen
  • Journal Title: Langmuir 25 Pages: 13633-13640
  • Peer Reviewed
• [Journal Article] Interconversion between Ladder-type Octanuclear and Linear Tetranuclear Copper(I) Complexes Supported by Tetraphosphine Ligands (2009)
  • Author(s): Y.Takemura, T.Nakajima, T.Tanase
  • Journal Title: Dalton Trans. Pages: 10231-10243
  • Peer Reviewed
• [Journal Article] Synthesis and Characterization of Linear Tetranuclear Silver(I) ?Complexes Bridged by Tetraphosphine Ligands (2009)
  • Author(s): Y.Takemura, T.Nakajima, T.Tanase
  • Journal Title: Eur.J.Inorg.Chem. Pages: 4820-4829
  • Peer Reviewed
• [Presentation] ニトリル類を軸配位子とした直鎖状パラジウム八核錯体の合成と構造 (2012)
  • Author(s): 中前佳那子, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-28
• [Presentation] 四座ホスフィン配位子rac-dpmppmにより支持されたパラジウム二核錯体の合成 (2012)
  • Author(s): 大滝理紗, 中前佳那子, 西田智子, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-25
• [Presentation] 電子求引性置換基を有する新規四座ホスフィン配位子により支持された直鎖状パラジウム多核錯体の合成と構造 (2012)
  • Author(s): 望月彩花, 中前佳那子, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2012-03-25
• [Presentation] Multinuclear Transition Metal Complexes Supported by Linear Tetra-Phosphines (2011)
  • Author(s): Y.Takemura, T.Nishida, K.Nakamae, B.Kure, T.Nakajima, T.Tanase
  • Organizer: International Symposium on Catalysis and Fine Chemicals 2011
  • Place of Presentation: Nara (Japan)(Invited Lecture IL27)(招待講演)
  • Year and Date: 2011-12-06
• [Presentation] アセトニトリルを軸配位子とした直鎖状パラジウム八核錯体 (2011)
  • Author(s): 中前佳那子, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 錯体化学会弟61回討論会
  • Place of Presentation: 岡山
  • Year and Date: 2011-09-18
• [Presentation] Nona-and Hexadecanuclear Copper Hydride Clusters Supported by Tetraphosphine Ligands (2011)
  • Author(s): 中前佳那子, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2011-09-07
• [Presentation] Multinucleation of Late Transition Metals with New Tetraphosphine Ligands (2011)
  • Author(s): 中島隆行, 野田紗世, 倉井佐知, 造田真希, 久禮文章, 棚瀬知明
  • Organizer: 第58回有機金属化学討論会
  • Place of Presentation: 名古屋
  • Year and Date: 2011-09-07
• [Presentation] Multinuclear Transition Metal Complexes Supported by Linear Tetraphosphines (2011)
  • Author(s): Y. Takemura, T. Nishida, K. Nakamae, B. Kure, T. Nakajima, and T. Tanase
  • Organizer: International Symposium on Catalysis and Fine Chemicals 2011
  • Place of Presentation: invited lecture IL27
• [Presentation] 三座ホスフィンによって支持された白金・パラジウム三核錯体と水銀塩との反応 (2010)
  • Author(s): 細川彩, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪
• [Presentation] 直鎖型四座ホスフィン配位子によって支持された11族金属イオンを含む直鎖状及び環状多核錯体の合成と構造及び性質 (2010)
  • Author(s): 西田智子, 竹村幸恵, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪
• [Presentation] 四座ホスフィン配位子により構造規制された金属-金属結合を有する直鎖状パラジウム八核錯体 (2010)
  • Author(s): 中前佳那子, 細川彩, 竹村幸恵, 久禮文章, 中島隆行, 棚瀬知明
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪
• [Presentation] Syntheses, Structures, and Reactivities of Cyclic Trinuclear Complexes with Group 9 and 10 Metals Supported by a Tetraphosphine Ligand', S. Noda, S. Kurai, B. Kure, T. Nakajima, and T. Tanase (2010)
  • Author(s): 野田沙世, 倉井佐知, 久禮文章, 中島隆, 棚瀬知明
  • Organizer: 第57回有機金属化学討論会
  • Place of Presentation: 東京
• [Presentation] Reactions of Trinuclear Platinum Complexes Supported by Tridentate Phosphine Ligands with Mercury Salts (2010)
  • Author(s): A. Hosokawa, B. Kure, T. Nakajima, and T. Tanase
  • Organizer: XXIV International Conference on Organometallic Chemistry
  • Place of Presentation: Taipei, Taiwan
• [Presentation] Linear Octanuclear Palladium Complexes Supported by Tetraphosphine Ligands (2010)
  • Author(s): K. Nakamae, T. Takemura, B. Kure, T. Nakajima, and T. Tanase
  • Organizer: XXIV International Conference on Organometallic Chemistry
  • Place of Presentation: Taipei, Taiwan
• [Presentation] Reactions of Trinuclear Platinum Complexes Supported by Tridentate Phosphine Ligands with Mercury Salts (2010)
  • Author(s): A.Hosokawa, B.Kure, T.Nakajima, T.Tanase
  • Organizer: XXIV International Conference on Organometallic Chemistry
  • Place of Presentation: Taipei, Taiwan (China)
• [Book] ハウスクロフト無機化学(上) (2012)
  • Author(s): C. E. Housecroft, A. G. Sharpe著
  • Total Pages: 561
  • Publisher: 東京化学同人(東京)
• [Book] ハウスクロフト無機化学(上) (2012)
  • Author(s): 巽, 西原, 穐田, 酒井監訳, 棚瀬(2,3,6章分担翻訳)
  • Total Pages: 561
  • Publisher: 東京化学同人
• [Remarks]
  • URL: http://www.chem.nara-wu.ac.jp/~tanase/TanaseGroup/