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Do the layered silicates in smectite-mica series form solid solution?

Research Project

Project/Area Number 21654078
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeSingle-year Grants
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionNational Institute for Materials Science

Principal Investigator

YAMADA Hirohisa  独立行政法人物質・材料研究機構, 環境再生材料ユニット, グループリーダー (00343848)

Co-Investigator(Kenkyū-buntansha) TAMURA Kenji  独立行政法人物質・材料研究機構, 環境再生材料ユニット, 主任研究員 (80370310)
SUEHARA Shigeru  独立行政法人物質・材料研究機構, 理論計算科学ユニット, 主任研究員 (00354374)
Project Period (FY) 2009 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,370,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,200,000 (Direct Cost: ¥1,200,000)
Fiscal Year 2009: ¥1,000,000 (Direct Cost: ¥1,000,000)
Keywords岩石・鉱物・鉱床学 / 人工・天然鉱物 / 層状ケイ酸塩 / 粘土鉱物学
Research Abstract

Smectite and mica, which belong to a group of layered silicate, have classified into expandable clay mineral and non-expandable layered silicate, respectively. Recently we found the expandable behavior of mica, and proposed the basic issues of their classification. In this research, we have carried out the fundamental researches for smectite. mica system by combing experimental mineralogy, material science, crystal chemistry and computational science.

Report

(4 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (56 results)

All 2011 2010 2009 Other

All Journal Article (23 results) (of which Peer Reviewed: 21 results) Presentation (27 results) Book (6 results)

  • [Journal Article] Geomaterials : their application to environmental remediation2011

    • Author(s)
      H. Yamada, K. Tamura, Y. Watanabe, N. Iyi and K. Morimoto
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 12

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intercalation of sugar alcohols into the interlayer of montmorillonite by wet and dry processes2011

    • Author(s)
      T. Hatta, T. Echigo, S. Nemoto, K. Tamura and H. Yamada
    • Journal Title

      Clay Science

      Volume: 15 Pages: 61-66

    • NAID

      110008661173

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of nano-sized boehmites for optimum phosphate sorption2011

    • Author(s)
      Y. Watanabe, T. Kasama, K. Fukushi, T. Ikoma, Y. Kamatsu, J. Tanaka, Y. Moriyoshi and H. Yamada
    • Journal Title

      Separation Science and Technology

      Volume: 46 Pages: 818-824

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption and photo-degradation properties of anionic dyes by layered double hydroxides2011

    • Author(s)
      K. Morimoto, K. Tamura, N. Iyi, J. Ye and H. Yamada
    • Journal Title

      J. Physics and Chemistry of Solids

      Volume: 72 Pages: 1037-1045

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption and photodegradation properties of anionic dyes by layered double hydroxides2011

    • Author(s)
      K.Morimoto, K.Tamura, N.Iyi, J.Ye, H.Yamada
    • Journal Title

      J.Physics and Chemistry of Solids

      Volume: 72 Issue: 9 Pages: 1037-1045

    • DOI

      10.1016/j.jpcs.2011.05.018

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Geomaterials : their application to environmental remediation/Geomaterials : their application to environmental remediation2011

    • Author(s)
      H.Yamada, K.Tamura, Y.Watanabe, N.Iyi, K.Morimoto
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 12 Issue: 6 Pages: 40921-40921

    • DOI

      10.1088/1468-6996/12/6/064705

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pre-paration and Properties of Exfoliated Vermiculite. Polyamide 6 Nanocomposite2010

    • Author(s)
      K. Tamura, K. Morimoto, T. Ushirouchi, H. Yamada, T. Hatta, Y. Mito
    • Journal Title

      Clay Science

      Volume: 14 Pages: 147-153

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-step con-version of CO32-LDH(layered double hydroxide) into anion-exchangeable LDHs using an acetate-buffer/salt method2010

    • Author(s)
      N. Iyi and H. Yamada
    • Journal Title

      Chem. Lett

      Volume: 39 Pages: 591-593

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption and photo-degradation reactions of anionic dye on Zn-Al-substituted layered double hydr-oxide2010

    • Author(s)
      K. Morimoto, K. Tamura, J. Ye and H. Yamada
    • Journal Title

      Trans. Mater. Res. Soc. Jpn

      Volume: 35 Pages: 813-816

    • NAID

      130005004068

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of mono-dispersed Zn-smectite2010

    • Author(s)
      C. S. Pascua, H. Yamada, M. Ohnuma, K. Tamura, Y. Matsushita, J. Cuadros, J. Ye
    • Journal Title

      Applied Clay Science

      Volume: 46 Pages: 55-59

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] 第1原理電子状態計算で熱力学:その第一歩2010

    • Author(s)
      末原茂
    • Journal Title

      金属(アグネ技術センター)

      Volume: 80 Pages: 11-17

    • Related Report
      2011 Final Research Report
  • [Journal Article] Preparation and Properties of Exfoliated Vermiculite-Polyamide 6 Nanocomposite2010

    • Author(s)
      Kenji Tamura, Kazuya Morimoto, Takatsugu Ushirouchi, Hirohisa Yamada, Tamao Hatta, Youhiko Mito
    • Journal Title

      Clay Science

      Volume: 14 Pages: 147-153

    • NAID

      110007641850

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-step conversion of CO32-LDH(layered double hydroxide) into anion-exchangeable LDHs using an acetate-buffer/salt method2010

    • Author(s)
      N.Iyi, H.Yamada
    • Journal Title

      Chemistry Letters

      Volume: 39 Pages: 591-593

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption and photodegradation reactions of anionic dye on Zn-Al-substituted layered double hydroxide2010

    • Author(s)
      K.Morimoto, K.Tamura, J.Ye, H.Yamada
    • Journal Title

      Transaction of the Materials Research Society of Japan

      Volume: 35 Pages: 813-816

    • NAID

      130005004068

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of monodispersed Zn-smectite2010

    • Author(s)
      C.S.Pascua, H.Yamada, M.Ohnuma, K.Tamura, Y.Matsushita, J.Cuadros, J.Ye
    • Journal Title

      Applied Clay Science 48

      Pages: 55-59

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 第1原理電子状態計算で熱力学:その第一歩2010

    • Author(s)
      末原茂
    • Journal Title

      金属(アグネ技術センター) 80

      Pages: 11-17

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Layered Silicate-Polyamide 6 Nano-composites : Influence of Silicate Species on Morphology and Properties2009

    • Author(s)
      K. Tamura, H. Uno, H. Yamada, K. Umeyama
    • Journal Title

      Journal of Polymer Science Part B : Polymer Physics

      Volume: 47 Pages: 583-595

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-assembled silicate nanolayers by Geonics, Trans2009

    • Author(s)
      H. Yamada, K. Tamura, C. S. Pascua, S. Yokoyama, T. Hatta
    • Journal Title

      Mater. Res. Soc. Jpn

      Volume: 34 Pages: 363-366

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Pre-paration and mechanical properties of exfoliated mica-polyamide 6 nano-composites using sericite mica2009

    • Author(s)
      H. Uno, K. Tamura, H Yamada, K. Umeyama, T. Hotta, Y. Moriyoshi
    • Journal Title

      Applied Clay Science

      Volume: 46 Pages: 81-88

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-assembled silicate nanolayers by Geonics2009

    • Author(s)
      H.Yamada, K.Tamura, C.S.Pascua, S.Yokoyama, T.Hatta
    • Journal Title

      Trans.Mater.Res.Soc.Jpn. 34

      Pages: 363-366

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and mechanical properties of exfoliated mica-polyamide 6 nanocomposites using sericite mica2009

    • Author(s)
      H.Uno, K.Tamura, H Yamada, K.Umeyama, T.Hotta, Y.Moriyoshi
    • Journal Title

      Applied Clay Science 46

      Pages: 81-88

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Layered Silicate-Polyamide 6 Nanocomposites : Influence of Silicate Species on Morphology and Properties2009

    • Author(s)
      K.Tamura, H.Uno, H.Yamada, K.Umeyama
    • Journal Title

      Journal of Polymer Science Part B : Polymer Physics 47

      Pages: 583-595

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Virtual-crystal approach to aluminum-avoidance materials : A first-principles density-functional calcula-tion of micas

    • Author(s)
      S. Suehara, H. Yamada, T. Sasaki
    • Journal Title

      Physical Review B

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Presentation] (Fe, Zn)置換サポナイトによるローダミンBの光分解2011

    • Author(s)
      山田裕久,田村堅志,越後拓也,森本和也,八田珠郎
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜情報文化センター,横浜
    • Year and Date
      2011-12-19
    • Related Report
      2011 Final Research Report
  • [Presentation] 溶融混合反応によるブルーサイトへの糖アルコールのインターカレーション2011

    • Author(s)
      田村堅志,森本和也,八田珠郎,山田裕久
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜情報文化センター,横浜
    • Year and Date
      2011-12-19
    • Related Report
      2011 Final Research Report
  • [Presentation] (Fe,Zn)置換サポナイトによるローダミンBの光分解2011

    • Author(s)
      山田裕久, 田村堅志, 越後拓也, 森本和也, 八田珠郎
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜情報文化センター(横浜)
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 溶融混合反応によるブルーサイトへの糖アルコールのインターカレーション2011

    • Author(s)
      田村堅志, 森本和也, 八田珠郎, 山田裕久
    • Organizer
      第21回日本MRS学術シンポジウム
    • Place of Presentation
      横浜情報文化センター(横浜)
    • Year and Date
      2011-12-19
    • Related Report
      2011 Annual Research Report
  • [Presentation] 第1原理計算による無水粘土鉱物の層間イオン交換エネルギー2011

    • Author(s)
      末原茂,佐々木泰造,山田裕久
    • Organizer
      第55回粘土科学討論会
    • Place of Presentation
      鹿児島大学,鹿児島
    • Year and Date
      2011-09-15
    • Related Report
      2011 Final Research Report
  • [Presentation] 第1原理計算による無水粘土鉱物の層間イオン交換エネルギー2011

    • Author(s)
      末原茂, 佐々木泰造, 山田裕久
    • Organizer
      第55回粘土科学討論会
    • Place of Presentation
      鹿児島大学(鹿児島)
    • Year and Date
      2011-09-15
    • Related Report
      2011 Annual Research Report
  • [Presentation] Photocatalytic properties of synthetic(Fe, Zn)-substituted saponite2011

    • Author(s)
      H. Yamada, K. Tamura, K. Morimoto and T. Hatta
    • Organizer
      Euroclay2011
    • Place of Presentation
      Antalya, Turkey
    • Year and Date
      2011-06-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Photocatalytic Properties of Synthetic (Fe, Zn)-substituted Saponites2011

    • Author(s)
      H.Yamada, K.Tamura, K.Morimoto, T.Hatta
    • Organizer
      Euroclay2011
    • Place of Presentation
      Dedeman Hotel (Antalya, TURKEY)
    • Year and Date
      2011-06-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of Photocatalytic Clay Minerals2011

    • Author(s)
      H. Yamada, K. Tamura, K. Morimoto & J. Ye
    • Organizer
      1st Korean Clay Workshop 2011
    • Place of Presentation
      Ewha Womans University,韓国
    • Year and Date
      2011-05-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Development of Photocatalytic Clay Minerals2011

    • Author(s)
      H.Yamada, K.Tamura, K.Morimoto, J.Ye
    • Organizer
      1st Korean Clay Workshop 2011
    • Place of Presentation
      Ewha Womans University(ソウル・韓国)(招待講演)
    • Year and Date
      2011-05-02
    • Related Report
      2011 Annual Research Report
  • [Presentation] 有機セリサイトのステージング挙動2010

    • Author(s)
      田村堅志,八田珠郎,道上勇一,森本和也,山田裕久
    • Organizer
      第54回粘土科学討論会
    • Place of Presentation
      名古屋大学,愛知県
    • Year and Date
      2010-09-07
    • Related Report
      2011 Final Research Report
  • [Presentation] 有機セリサイトのステージング挙動2010

    • Author(s)
      田村堅志
    • Organizer
      第54回粘土科学討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2010-09-07
    • Related Report
      2010 Annual Research Report
  • [Presentation] Photocatalytic degradation of Rhodamine B in water by synthetic Zn-substituted phyllo-silicates2010

    • Author(s)
      H. Yamada, K. Morimoto, K. Tamura, C. S. Pascua, & T. Hatta
    • Organizer
      5th Mid-European Clay Conference
    • Place of Presentation
      Eotvos Lorand Univ. Hungary
    • Year and Date
      2010-08-27
    • Related Report
      2011 Final Research Report
  • [Presentation] Photocatalytic degradation of Rhodamine B in water by synthetic Zn-substituted phyllosilicates2010

    • Author(s)
      H.Yamada, K.Morimoto, K.Tamura, C.S.Pascua, T.Hatta
    • Organizer
      5th Mid-European Clay Conference
    • Place of Presentation
      Eotvos Lorand University(ハンガリー)
    • Year and Date
      2010-08-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesisi and Characteri-zation of Phyllosilicates in montmorillonite-stevensite compositional series2010

    • Author(s)
      H. Yamada, K. Tamura, K. Morimoto, S. Yokoyama & T. Hatta
    • Organizer
      2010 Trilateral Meeting on Clays(SEA, CSSJ, CMS)
    • Place of Presentation
      Hotel Melia Sevilla, Spain
    • Year and Date
      2010-06-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Polymer nanocomposite using a second-staged alkylammonium-sericite complex2010

    • Author(s)
      K. Tamura, T. Hatta, H. Yamada
    • Organizer
      2010 Trilateral Meeting on Clays(SEA, CSSJ, CMS)
    • Place of Presentation
      Hotel Melia Sevilla, Spain
    • Year and Date
      2010-06-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Polymer nanocomposite using a second-staged alkylammonium-sericite complex2010

    • Author(s)
      田村堅志
    • Organizer
      2010 Trilateral Meeting on Clays(SEA, CSSJ, CMS)
    • Place of Presentation
      Hotel Melia Sevilla(スペイン)
    • Year and Date
      2010-06-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] SYNTHESIS AND CHARACTERIZATION OF PHYLLOSILICATES IN MONTMORILLONITE-STEVENSITE COMPOSITIONAL SERIES2010

    • Author(s)
      H.Yamada, K.Tamura, K.Morimoto, S.Yokoyama, T.Hatta
    • Organizer
      2010 Trilateral Meeting on Clays(SEA, CSSJ, CMS)
    • Place of Presentation
      Hotel Melia Sevilla(スペイン)
    • Year and Date
      2010-06-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 粘土:古くて新しい素材2010

    • Author(s)
      山田裕久
    • Organizer
      耐火物の基礎学問と検査技術研修
    • Place of Presentation
      岡山セラミックスセンター、備前市
    • Year and Date
      2010-05-17
    • Related Report
      2011 Final Research Report 2010 Annual Research Report
  • [Presentation] Hydrothermal Syntheses of Interstratified Clay Minerals from(K, Na)-Montmorillonite Glass2009

    • Author(s)
      H. Yamada, S. Yokoyama, K. Tamura, Y. Watanabe
    • Organizer
      The 26th International Japan-Korea Seminar on Ceramics
    • Place of Presentation
      つくば国際会議場,つくば
    • Year and Date
      2009-11-24
    • Related Report
      2011 Final Research Report
  • [Presentation] Hydrothermal Syntheses of Interstratified Clay Minerals from (K, Na)-Montmorillonite Glass2009

    • Author(s)
      H.Yamada, S.Yokoyama, K.Tamura, Y.Watanabe
    • Organizer
      The 26th International Japan-Korea Seminar on Ceramics
    • Place of Presentation
      つくば国際会議場,Tsukuba, Japan
    • Year and Date
      2009-11-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] 3八面体型バーミキュライト様相の合成と特徴づけ2009

    • Author(s)
      山田裕久,田村堅志,横山信吾,渡辺雄二郎,八田珠郎
    • Organizer
      第53回粘土科学討論会
    • Place of Presentation
      岩手大学、岩手県盛岡市
    • Year and Date
      2009-09-09
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Virtual Crystal近似による雲母の第1原理計算2009

    • Author(s)
      末原茂、山田裕久、田村堅志、佐々木泰造
    • Organizer
      第53回粘土科学討論会
    • Place of Presentation
      岩手大学、岩手県盛岡市
    • Year and Date
      2009-09-09
    • Related Report
      2011 Final Research Report 2009 Annual Research Report
  • [Presentation] Synthesis of Trioctahedral Phyllo-silicates in Sodium Saponite. Phlo-gopite system2009

    • Author(s)
      H. Yamada, K. Tamura, S. Yokoyama
    • Organizer
      14ICC-International Clay Conference Italy 2009
    • Place of Presentation
      Nova Yardinia venue, Italy
    • Year and Date
      2009-06-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Preparation of Regularly Interstratified Layered Silicate-Polymer Nanocomposite2009

    • Author(s)
      K. Tamura, H. Yamada, S. Yokoyama, K. Kurashima
    • Organizer
      14th ICC
    • Place of Presentation
      Nova Yardinia venue, Italy
    • Year and Date
      2009-06-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Synthesis of Trioctahedral Phyllosilicates in Sodium Saponite-Phlogopite system2009

    • Author(s)
      H.Yamada, K.Tamura, S.Yokoyama
    • Organizer
      14ICC-International Clay Conference Italy 2009
    • Place of Presentation
      Nova Yardinia venue, Italy
    • Year and Date
      2009-06-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Preparation of Regularly Interstratified Layered Silicate-Polymer Nanocomposite2009

    • Author(s)
      K.Tamura, H.Yamada, S.Yokoyama, K.Kurashima
    • Organizer
      14ICC-International Clay Conference Italy 2009
    • Place of Presentation
      Nova Yardinia venue, Italy
    • Year and Date
      2009-06-16
    • Related Report
      2009 Annual Research Report
  • [Book] Clayteam技術解説書2011

    • Author(s)
      山田裕久・田村堅志・森本和也
    • Publisher
      産業技術総合研究所
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Book] 環境・エネルギーハンドブック2011

    • Author(s)
      山田裕久
    • Publisher
      オーム社
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
  • [Book] Optimization of Polymer Nanocomposite Properties2010

    • Author(s)
      K. Tamura and H. Yamada
    • Publisher
      Wiley-VCH
    • Related Report
      2011 Final Research Report
  • [Book] 機能性粘土素材の最新動向2010

    • Author(s)
      田村堅志,山田裕久
    • Publisher
      シーエムシー出版
    • Related Report
      2011 Final Research Report
  • [Book] Morphology Control Technique Using Various Layered Silicates for Polymer Nanocomposites, Chap.15, In Optimization of Polymer Nanocomposite Properties2010

    • Author(s)
      Kenji Tamura, Hirohisa Yamada
    • Publisher
      Wiley-VCH
    • Related Report
      2010 Annual Research Report
  • [Book] 「樹脂添加物」,第3章,『機能性粘土素材の最新動向』(第III編 素材としての粘土鉱物応用)2010

    • Author(s)
      田村堅志, 山田裕久
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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