Project/Area Number |
21655030
|
Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
Allocation Type | Single-year Grants |
Research Field |
Analytical chemistry
|
Research Institution | Sophia University |
Principal Investigator |
|
Co-Investigator(Kenkyū-buntansha) |
ENDO Akira 上智大学, 理工学部, 准教授 (00119124)
HASHIMOTO Takeshi 上智大学, 理工学部, 助教 (20333049)
|
Project Period (FY) |
2009 – 2011
|
Project Status |
Completed (Fiscal Year 2011)
|
Budget Amount *help |
¥3,370,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥900,000 (Direct Cost: ¥900,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,300,000)
|
Keywords | 糖鎖 / 識別機能 / アゾ色素 / 化学センサー / ボロン酸 / デンドリマー / 超分子 |
Research Abstract |
In this study, we have developed new types of sugar recognition systems based upon self-assembly of boronic acid azoprobes or ruthenium complexes on the surface of polyamide amine dendrimer(PAMAM). The generation of PAMAM and the sugar species were found to selectively affect the UV-vis and electrochemical responses of phenylboronic acid probe/dendrimer complexes, providing a novel chemosensor functioned in water.
|