Separation and recovery technology for rare metal from process solution using layered double hydroxides modified with organic materials

• Project/Area Number: 21681007
• Research Category: Grant-in-Aid for Young Scientists (A)
• Allocation Type: Single-year Grants
• Research Field: Environmental technology/Environmental materials
• Research Institution: Tohoku University
• Principal Investigator: KAMEDA Tomohito 東北大学, 大学院・工学研究科, 准教授 (60333895)
• Project Period (FY): 2009 – 2012
• Project Status: Completed (Fiscal Year 2012)
• Budget Amount: ¥25,480,000 (Direct Cost: ¥19,600,000、Indirect Cost: ¥5,880,000); Fiscal Year 2012: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2011: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000); Fiscal Year 2010: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000); Fiscal Year 2009: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
• Keywords: 環境負荷低減技術 / 層状複水酸化物 / 有機酸アニオン / 金属イオン / キレート錯体形成 / 捕捉 / 溶解 / 架橋構造 / 有機修飾 / 銅-アルミニウム系 / 速度論 / 平衡論 / 生成物層内拡散律速 / Langmuir / キレート剤 / レアアース / 選択性 / 速度解析 / 化学反応律速 / 活性化エネルギー

Research Abstract

This study has clarified that layered double hydroxidesintercalated with organic acid anions with the ability of chelate complex formation couldtake up rare metal ions from an aqueous solution. The material has uptake selectivityof rare metal ions. This reaction is under chemical reaction control.

Research Products

• [Journal Article] Preparation of Cu-Al layered double hydroxide intercalated with ethylenediaminetetraacetate bycoprecipitation and its uptake of rare earth ions from aqueous solution (2013)
  • Author(s): Tomohito Kameda, Kazuaki Hoshi, and Toshiaki Yoshioka
  • Journal Title: Solid State Sciences Volume: 17 Pages: 28-34
  • Peer Reviewed
• [Journal Article] Preparation of Cu-Al layered double hydroxide intercalated with ethylenediaminetetraacetate by coprecipitation and its uptake of rare earth ions from aqueous solution (2013)
  • Author(s): Tomohito Kameda, Kazuaki Hoshi, and Toshiaki Yoshioka
  • Journal Title: Solid State Sciences Volume: 17 Pages: 28-34
  • Peer Reviewed
• [Journal Article] Thermal decomposition behavior of Cu-Al layered double hydroxide, and ethylenediaminetetraacetate-intercalated Cu-Al layered double hydroxide reconstructed from Cu-Al oxide for uptake of Y^<3+> from aqueous solution (2012)
  • Author(s): Tomohito Kameda, Kazuaki Hoshi, Toshiaki Yoshioka
  • Journal Title: Materials Research Bulletin Volume: 47 Pages: 4216-4219
  • Peer Reviewed
• [Journal Article] Thermal decomposition behavior of Cu–Al layered double hydroxide, and ethylenediaminetetraacetate-intercalated Cu–Al layered double hydroxide reconstructed from Cu–Al oxide for uptake of Y3+ from aqueous solution (2012)
  • Author(s): Tomohito Kameda, Kazuaki Hoshi, Toshiaki Yoshioka
  • Journal Title: Materials Research Bulletin Volume: 47 Pages: 4216-4219
  • Peer Reviewed
• [Journal Article] 有機修飾層状複水酸化物による重金属イオンの捕捉 (2012)
  • Author(s): 亀田知人, 吉岡敏明
  • Journal Title: Journal of the Society of Inorganic Materials, Japan Volume: 19 Pages: 126-132
  • NAID: 10030141398
  • Peer Reviewed
• [Journal Article] Ni-Al layered double hydroxides modified with citrate, malate, andtartrate: Preparation by coprecipitation and uptake of Cu2+ from aqueous solution (2011)
  • Author(s): Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
  • Journal Title: Journal of Physics and Chemistry of Solids Volume: 72 Pages: 846-851
  • Peer Reviewed
• [Journal Article] Uptake of Sc^<3+> and La^<3+> from aqueoussolution using ethylenediaminetetraacetate-intercalated Cu-Al layered double hydroxide reconstructed from Cu-Al oxide (2011)
  • Author(s): Tomohito Kameda, Kazuaki Hoshi, Toshiaki Yoshioka
  • Journal Title: Solid State Sciences Volume: 13 Pages: 366-371
  • Peer Reviewed
• [Journal Article] Ni-Al layered double hydroxides modified with citrate, malate, and tartrate : Preparation by coprecipitation and uptake of Cu^<2+> from aqueous solution (2011)
  • Author(s): Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
  • Journal Title: Journal of Physics and Chemistry of Solids Volume: 72 Pages: 846-851
  • Peer Reviewed
• [Journal Article] Uptake of Sc^<3+> and La^<3+> from aqueous solution using ethylenediaminetetra acetate-intercalated Cu-Al layered double hydroxide reconstructed from Cu-Al oxide (2011)
  • Author(s): Tomohito Kameda, Kazuaki Hoshi, Toshiaki Yoshioka
  • Journal Title: Solid State Sciences Volume: 13 Pages: 366-371
  • Peer Reviewed
• [Journal Article] Kinetics of uptake of Cu2+ and Cd2+ by Mg-Al layered double hydroxides intercalated with citrate, malate, and tartrate (2010)
  • Author(s): Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
  • Journal Title: Colloids and Surfaces A: Physicochemical and Engineering Aspects Volume: 355 Pages: 172-177
  • Peer Reviewed
• [Journal Article] Kinetics of uptake of Cu^<2+> and Cd^<2+> by Mg-Al layered double hydroxides intercalated with citrate, malate, and tartrate (2010)
  • Author(s): Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
  • Journal Title: Colloids and Surfaces A : Physicochemical and Engineering Aspects 355 Pages: 172-177
  • Peer Reviewed
• [Journal Article] Preparation of organic acid anion-modified magnesium hydroxides by coprecipitation: A novel material for theuptake of heavy metal ions from aqueous solutions (2009)
  • Author(s): Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
  • Journal Title: Journal of Physics and Chemistry of Solids Volume: 70 Pages: 1104-1108
  • Peer Reviewed
• [Journal Article] Preparation of organic acid anion-modified magnesium hydroxides by coprecipitation : A novel material for the uptake of heavy metal ions from aqueous solutions (2009)
  • Author(s): Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
  • Journal Title: Journal of Physics and Chemistry of Solids 70 Pages: 1104-1108
  • Peer Reviewed
• [Presentation] 有機修飾層状複水酸化物による水溶液からの有害物質の捕捉 (2012)
  • Author(s): 亀田知人,吉岡敏明
  • Organizer: 廃棄物資源循環学会東北支部第4回研究発表会
  • Place of Presentation: 仙台
  • Year and Date: 2012-01-27
• [Presentation] edta型Cu-Al系層状複水酸化物を用いたキレート錯体生成によるレアアースの捕捉 (2011)
  • Author(s): 星和暁,亀田知人,吉岡敏明
  • Organizer: 無機マテリアル学会第123回学術講演会
  • Place of Presentation: 佐賀
  • Year and Date: 2011-11-17
• [Presentation] Uptake of rare earth metal from aqueous solution using copper-aluminium layered double hydroxides intercalated with EDTA (2011)
  • Author(s): K. Hoshi, T. Kameda, T. Yoshioka
  • Organizer: 16th International Symposium on Intercalation Compounds (ISIC16)
  • Place of Presentation: Sec-Ustupky, Czech Republic
  • Year and Date: 2011-05-24
• [Presentation] Uptake of rare earth metal from aqueous solution using copper-aluminium layered double hydroxides intercalated with EDTA (2011)
  • Author(s): K.Hoshi, T.Kameda, T.Yoshioka
  • Organizer: 16^<th> International Symposium on Intercalation Compounds (ISIC16)
  • Place of Presentation: Sec-Ustupky, Czech Republic
  • Year and Date: 2011-05-24
• [Presentation] edta型Cu-Al系層状複水酸化物による水溶液からのレアアースの回収 (2011)
  • Author(s): 星和暁,亀田知人,吉岡敏明
  • Organizer: 日本化学会第91春季年会,講演予稿集
  • Year and Date: 2011-03-11
• [Presentation] edta型Cu-Al系層状複水酸化物による水溶液からのレアアースの回収 (2011)
  • Author(s): 星和暁, 亀田知人, 吉岡敏明
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: (講演予稿集)
  • Year and Date: 2011-03-11
• [Presentation] edta型Cu-Al系層状複水酸化物によるSc^<3+>およびLa^<3+>の捕捉 (2010)
  • Author(s): 星和暁,亀田知人,吉岡敏明
  • Organizer: 無機マテリアル学会第121回学術講演会
  • Place of Presentation: 仙台
  • Year and Date: 2010-11-04
• [Presentation] edta型Cu-Al系層状複水酸化物によるSc^<3+>およびLa^<3+>の捕捉 (2010)
  • Author(s): 星和暁, 亀田知人, 吉岡敏明
  • Organizer: 無機マテリアル学会第121回学術講演会
  • Place of Presentation: 仙台,東北大学
  • Year and Date: 2010-11-04
• [Presentation] UPTAKE OF HEAVY METAL IONS FROM AQUEOUS SOLUTION BY Mg-Al LAYERED DOUBLE HYDROXIDES INTERCALATED WITH ORGANIC ACID ANIONS, AND ITS KINETICS (2010)
  • Author(s): T. Kameda, H. Takeuchi, T. Yoshioka
  • Organizer: 2010 SEA-CSSJ-CMS Trilateral Meeting on Clays (2010TMC)
  • Place of Presentation: Seville, Spain
  • Year and Date: 2010-06-10
• [Presentation] UPTAKE OF HEAVY METAL IONS FROM AQUEOUS SOLUTION BY Mg-Al LAYERED DOUBLE HYDROXIDES INTERCALATED WITH ORGANIC ACID ANIONS, AND ITS KINETICS (2010)
  • Author(s): T.Kameda, H.Takeuchi, T.Yoshioka
  • Organizer: 2010 SEA-CSSJ-CMS Trilateral Meeting on Clays (2010TMC)
  • Place of Presentation: セビリア,スペイン
  • Year and Date: 2010-06-10
• [Presentation] 有機修飾層状複水酸化物の合成と水環境保全・浄化への応用 (2009)
  • Author(s): 亀田知人
  • Organizer: 平成21年度化学系学協会東北大会
  • Place of Presentation: 郡山
  • Year and Date: 2009-09-19
• [Presentation] 有機修飾層状複水酸化物の合成と水環境保全・浄化への応用 (2009)
  • Author(s): 亀田知人
  • Organizer: 平成21年度化学系学協会東北大会
  • Place of Presentation: 郡山, 日本大学工学部
  • Year and Date: 2009-09-19
• [Book] Hybrid Inorganic-organic Composites of Layered Double Hydroxides Intercalated with Organic Acid Anions for the Uptake of Hazardous Substances from Aqueous Solution (2011)
  • Author(s): Tomohito Kameda, Toshiaki Yoshioka, METAL, CERAMIC AND POLYMERIC COMPOSITES FOR VARIOUS USES, INTECH
  • Publisher: Chapter 6
• [Book] METAL, CERAMIC AND POLYMERIC COMPOSITES FOR VARIOUS USES (2011)
  • Author(s): Tomohito Kameda, Toshiaki Yoshioka, 他
  • Publisher: INTECH