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Separation and recovery technology for rare metal from process solution using layered double hydroxides modified with organic materials

Research Project

Project/Area Number 21681007
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Environmental technology/Environmental materials
Research InstitutionTohoku University

Principal Investigator

KAMEDA Tomohito  東北大学, 大学院・工学研究科, 准教授 (60333895)

Project Period (FY) 2009 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥25,480,000 (Direct Cost: ¥19,600,000、Indirect Cost: ¥5,880,000)
Fiscal Year 2012: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2011: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2010: ¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2009: ¥9,100,000 (Direct Cost: ¥7,000,000、Indirect Cost: ¥2,100,000)
Keywords環境負荷低減技術 / 層状複水酸化物 / 有機酸アニオン / 金属イオン / キレート錯体形成 / 捕捉 / 溶解 / 架橋構造 / 有機修飾 / 銅-アルミニウム系 / 速度論 / 平衡論 / 生成物層内拡散律速 / Langmuir / キレート剤 / レアアース / 選択性 / 速度解析 / 化学反応律速 / 活性化エネルギー
Research Abstract

This study has clarified that layered double hydroxidesintercalated with organic acid anions with the ability of chelate complex formation couldtake up rare metal ions from an aqueous solution. The material has uptake selectivityof rare metal ions. This reaction is under chemical reaction control.

Report

(5 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • 2009 Annual Research Report
  • Research Products

    (27 results)

All 2013 2012 2011 2010 2009

All Journal Article (13 results) (of which Peer Reviewed: 13 results) Presentation (12 results) Book (2 results)

  • [Journal Article] Preparation of Cu-Al layered double hydroxide intercalated with ethylenediaminetetraacetate bycoprecipitation and its uptake of rare earth ions from aqueous solution2013

    • Author(s)
      Tomohito Kameda, Kazuaki Hoshi, and Toshiaki Yoshioka
    • Journal Title

      Solid State Sciences

      Volume: 17 Pages: 28-34

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Cu-Al layered double hydroxide intercalated with ethylenediaminetetraacetate by coprecipitation and its uptake of rare earth ions from aqueous solution2013

    • Author(s)
      Tomohito Kameda, Kazuaki Hoshi, and Toshiaki Yoshioka
    • Journal Title

      Solid State Sciences

      Volume: 17 Pages: 28-34

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermal decomposition behavior of Cu-Al layered double hydroxide, and ethylenediaminetetraacetate-intercalated Cu-Al layered double hydroxide reconstructed from Cu-Al oxide for uptake of Y^<3+> from aqueous solution2012

    • Author(s)
      Tomohito Kameda, Kazuaki Hoshi, Toshiaki Yoshioka
    • Journal Title

      Materials Research Bulletin

      Volume: 47 Pages: 4216-4219

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Thermal decomposition behavior of Cu–Al layered double hydroxide, and ethylenediaminetetraacetate-intercalated Cu–Al layered double hydroxide reconstructed from Cu–Al oxide for uptake of Y3+ from aqueous solution2012

    • Author(s)
      Tomohito Kameda, Kazuaki Hoshi, Toshiaki Yoshioka
    • Journal Title

      Materials Research Bulletin

      Volume: 47 Pages: 4216-4219

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 有機修飾層状複水酸化物による重金属イオンの捕捉2012

    • Author(s)
      亀田知人, 吉岡敏明
    • Journal Title

      Journal of the Society of Inorganic Materials, Japan

      Volume: 19 Pages: 126-132

    • NAID

      10030141398

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Ni-Al layered double hydroxides modified with citrate, malate, andtartrate: Preparation by coprecipitation and uptake of Cu2+ from aqueous solution2011

    • Author(s)
      Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 72 Pages: 846-851

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Uptake of Sc^<3+> and La^<3+> from aqueoussolution using ethylenediaminetetraacetate-intercalated Cu-Al layered double hydroxide reconstructed from Cu-Al oxide2011

    • Author(s)
      Tomohito Kameda, Kazuaki Hoshi, Toshiaki Yoshioka
    • Journal Title

      Solid State Sciences

      Volume: 13 Pages: 366-371

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Ni-Al layered double hydroxides modified with citrate, malate, and tartrate : Preparation by coprecipitation and uptake of Cu^<2+> from aqueous solution2011

    • Author(s)
      Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 72 Pages: 846-851

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Uptake of Sc^<3+> and La^<3+> from aqueous solution using ethylenediaminetetra acetate-intercalated Cu-Al layered double hydroxide reconstructed from Cu-Al oxide2011

    • Author(s)
      Tomohito Kameda, Kazuaki Hoshi, Toshiaki Yoshioka
    • Journal Title

      Solid State Sciences

      Volume: 13 Pages: 366-371

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics of uptake of Cu2+ and Cd2+ by Mg-Al layered double hydroxides intercalated with citrate, malate, and tartrate2010

    • Author(s)
      Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: 355 Pages: 172-177

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics of uptake of Cu^<2+> and Cd^<2+> by Mg-Al layered double hydroxides intercalated with citrate, malate, and tartrate2010

    • Author(s)
      Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
    • Journal Title

      Colloids and Surfaces A : Physicochemical and Engineering Aspects 355

      Pages: 172-177

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of organic acid anion-modified magnesium hydroxides by coprecipitation: A novel material for theuptake of heavy metal ions from aqueous solutions2009

    • Author(s)
      Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
    • Journal Title

      Journal of Physics and Chemistry of Solids

      Volume: 70 Pages: 1104-1108

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of organic acid anion-modified magnesium hydroxides by coprecipitation : A novel material for the uptake of heavy metal ions from aqueous solutions2009

    • Author(s)
      Tomohito Kameda, Hidenori Takeuchi, Toshiaki Yoshioka
    • Journal Title

      Journal of Physics and Chemistry of Solids 70

      Pages: 1104-1108

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 有機修飾層状複水酸化物による水溶液からの有害物質の捕捉2012

    • Author(s)
      亀田知人,吉岡敏明
    • Organizer
      廃棄物資源循環学会東北支部第4回研究発表会
    • Place of Presentation
      仙台
    • Year and Date
      2012-01-27
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] edta型Cu-Al系層状複水酸化物を用いたキレート錯体生成によるレアアースの捕捉2011

    • Author(s)
      星和暁,亀田知人,吉岡敏明
    • Organizer
      無機マテリアル学会第123回学術講演会
    • Place of Presentation
      佐賀
    • Year and Date
      2011-11-17
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Uptake of rare earth metal from aqueous solution using copper-aluminium layered double hydroxides intercalated with EDTA2011

    • Author(s)
      K. Hoshi, T. Kameda, T. Yoshioka
    • Organizer
      16th International Symposium on Intercalation Compounds (ISIC16)
    • Place of Presentation
      Sec-Ustupky, Czech Republic
    • Year and Date
      2011-05-24
    • Related Report
      2012 Final Research Report
  • [Presentation] Uptake of rare earth metal from aqueous solution using copper-aluminium layered double hydroxides intercalated with EDTA2011

    • Author(s)
      K.Hoshi, T.Kameda, T.Yoshioka
    • Organizer
      16^<th> International Symposium on Intercalation Compounds (ISIC16)
    • Place of Presentation
      Sec-Ustupky, Czech Republic
    • Year and Date
      2011-05-24
    • Related Report
      2011 Annual Research Report
  • [Presentation] edta型Cu-Al系層状複水酸化物による水溶液からのレアアースの回収2011

    • Author(s)
      星和暁,亀田知人,吉岡敏明
    • Organizer
      日本化学会第91春季年会,講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2012 Final Research Report
  • [Presentation] edta型Cu-Al系層状複水酸化物による水溶液からのレアアースの回収2011

    • Author(s)
      星和暁, 亀田知人, 吉岡敏明
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      (講演予稿集)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] edta型Cu-Al系層状複水酸化物によるSc^<3+>およびLa^<3+>の捕捉2010

    • Author(s)
      星和暁,亀田知人,吉岡敏明
    • Organizer
      無機マテリアル学会第121回学術講演会
    • Place of Presentation
      仙台
    • Year and Date
      2010-11-04
    • Related Report
      2012 Final Research Report
  • [Presentation] edta型Cu-Al系層状複水酸化物によるSc^<3+>およびLa^<3+>の捕捉2010

    • Author(s)
      星和暁, 亀田知人, 吉岡敏明
    • Organizer
      無機マテリアル学会第121回学術講演会
    • Place of Presentation
      仙台,東北大学
    • Year and Date
      2010-11-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] UPTAKE OF HEAVY METAL IONS FROM AQUEOUS SOLUTION BY Mg-Al LAYERED DOUBLE HYDROXIDES INTERCALATED WITH ORGANIC ACID ANIONS, AND ITS KINETICS2010

    • Author(s)
      T. Kameda, H. Takeuchi, T. Yoshioka
    • Organizer
      2010 SEA-CSSJ-CMS Trilateral Meeting on Clays (2010TMC)
    • Place of Presentation
      Seville, Spain
    • Year and Date
      2010-06-10
    • Related Report
      2012 Final Research Report
  • [Presentation] UPTAKE OF HEAVY METAL IONS FROM AQUEOUS SOLUTION BY Mg-Al LAYERED DOUBLE HYDROXIDES INTERCALATED WITH ORGANIC ACID ANIONS, AND ITS KINETICS2010

    • Author(s)
      T.Kameda, H.Takeuchi, T.Yoshioka
    • Organizer
      2010 SEA-CSSJ-CMS Trilateral Meeting on Clays (2010TMC)
    • Place of Presentation
      セビリア,スペイン
    • Year and Date
      2010-06-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機修飾層状複水酸化物の合成と水環境保全・浄化への応用2009

    • Author(s)
      亀田知人
    • Organizer
      平成21年度化学系学協会東北大会
    • Place of Presentation
      郡山
    • Year and Date
      2009-09-19
    • Related Report
      2012 Final Research Report
  • [Presentation] 有機修飾層状複水酸化物の合成と水環境保全・浄化への応用2009

    • Author(s)
      亀田知人
    • Organizer
      平成21年度化学系学協会東北大会
    • Place of Presentation
      郡山, 日本大学工学部
    • Year and Date
      2009-09-19
    • Related Report
      2009 Annual Research Report
  • [Book] Hybrid Inorganic-organic Composites of Layered Double Hydroxides Intercalated with Organic Acid Anions for the Uptake of Hazardous Substances from Aqueous Solution2011

    • Author(s)
      Tomohito Kameda, Toshiaki Yoshioka, METAL, CERAMIC AND POLYMERIC COMPOSITES FOR VARIOUS USES, INTECH
    • Publisher
      Chapter 6
    • Related Report
      2012 Final Research Report
  • [Book] METAL, CERAMIC AND POLYMERIC COMPOSITES FOR VARIOUS USES2011

    • Author(s)
      Tomohito Kameda, Toshiaki Yoshioka, 他
    • Publisher
      INTECH
    • Related Report
      2011 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2019-07-29  

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