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Highly efficient removal and degradation of toxic compounds with novel host molecule-metal ion complexes having enzyme-like activities

Research Project

Project/Area Number 21710078
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental technology/Environmental materials
Research InstitutionNagoya University

Principal Investigator

MATSUMIYA Hiroaki  Nagoya University, 工学研究科, 助教 (10362287)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywordsチアカリックスアレーン / セリウム / 界面活性剤 / アドミセル / 有機リン系農薬 / カーバメイト系農薬 / エステル加水分解 / 複核錯体
Research Abstract

The present study was conducted with a view to developing highly efficient environmental purification systems by which the removal and subsequent detoxification of hazardous chemicals can be achieved with novel host molecule-metal ion complexes having enzyme-like activities. Taking organophosphate (e.g., fenitrothion, dichlorvos, and paraoxon) and carbamate (e.g., carbaryl and propoxur) pesticides as examples, their removal from water, followed by the hydrolytic degradation to reduce their neurotoxicity, was examined. The obtained results provide guidelines for the further design and development of environmental purification materials and systems for practical use.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (14 results)

All 2010 2009

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (10 results)

  • [Journal Article] Catalytic degradation of organophosphates and carbamates with cerium(IV)-thiacalix[4]arene complexes2010

    • Author(s)
      H.Matsumiya, H.Ishima, H.Nakamura, M.Hiraide
    • Journal Title

      Proceedings of International Conference on Environment CD-ROM

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic degradation of organophosphates and carbamates with cerium(IV)-thiacalix[4]arene complexes2010

    • Author(s)
      Hiroaki Matsumiya, Hayato Ishima, Hiroko Nakamura, Masataka Hiraide
    • Journal Title

      Proceedings of International Conference on Environment 2010

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phosphoester hydrolysis by cerium(IV)-thiacalix[4]arene complexes and its application to immunoassay2009

    • Author(s)
      H.Matsumiya, H.Nakamura, M.Hiraide
    • Journal Title

      Analytical and Bioanalytical Chemistry Vol.394, No.5

      Pages: 1471-1476

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phosphoester hydrolysis by cerium(IV)-thiacalix[4]arene complexes and its application to immunoassay2009

    • Author(s)
      Hiroaki Matsumiya, Hiroko Nakamura, Masataka Hiraide
    • Journal Title

      Analytical and Bioanalytical Chemistry 394

      Pages: 1471-1476

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] Catalytic degradation of organophosphates and carbamates with cerium(IV)-thiacalix[4]arene complexes2010

    • Author(s)
      H.Matsumiya, H.Ishima, H.Nakamura, M.Hiraide
    • Organizer
      International Conference on Environment 2010
    • Place of Presentation
      Park Royal Hotel (Penang, Malaysia)
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] アドミセルを用いる水中フェニトロチオンの捕集と触媒的加水分解2010

    • Author(s)
      石間早翔, 松宮弘明, 平出正孝
    • Organizer
      第29回溶媒抽出討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 界面活性剤によるチアカリックスアレーン金属錯体の触媒能向上とイムノアッセイの高感度化2010

    • Author(s)
      福島浩之, 永井真二, 松宮弘明, 平出正孝
    • Organizer
      第29回溶媒抽出討論会
    • Place of Presentation
      広島大学東広島キャンパス(広島県東広島市)
    • Related Report
      2010 Final Research Report
  • [Presentation] Extraction of trace constituents with hydrophobic aggregates for water analysis2010

    • Author(s)
      M.Hiraide, T.Saitoh, H.Matsumiya
    • Organizer
      The 5th International Conference on Ion Exchange
    • Place of Presentation
      The University of Melbourne (Melbourne, Australia)
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Collection of trace metals with admicelles and the subsequent flotation for environmental water analysis2009

    • Author(s)
      H.Matsumiya, Y.Yatsuya, K.Kitakata, M.Hiraide
    • Organizer
      The 3rd Asian Conference on Colloids and Interface Science
    • Place of Presentation
      International Convention Center Jeju (Seogwipo, Korea)
    • Related Report
      2010 Final Research Report
  • [Presentation] カチオン界面活性剤を増感剤とするチアカリックスアレーン錯体によるイムノアッセイ2009

    • Author(s)
      松宮弘明, 永井真二, 平出正孝
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(北海道札幌市)
    • Related Report
      2010 Final Research Report
  • [Presentation] アドミセルおよびチアカリックスアレーン金属錯体を用いる農薬成分の捕集と分解2009

    • Author(s)
      石間早翔, 松宮弘明, 平出正孝
    • Organizer
      第70回分析化学討論会
    • Place of Presentation
      和歌山大学栄谷キャンパス(和歌山県和歌山市)
    • Related Report
      2010 Final Research Report
  • [Presentation] アドミセルおよびチアカリックスアレーン金属錯体を用いる農薬成分の捕集と分解2009

    • Author(s)
      石間早翔、松宮弘明、平出正孝
    • Organizer
      第70回分析化学討論会
    • Place of Presentation
      和歌山大学栄谷キャンパス(和歌山)
    • Related Report
      2009 Annual Research Report
  • [Presentation] カチオン界面活性剤を増感剤とするチアカリックスアレーン錯体によるイムノアツセイ2009

    • Author(s)
      松宮弘明、永井真二、平出正孝
    • Organizer
      日本分析化学会第58年会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(札幌)
    • Related Report
      2009 Annual Research Report
  • [Presentation] Collection of trace metals with admicelles and the subsequent flotation for environmental water analysis2009

    • Author(s)
      Hiroaki Matsumiya, Yosuke Yatsuya, Kengo Kitakata, Masataka Hiraide
    • Organizer
      The 3rd Asian Conference on Colloids and Interface Science
    • Place of Presentation
      International Convention Center Jeju (Korea)
    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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