| Project/Area Number |
21750013
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Physical chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
MIYAZAKI Mitsuhiko Tokyo Institute of Technology, 資源化学研究所, 助教 (00378598)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
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| Keywords | 中赤外レーザー / ZnGeP_2 / 超音速ジェット / レーザー分光 / 溶媒和クラスター / プロトン移動反応 / 中赤外波長可変レーザー / 励起状態プロトン移動反応 |
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| Research Abstract |
I developed new tunable coherent infrared source in the mid-infrared (MIR) region that is applicable to supersonic jet infrared spectroscopies. The light source can provides continuous tunability covering 1000-2200cm^<-1> with the output of >0.5mJ/pulse and the energy resolution of <0.4cm^<-1>, which are necessary conditions to perform double resonance spectroscopies on supersonically cooled species.
Applications of the MIR laser to the infrared spectroscopy of the skeletal vibrations of several reactive systems, such as phenol-ammonia clusters, methylsalicylate shed new insight into their proton transfer reaction mechanisms that have been inferred only from uninformative broad spectroscopic features.
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