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Synthesis of novel magnetic ferroelectrics under high pressure with the use of ion exchange and hydrothermal reactions

Research Project

Project/Area Number 21750069
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Inorganic chemistry
Research InstitutionThe Institute of Physical and Chemical Research

Principal Investigator

ISHIWATA Shintaro  The Institute of Physical and Chemical Research, 大学院・工学系研究科, 特任准教授 (00525355)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsマルチフェロイックス / ペロブスカイト型マンガン酸化物 / 高圧合成 / 電気磁気効果 / 放射光X線回折 / 強相関電子系 / 単結晶構造解析 / フラストレーション / 対称性交換歪み
Research Abstract

We have succeeded in obtaining high-quality polycrystalline samples of perovskite Eu_<1-x>Y_xMnO_3 and Y_<1-x>Y_xMnO_3 by a high pressure technique with using single crystalline precursors of the ambient pressure phase. Complete multiferroic phase diagram of orthorhombic RMnO_3 was established. Furthermore, we have found that the magnetoelectric response is enhanced near the bicritical phase boundary. Single crystals of perovskite YMnO_3 were successfully grown under high pressure with a quasi hydrothermal condition. By using a synchrotron x-ray, we have observed for the first time ferroelectric lattice displacement driven by a magnetic order in YMnO_3.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (48 results)

All 2011 2010 2009 Other

All Journal Article (22 results) (of which Peer Reviewed: 22 results) Presentation (24 results) Remarks (2 results)

  • [Journal Article]2011

    • Author(s)
      T.Kurumaji, S.Seki, S.Ishiwata, H.Murakawa, Y.Tokunaga, Y.Kaneko, Y.Tokura
    • Journal Title

      Phys.Rev.Lett. 106

      Pages: 167206-167206

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2011

    • Author(s)
      H.Nakao, T.Murata, D.Bizen, Y.Murakami, K.Ohoyama, K.Yamada, S.Ishiwata, W.Kobayashi, I.Terasaki
    • Journal Title

      J.Phys.Soc.Jpn. 80

      Pages: 23711-23711

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2011

    • Author(s)
      N.Kida, S.Kumakura, S.Ishiwata, Y.Taguchi, Y.Tokura
    • Journal Title

      Phys.Rev.B 83

      Pages: 64422-64422

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2011

    • Author(s)
      S.Ishiwata, T.Nakano, I.Terasaki, Y.Uwatoko, H.Nakao, Y.Murakami, M.Takano
    • Journal Title

      Phys.Rev.B 83

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2011

    • Author(s)
      X.Z.Yu, N.Kanazawa, Y.Onose, K.Kimoto, W.Z.Zhang, S.Ishiwata, Y.Matsui, Y.Tokura
    • Journal Title

      Nature Materials 10

      Pages: 106-109

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Near room-temperature formation of a skyrmion crystal in thin-films of the helimagnet FeGe2011

    • Author(s)
      X.Z.Yu, N.Kanazawa, Y.Onose, K.Kimoto, W.Z.Zhang, S.Ishiwata, Y.Matsui, Y.Tokura
    • Journal Title

      Nature Materials

      Volume: 10 Pages: 106-109

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Uniaxial Colossal Magnetoresistance in the Ising Magnet SrCo12O192011

    • Author(s)
      S.Ishiwata, T.Nakano, I.Terasaki, Y.Uwatoko, H.Nakao, Y.Murakami, M.Takano
    • Journal Title

      Physical Review B

      Volume: 83

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gigantic terahertz magnetochromism via electromagnons in the hexaferrite magnet Ba2Mg2Fe12O222011

    • Author(s)
      N.Kida, S.Kumakura, S.Ishiwata, Y.Taguchi, Y.Tokura
    • Journal Title

      Physical Review B

      Volume: 83

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Orbital Ordering of Intermediate-Spin State of Co3+ in Sr3YCo4O10.52011

    • Author(s)
      H.Nakao, T.Murata, D.Bizen, Y.Murakami, K.Ohoyama, K.Yamada, S.Ishiwata, W.Kobayashi, I.Terasaki
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 83

    • NAID

      210000108883

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2010

    • Author(s)
      Y.Tokunaga, Y.Kaneko, D.Okuyama, S.Ishiwata, T.Arima, S.Wakimoto, K.Kakurai, Y.Taguchi, Y.Tokura
    • Journal Title

      Phys.Rev.Lett. 105

      Pages: 257201-257201

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2010

    • Author(s)
      S.Seki, T.Kurumaji, S.Ishiwata, H.Matsui, H.Murakawa, Y.Tokunaga, Y.Kaneko, T.Hasegawa, Y.Tokura
    • Journal Title

      Phys.Rev.B 82

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2010

    • Author(s)
      S.Ishiwata, D.Okuyama, K.Kakurai, M.Nishi, Y.Taguchi, Y.Tokura
    • Journal Title

      Phys.Rev.B 81

      Pages: 174418-174418

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2010

    • Author(s)
      S.Ishiwata, Y.Kaneko, Y.Tokunaga, Y.Taguchi, T.Arima, Y.Tokura
    • Journal Title

      Phys.Rev.B 81

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2010

    • Author(s)
      Y.Takahashi, S.Ishiwata, S.Miyahara, Y.Kaneko, N.Furukawa, Y.Taguchi, R.Shimano, Y.Tokura
    • Journal Title

      Phys.Rev.B 81

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Neutron diffraction studies on the multiferroic conical magnet Ba2Mg2Fe12O222010

    • Author(s)
      S.Ishiwata, D.Okuyama, K.Kakurai, M.Nishi, Y.Taguchi, Y.Tokura
    • Journal Title

      Physical Review B

      Volume: 81

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cupric chloride CuCl2 as an S=1/2 chain multiferroic2010

    • Author(s)
      S.Seki, T.Kurumaji, S.Ishiwata, H.Matsui, H.Murakawa, Y.Tokunaga, Y.Kaneko, T.Hasegawa, Y.Tokura
    • Journal Title

      Physical Review B

      Volume: 82

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structure, and Physical Properties of A-site Ordered Perovskites ACu3Co4O12(A=Ca and Y)2010

    • Author(s)
      I.Yamada, S.Ishiwata, I.Terasaki, M.Azuma, Y.Shimakawa, M.Takano
    • Journal Title

      Chemistry of Materials

      Volume: 22 Pages: 5828-5332

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrons doped in cubic perovskite SrMnO3 : isotropic metal versus chainlike ordering of Jahn-Teller polarons2010

    • Author(s)
      H.Sakai, S.Ishiwata, D.Okuyama, A.Nakao, H.Nakao, Y.Murakami, Y.Taguchi, Y.Tokura
    • Journal Title

      Physical Review B

      Volume: 82

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Multiferroic M-type hexaferrites with room-temperature conical state and magnetically controllable spin helicity2010

    • Author(s)
      Y.Tokunaga, Y.Kaneko, D.Okuyama, S.Ishiwata, T.Arima, S.Wakimoto, K.Kakurai, Y.Taguchi, Y.Tokura
    • Journal Title

      Physical Review Letters

      Volume: 105

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electric-dipole-active magnetic resonance in the conical-spin magnet Ba2Mg2Fe12O222009

    • Author(s)
      N.Kida, D.Okuyama, S.Ishiwata, Y.Taguchi, R.Shimano, K.Iwasa, T.Arima, Y.Tokura
    • Journal Title

      Physical Review B 80

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article]

    • Author(s)
      D.Okuyama, S.Ishiwata, Y.Takahashi, K.Yamauchi, S.Picozzi, K.Sugimoto, H.Sakai, M.Takata, R.Shimano, Y.Taguchi, T.Arima, Y.Tokura
    • Journal Title

      Phys.Rev.B. 掲載決定

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Perovskite Manganites Hosting Versatile Multiferroic Phases with Symmetric and Antisymmetric Exchange Strictions

    • Author(s)
      S.Ishiwata, Y.Kaneko, Y.Tokunaga, Y.Taguchi, T.Arima, Y.Tokura
    • Journal Title

      Physical Review B (印刷中)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation]2011

    • Author(s)
      S.Ishiwata
    • Organizer
      APS March Meeting 2011
    • Year and Date
      2011-03-21
    • Related Report
      2010 Final Research Report
  • [Presentation] Multiferroic Perovskite Manganites with Symmetric Exchange Striction2011

    • Author(s)
      S.Ishiwata
    • Organizer
      APS March Meeting 2011
    • Place of Presentation
      ダラス,米国
    • Year and Date
      2011-03-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Multiferroic Perovskite Manganites with Symmetric and Antisymmetric Exchange Strictions2011

    • Author(s)
      S.Ishiwata, D.Okuyama, Y.Takahashi, Y.Kaneko, H.Sakai, K.Sugimoto, Y.Tokunaga, R.Shimano, Y.Taguchi, T.Arima, Y.Tokura
    • Organizer
      The 3rd APCTP workshop on multiferroics
    • Place of Presentation
      新宿区早稲田大学
    • Year and Date
      2011-01-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Multiferroic perovskite manganites synthesized under high pressure2010

    • Author(s)
      S.Ishiwata, Y.Kaneko, D.Okuyama, H.Sakai, Y.Tokunaga, Y.Taguchi, T.Anima, Y.Tokura
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ワイキキ、米国
    • Year and Date
      2010-12-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Anomalous Hall effect in the helimagnetic cubic perovskite SrFeO32010

    • Author(s)
      S.Ishiwata, Y.Kaneko, M.Tokunaga, D.Okuyama, Y.Tokunaga, T.Arima, S.Wakimoto, K.Kakurai, Y.Taguchi, Y.Tokura
    • Organizer
      2010 Opening Symposium of QS2C Theory Forum
    • Place of Presentation
      和光市 理化学研究所
    • Year and Date
      2010-09-30
    • Related Report
      2010 Annual Research Report
  • [Presentation]2010

    • Author(s)
      S.Ishiwata, Y.Kaneko, M.Tokunaga, Y.Taguchi, Y.Tokura
    • Organizer
      日本物理学会平成22年度秋季大会
    • Year and Date
      2010-09-24
    • Related Report
      2010 Final Research Report
  • [Presentation] らせん磁性体SrFeO3における異常ホール効果と磁場誘起相転移2010

    • Author(s)
      S.Ishiwata, Y.Kaneko, M.Tokunaga, Y.Taguchi, Y.Tokura
    • Organizer
      日本物理学会平成22年度秋期大会
    • Place of Presentation
      大阪府堺市 大阪府立大学
    • Year and Date
      2010-09-24
    • Related Report
      2010 Annual Research Report
  • [Presentation]2010

    • Author(s)
      S.Ishiwata, D.Okuyama, H.Sakai, Y.Tokunaga, K.Sugimoto, Y.Taguchi, T.Arima, Y.Tokura
    • Organizer
      日本物理学会第65回年次大会
    • Year and Date
      2010-03-21
    • Related Report
      2010 Final Research Report
  • [Presentation] ペロブスカイト型YMnO3単結晶における磁気強誘電性2010

    • Author(s)
      石渡晋太郎、奥山大輔、酒井英明、徳永祐介、杉本邦久、田口康二郎、有馬孝尚、十倉好紀
    • Organizer
      日本物理学会第65回年次大会
    • Place of Presentation
      岡山
    • Year and Date
      2010-03-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Relation between helimagnetic structure and electric polarization in Y-type hexaferrite Ba2Mg2Fe12O222010

    • Author(s)
      石渡晋太郎, 奥山大輔, 加倉井和久, 西正和, 田口康二郎, 十倉好紀
    • Organizer
      Flipper 2010 International Workshop on Single-Crystal Diffraction with Polarized Neutrons, Grenoble
    • Place of Presentation
      Grenoble, France
    • Year and Date
      2010-01-30
    • Related Report
      2009 Annual Research Report
  • [Presentation]2010

    • Author(s)
      S.Ishiwata, D.Okuyama, K.Kakurai, M.Nishi, Y.Taguchi, Y.Tokura
    • Organizer
      Flipper 2010 International Workshop on Single-Crystal Diffraction with Polarized Neutrons
    • Place of Presentation
      Grenoble
    • Related Report
      2010 Final Research Report
  • [Presentation] Multiferroic Perovskite Manganites with Symmetric and Antisymmetric Exchange Strictions2009

    • Author(s)
      石渡晋太郎, 金子良夫, 徳永祐介, 田口康二郎, 有馬孝尚, 十倉好紀
    • Organizer
      RIKEN Workshop on Emergent Phenomena of Correlated Materials
    • Place of Presentation
      和光
    • Year and Date
      2009-12-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 斜方晶RMnO_3(R=Y, Ho, Er, Tm, Yb, Lu)における磁気強誘電性のAサイト依存性2009

    • Author(s)
      石渡晋太郎, 金子良夫, 高橋陽太郎, 徳永祐介, 徳永将史, 有馬孝尚, 島野亮, 田口康二郎, 十倉好紀
    • Organizer
      日本物理学会2009年秋期大会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 斜方晶RMnO_3(R=Y, Ho, Er, Tm, Yb, Lu)における電場誘起による磁気励起の観測2009

    • Author(s)
      高橋陽太郎, 石渡晋太郎, 金子良夫, 貴田徳明, 田口康二郎, 島野亮, 十倉好紀
    • Organizer
      日本物理学会2009年秋期大会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 偏極中性子を用いたらせん磁性体Ba_2Mg_2Fe_<12>O_<22>における磁場誘起強誘電相の研究2009

    • Author(s)
      石渡晋太郎, 奥山大輔, 加倉井和久, 西正和, 田口康二郎, 十倉好紀
    • Organizer
      日本物理学会2009年秋期大会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] 中性子非弾性散乱によるBa_2Mg_2Fe_<12>O_<22>のマグノンの観測2009

    • Author(s)
      奥山大輔, 貴田徳明, 岩佐和晃, 石渡晋太郎, 田口康二郎, 有馬孝尚, 十倉好紀
    • Organizer
      日本物理学会2009年秋期大会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] M型ヘキサフェライトのマルチフェロイック特性2009

    • Author(s)
      徳永祐介, 金子良夫, 石渡晋太郎, 田口康二郎, 十倉好紀
    • Organizer
      日本物理学会2009年秋期大会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation] コニカル磁性体Ba_2(Mg_<1-x>Zn_x)_2Fe_<12>O_<22>における光の電場で誘起される磁気励起2009

    • Author(s)
      貴田徳明, 石渡晋太郎, 田口康二郎, 島野亮, 有馬孝尚, 十倉好紀
    • Organizer
      日本物理学会2009年秋期大会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-25
    • Related Report
      2009 Annual Research Report
  • [Presentation]2009

    • Author(s)
      S.Ishiwata, Y.Taguchi, H.Murakawa, Y.Tokunaga, D.Okuyama, K.Kakurai, M.Nishi, Y.Onose, Y.Tokura
    • Organizer
      第33回日本磁気学会
    • Place of Presentation
      長崎
    • Year and Date
      2009-09-13
    • Related Report
      2010 Final Research Report
  • [Presentation] Low-magnetic-field control of electric polarization in a conical helimagnet Ba2Mg2Fe12O222009

    • Author(s)
      石渡晋太郎, 田口康二郎, 村川寛, 徳永祐介, 奥山大輔, 加倉井和久, 西正和, 小野瀬佳文, 十倉好紀
    • Organizer
      第33回日本磁気学会
    • Place of Presentation
      長崎
    • Year and Date
      2009-09-13
    • Related Report
      2009 Annual Research Report
  • [Presentation]2009

    • Author(s)
      S.Ishiwata, Y.Kaneko, Y.Taguchi, Y.Tokura
    • Organizer
      Joint AIRAPT-22 & HPCJ-50 International Conference on High Pressure Science and Technology
    • Place of Presentation
      Tokyo
    • Year and Date
      2009-07-28
    • Related Report
      2010 Final Research Report
  • [Presentation] High Pressure Syntheses and Magnetoelectric Properties of Orthorhombic RMnO_32009

    • Author(s)
      石渡晋太郎, 金子良夫, 田口康二郎, 十倉好紀
    • Organizer
      Joint AIRAPT-22 & HPCJ-50 International Conference on High Pressure Science and Technology
    • Place of Presentation
      東京
    • Year and Date
      2009-07-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] Relation between helimagnetic structure and electric polarization in anisotropy-controlled hexaferrite2009

    • Author(s)
      石渡晋太郎
    • Organizer
      Joint European Japanese Conference : Frustration in Condensed Matter
    • Place of Presentation
      Lyon
    • Year and Date
      2009-05-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] 回転磁場下におけるDyMnO_3の希土類サイトの磁気秩序状態と強誘電ドメインの変遷過程2009

    • Author(s)
      村川寛, 小野瀬佳文, 賀川史敬, 石渡晋太郎, 金子良夫, 十倉好紀
    • Organizer
      日本物理学会第64回年次大会
    • Place of Presentation
      東京
    • Year and Date
      2009-03-27
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.qpec.t.u-tokyo.ac.jp/ishiwata_lab/index.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.qpec.t.u-tokyo.ac.jp/ishiwata_lab/index.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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