Development of selective oxidation catalysts with multi-core active center using a theoretical approach
Project/Area Number |
21750089
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Research Category |
Grant-in-Aid for Young Scientists (B)
|
Allocation Type | Single-year Grants |
Research Field |
Synthetic chemistry
|
Research Institution | Tohoku University (2010) University of Tsukuba (2009) |
Principal Investigator |
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Project Period (FY) |
2009 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
Keywords | 合成化学 / 計算化学 / ポリオキソメタレート / バナジウム / 銀 / 選択酸化 / アルカン水酸化 / 多価アルコール / 量子化学計算 |
Research Abstract |
Catalyses of polyoxometalate catalysts with di-vanadium core were investigated. The catalyst with phosphorous as a central atom showed high performance for both epoxidation of alkenes and hydroxylation of alkanes. Catalysts for selective oxidation of aqueous poly-ols were also investigated. The combination of silver and noble metal showed high performance.
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Report
(3 results)
Research Products
(3 results)