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Creation of Lithium-ion Conductive Polymer Nanocomposites using Dissociation Effect of Carbon Dioxide

Research Project

Project/Area Number 21750113
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

TOMINAGA Yoichi  Tokyo University of Agriculture and Technology, 大学院・工学研究院, 講師 (30323786)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords二酸化炭素 / 層状化合物 / ナノコンポジット / イオン伝導度 / Liイオン二次電池 / クレイ
Research Abstract

We used a supercritical carbon dioxide (scCO_2) treatment technique for improvement in ionic conductivity and dispersion of solid polymer electrolytes (SPE)-clay composites. In this study, we prepared amorphous polyether/saponite (S_<Na>) composites treated with the scCO_2 and characterized the properties. Wide-angle X-ray diffraction (WAXD) patterns of the composite samples indicated almost no expansion of the d-spacing with the scCO_2 treatment. However, the conductivity of the scCO_2-treated samples was higher than that of the original samples. In particular, the scCO_2-treated sample including 10wt% of freeze-dried S_<Na> showed approximately 35-times higher conductivity than the original sample at 30℃.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (35 results)

All 2011 2010 2009 Other

All Journal Article (10 results) (of which Peer Reviewed: 8 results) Presentation (22 results) Remarks (3 results)

  • [Journal Article] Utilization of carbon dioxide for polymer electrolytes [II]: Synthesis of alternating copolymers with glycidyl ethers as novel ion-conductive polymers2011

    • Author(s)
      M.Nakamura, Y. Tominaga
    • Journal Title

      Electrochimica Acta in press

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Utilization of carbon dioxide for polymer electrolytes [I]: Effect of supercritical treatment conditions on ionic conduction in amorphous polyether/salt mixtures2011

    • Author(s)
      Y.Oe, Y. Tominaga
    • Journal Title

      Electrochimica Acta in press

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Utilization of carbon dioxide for polymer electrolytes [I] : Effect of supercritical treatment conditions on ionic conduction in amorphous polyether/salt mixtures2011

    • Author(s)
      Y.Oe, Y.Tominaga
    • Journal Title

      Electrochimica Acta

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Utilization of carbon dioxide for polymer electrolytes [II] : Synthesis of alternating copolymers with glycidyl ethers as novel ion-conductive polymers2011

    • Author(s)
      M.Nakamura, Y.Tominaga
    • Journal Title

      Electrochimica Acta

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alternating copolymers of carbon dioxide with glycidyl ethers for novel ion-conductive polymer electrolytes2010

    • Author(s)
      Y. Tominaga, T.Shimomura, M.Nakamura
    • Journal Title

      Polymer 51(19)

      Pages: 4295-4298

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 二酸化炭素の有効利用による新しいイオン伝導性ポリマーの開発技術2010

    • Author(s)
      富永洋一
    • Journal Title

      ケミカルエンジニヤリング(化学工業社,解説) 55(3)

      Pages: 17-23

    • Related Report
      2010 Final Research Report
  • [Journal Article] Alternating copolymers of carbon dioxide with glycidyl ethers for novel ion-conductive polymer electrolytes2010

    • Author(s)
      Y.Tominaga, T.Shimomura, M.Nakamura
    • Journal Title

      Polymer

      Volume: 51 Pages: 4295-4298

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 二酸化炭素の有効利用による新しいイオン伝導性ポリマーの開発技術2010

    • Author(s)
      富永洋一
    • Journal Title

      ケミカルエンジニヤリング 55

      Pages: 17-23

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Enhanced cationic conduction in a polyether/saponite nanocomposite treated with supercritical carbon dioxide2009

    • Author(s)
      S.Kitajima, Y. Tominaga
    • Journal Title

      Macromolecules 42(15)

      Pages: 5422-5424

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced cationic conduction in a polyether/saponite nanocomposite treated with supercritical carbon dioxide2009

    • Author(s)
      S.Kitajima, Y.Tominaga
    • Journal Title

      Macromolecules 42

      Pages: 5422-5424

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 超臨界二酸化炭素によるシングルイオン伝導性ポリマーの解離促進と伝導度への影響2011

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      電気化学会第78回大会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2011-03-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] Improvement in ionic conductivity of polyether/clay composites (Poster)2010

    • Author(s)
      S. Kitajima, Y. Tominaga
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (PACIFICHEM) 2010
    • Place of Presentation
      Hawaii(USA)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Improvement in ionic conductivity of polyether/clay composites2010

    • Author(s)
      S.Kitajima, Y.Tominaga
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2010
    • Place of Presentation
      Hawaii (USA)
    • Year and Date
      2010-12-19
    • Related Report
      2010 Annual Research Report
  • [Presentation] 凍結乾燥クレイを利用したポリエーテルナノ複合材料の作製と超臨界二酸化炭素処理によるイオン伝導度の改善2010

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第22回高分子加工技術討論会
    • Place of Presentation
      名古屋市工業研究所(口頭)
    • Year and Date
      2010-10-26
    • Related Report
      2010 Final Research Report
  • [Presentation] 凍結乾燥クレイを利用したポリエーテルナノ複合材料の作製と超臨界二酸化炭素処理によるイオン伝導度の改善2010

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第22回高分子加工技術討論会
    • Place of Presentation
      名古屋市工業研究所
    • Year and Date
      2010-10-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 凍結乾燥クレイを充填したポリエーテル型ナノコンポジットの作製と超臨界二酸化炭素処理によるイオン伝導度の改善2010

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学(口頭)
    • Year and Date
      2010-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] 凍結乾燥クレイを充填したポリエーテル型ナノコンポジットの作製と超臨界二酸化炭素処理によるイオン伝導度の改善2010

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Improvement in ionic conductivity of polyether/clay composites by supercritical carbon dioxide treatment2010

    • Author(s)
      S. Kitajima, Y. Tominaga
    • Organizer
      XII International Symposium on Polymer Electrolytes (ISPE-12)(Poster)
    • Place of Presentation
      Padova(Italy)
    • Year and Date
      2010-08-31
    • Related Report
      2010 Final Research Report
  • [Presentation] Improvement in ionic conductivity of polyether/clay composites by supercritical carbon dioxide treatment2010

    • Author(s)
      S.Kitajima, Y.Tominaga
    • Organizer
      12th International Symposium on Polymer Electrolytes
    • Place of Presentation
      Padova (Italy)
    • Year and Date
      2010-08-31
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリエーテル/凍結乾燥クレイ複合体の作製と超臨界二酸化炭素によるイオン伝導度の改善2010

    • Author(s)
      北島峻輔, 富永洋一, 平原英俊
    • Organizer
      平成22年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(口頭)
    • Year and Date
      2010-06-17
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリエーテル/凍結乾燥クレイ複合体の作製と超臨界二酸化炭素によるイオン伝導度の改善2010

    • Author(s)
      北島峻輔, 富永洋一, 平原英俊
    • Organizer
      平成22年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2010-06-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 超臨界二酸化炭素を利用した固体高分子電解質/クレイ複合体のナノ分散化とイオン伝導挙動の解析(ポスター)2010

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-26
    • Related Report
      2010 Final Research Report
  • [Presentation] 超臨界二酸化炭素を利用した固体高分子電解質/クレイ複合体のナノ分散化とイオン伝導挙動の解析2010

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリエーテル/クレイ複合体の作製と超臨界二酸化炭素処理によるイオン伝導度の改善(ポスター)2010

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山大学
    • Year and Date
      2010-03-29
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリエーテル/クレイ複合体の作製と超臨界二酸化炭素処理によるイオン伝導度の改善2010

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      電気化学会第77回大会
    • Place of Presentation
      富山大学(富山県)
    • Year and Date
      2010-03-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] 二酸化炭素の有効利用による固体高分子電解質の高性能化(ポスター)2009

    • Author(s)
      北島峻輔, 大江祥元, 中村美月, 富永洋一
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学
    • Year and Date
      2009-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 二酸化炭素の有効利用による固体高分子電解質の高性能化2009

    • Author(s)
      北島峻輔, 大江祥元, 中村美月, 富永洋一
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本大学(熊本県)
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] 超臨界二酸化炭素を利用した新規クレイ/イオン伝導性高分子ナノコンポジットの作製(ポスター)2009

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2009-06-10
    • Related Report
      2010 Final Research Report
  • [Presentation] 超臨界二酸化炭素を利用した新規クレイ/イオン伝導性高分子ナノコンポジットの作製2009

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2009-06-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] イオン伝導性クレイ/高分子電解質ナノコンポジットの作製と超臨界二酸化炭素処理の影響(ポスター)2009

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第20回プラスチック成形加工学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2009-06-03
    • Related Report
      2010 Final Research Report
  • [Presentation] 超臨界二酸化炭素処理によるクレイ/固体高分子電解質ナノコンポジットの作製とイオン伝導性の評価(ポスター)2009

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場
    • Year and Date
      2009-05-27
    • Related Report
      2010 Final Research Report
  • [Presentation] 超臨界二酸化炭素処理によるクレイ/固体高分子電解質ナノコンポジットの作製とイオン伝導性の評価2009

    • Author(s)
      北島峻輔, 富永洋一
    • Organizer
      第58回高分子学会年次大会
    • Place of Presentation
      神戸国際会議場(兵庫県)
    • Year and Date
      2009-05-27
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www.tuat.ac.jp/~tominaga/main/research/2-1_clay.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~tominaga/main/research/2-1_clay.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~tominaga/main-menu/research/2-1_clay.html

    • Related Report
      2009 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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