Creation of Lithium-ion Conductive Polymer Nanocomposites using Dissociation Effect of Carbon Dioxide
| Project/Area Number |
21750113
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Polymer chemistry
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| Research Institution | Tokyo University of Agriculture and Technology |
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Principal Investigator |
TOMINAGA Yoichi Tokyo University of Agriculture and Technology, 大学院・工学研究院, 講師 (30323786)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2009: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Keywords | 二酸化炭素 / 層状化合物 / ナノコンポジット / イオン伝導度 / Liイオン二次電池 / クレイ |
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| Research Abstract |
We used a supercritical carbon dioxide (scCO_2) treatment technique for improvement in ionic conductivity and dispersion of solid polymer electrolytes (SPE)-clay composites. In this study, we prepared amorphous polyether/saponite (S_<Na>) composites treated with the scCO_2 and characterized the properties. Wide-angle X-ray diffraction (WAXD) patterns of the composite samples indicated almost no expansion of the d-spacing with the scCO_2 treatment. However, the conductivity of the scCO_2-treated samples was higher than that of the original samples. In particular, the scCO_2-treated sample including 10wt% of freeze-dried S_<Na> showed approximately 35-times higher conductivity than the original sample at 30℃.
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Report
(3 results)
Research Products
(35 results)
