Selective Formose Reaction Using Small Spaces
Project/Area Number |
21750124
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Single-year Grants |
Research Field |
Polymer chemistry
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Research Institution | Osaka University |
Principal Investigator |
HASHIDZUME Akihito Osaka University, 大学院・理学研究科, 講師 (70294147)
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Project Period (FY) |
2009 – 2010
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Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
|
Keywords | 微小空間 / ホルモース反応 / ホルモース / ホルムアルデヒド / 多孔性アルミナ / 逆ミセル / 界面活性剤 / 両親媒性ブロック共重合体 / 13^C NMR / 多孔性材料 / エーロゾルOT |
Research Abstract |
In order to realize selective formose reaction, formose reactions were carried out using porous alumina and water pools of reverse micelles as small reaction media. Porous alumina showed a higher catalytic activity for formose reaction to form sugar alcohols of larger carbon numbers. In the formose reactions in water pools of reverse micelles, acceleration of the initial reaction and a selectivity of products were observed.
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Report
(3 results)
Research Products
(19 results)
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[Presentation] 微小空間におけるホルモース反応2010
Author(s)
橋爪章仁、真田雄介、藤本拓、正岡誠、佐藤尚弘
Organizer
第59回高分子討論会,3Pc111
Place of Presentation
北海道大学高等教育機能開発総合センター(札幌)
Year and Date
2010-09-17
Related Report
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[Presentation] 微小空間におけるホルモース反応2010
Author(s)
橋爪章仁, 真田雄介, 藤本拓, 正岡誠, 佐藤尚弘
Organizer
第59回高分子討論会
Place of Presentation
北海道大学高等教育機能開発総合センター(札幌)
Year and Date
2010-09-17
Related Report
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