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Selective Formose Reaction Using Small Spaces

Research Project

Project/Area Number 21750124
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Polymer chemistry
Research InstitutionOsaka University

Principal Investigator

HASHIDZUME Akihito  Osaka University, 大学院・理学研究科, 講師 (70294147)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywords微小空間 / ホルモース反応 / ホルモース / ホルムアルデヒド / 多孔性アルミナ / 逆ミセル / 界面活性剤 / 両親媒性ブロック共重合体 / 13^C NMR / 多孔性材料 / エーロゾルOT
Research Abstract

In order to realize selective formose reaction, formose reactions were carried out using porous alumina and water pools of reverse micelles as small reaction media. Porous alumina showed a higher catalytic activity for formose reaction to form sugar alcohols of larger carbon numbers. In the formose reactions in water pools of reverse micelles, acceleration of the initial reaction and a selectivity of products were observed.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (19 results)

All 2011 2010 2009 Other

All Journal Article (5 results) (of which Peer Reviewed: 5 results) Presentation (12 results) Remarks (2 results)

  • [Journal Article] 糖存在下でのゾルゲル法による多孔性アルミナの調製と得られた多孔性アルミナの機能2010

    • Author(s)
      橋爪章仁、藤本拓、正岡誠、真田雄介、佐藤尚弘
    • Journal Title

      高分子論文集 Vol.67、No.5

      Pages: 312-317

    • NAID

      10026213750

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interaction of poly(N-acryloyl-amino acids) with saccharides in aqueous media2010

    • Author(s)
      HASHIDZUME, Akihito、TANAKA, Atsushi、SATO, Takahiro
    • Journal Title

      Polymer Vol.51、No.1

      Pages: 18-21

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] 糖存在下でのゾルゲル法による多孔性アルミナの調製と得られた多孔性アルミナの機能2010

    • Author(s)
      橋爪章仁, 藤本拓, 正岡誠, 真田雄介, 佐藤尚弘
    • Journal Title

      高分子論文集

      Volume: 67 Pages: 312-317

    • NAID

      10026213750

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Interaction of poly(N-acryloyl-amino acids) with saccharides in aqueous media2010

    • Author(s)
      A.Hashidzume, A.Tanaka, T.Sato
    • Journal Title

      Polymer 51

      Pages: 18-21

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 糖存在下でのゾルゲル法による多孔性アルミナの調製と得られた多孔性アルミナの機能2010

    • Author(s)
      橋爪章仁, 藤本拓, 正岡誠, 真田雄介, 佐藤尚弘
    • Journal Title

      高分子論文集 67(印刷中)

    • NAID

      10026213750

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 逆ミセル内のウォータープール中でのホルモース反応2011

    • Author(s)
      正岡誠、橋爪章仁、佐藤尚弘
    • Organizer
      日本化学会第91春季年会,2PC-118
    • Place of Presentation
      神奈川大学横浜キャンパス(横浜)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] 逆ミセル内のウォータープール中でのホルモース反応2011

    • Author(s)
      正岡誠, 橋爪章仁, 佐藤尚弘
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学横浜キャンパス(横浜)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 微小空間におけるホルモース反応2010

    • Author(s)
      橋爪章仁、真田雄介、藤本拓、正岡誠、佐藤尚弘
    • Organizer
      第59回高分子討論会,3Pc111
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(札幌)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 微小空間におけるホルモース反応2010

    • Author(s)
      橋爪章仁, 真田雄介, 藤本拓, 正岡誠, 佐藤尚弘
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(札幌)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 糖の存在下ゾルゲル法によって調製した多孔性アルミナの特性2010

    • Author(s)
      橋爪章仁、藤本拓、正岡誠、真田雄介、佐藤尚弘
    • Organizer
      日本化学会第90春季年会,3PB-128
    • Place of Presentation
      近畿大学本部キャンパス(東大阪)
    • Year and Date
      2010-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 糖の存在下ゾルゲル法によって調製した多孔性アルミナの特性2010

    • Author(s)
      橋爪章仁・藤本拓・正岡誠・真田雄介・佐藤尚弘
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパ(東大阪)
    • Year and Date
      2010-03-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] エーロゾルOT逆ミセルのウォータープール中におけるホルモース反応2010

    • Author(s)
      正岡誠、橋爪章仁、佐藤尚弘
    • Organizer
      日本化学会第90春季年会,2PC-027
    • Place of Presentation
      近畿大学本部キャンパス(東大阪)
    • Year and Date
      2010-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] エーロゾルOT逆ミセルのウォータープール中におけるホルモース反応2010

    • Author(s)
      正岡誠・橋爪章仁・佐藤尚弘
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学本部キャンパス(東大阪)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Formose reaction in water pools of Aerosol OT reverse micelles2009

    • Author(s)
      M.Masaoka, A.Hashidzume, T.Sato
    • Organizer
      Osaka University Macromolecular Symposium on Chemistry, Physics, and Biology in Macromolecular Science (OUMS '09)
    • Place of Presentation
      大阪大学理学部(豊中)
    • Year and Date
      2009-12-13
    • Related Report
      2009 Annual Research Report
  • [Presentation] Formose reaction in water pools of Aerosol OT reverse micelles2009

    • Author(s)
      Makoto Masaoka、Akihito Hashidzume、Takahiro Sato
    • Organizer
      Osaka University Macromolecular Symposium on Chemistry, Physics, and Biology in Macromolecular Science (OUMS '09),I-25
    • Place of Presentation
      Graduate School of Science, Osaka University (Toyonaka)
    • Year and Date
      2009-12-12
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation of porous alumina by the sol-gel process in the presence of sugars and functions of the alumina obtained2009

    • Author(s)
      Akihito Hashidzume、Taku Fujimoto、Makoto Masaoka、Yusuke Sanada、Takahiro Sato
    • Organizer
      Osaka University Macromolecular Symposium on Chemistry, Physics, and Biology in Macromolecular Science (OUMS '09),I-22
    • Place of Presentation
      Graduate School of Science, Osaka University (Toyonaka)
    • Year and Date
      2009-12-12
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation of porous alumina by the sol-gel process in the presence of sugars and functions of the alumina obtained2009

    • Author(s)
      A.Hashidzume, T.Fujimoto, M.Masaoka, Y.Sanada, T.Sato
    • Organizer
      Osaka University Macromolecular Symposium on Chemistry, Physics, and Biology in Macromolecular Science (OUMS '09)
    • Place of Presentation
      大阪大学理学部(豊中)
    • Year and Date
      2009-12-12
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/sato/sato_lab_j/member_j/hashidzume_j/hashi2_pb_j.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/sato/sato_lab_j/member_j/hashidzume_j/hashi2_pb_j.html

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2009-04-01   Modified: 2016-04-21  

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