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Construction of π-Electron Rich Molecular Tubes Using para-Bridged Macrocyclic Host Molecules

Research Project

Project/Area Number 21750140
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Functional materials chemistry
Research InstitutionKanazawa University

Principal Investigator

OGOSHI Tomoki  Kanazawa University, 物質化学系, 准教授 (00447682)

Project Period (FY) 2009 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
KeywordsPillar[5]arene / ポリロタキサン / 分子チューブ / 水素結合 / ピラー[5]アレーン / 環状ホスト分子 / フェノール / ホスト-ゲスト包接錯体 / 対称性 / 柱構造 / ピラー[5]アレン / 超分子 / ホストーゲスト包接錯体 / ビオロゲンポリマー / 電荷移動錯体
Research Abstract

New polyrotaxane composed of pillar[5]arene and viologen polymer was successfully prepared with extremely high yield by capping the chain ends with adamantyl moieties. We also prepared organo-nanotubes from pillar[5]arene molecules via inter-molecular hydrogen bonding between the molecules.

Report

(3 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • Research Products

    (21 results)

All 2011 2010 2009 Other

All Journal Article (11 results) (of which Peer Reviewed: 6 results) Presentation (7 results) Remarks (3 results)

  • [Journal Article] Monofunctionalized Pillar[5]arenes : Synthesis and Supramolecular Structure.2011

    • Author(s)
      Ogoshi, T., Demachi K., Kitajima, K., Yamagishi, T.
    • Journal Title

      Chem.Commun. in press

    • Related Report
      2010 Final Research Report
  • [Journal Article] Facile, Rapid, and High-Yield Synthesis of Pillar[5]arene from Commercially Available Reagents and Its X-ray Crystal Structure2011

    • Author(s)
      生越友樹、青木崇倫、北島啓資、藤波修平、山岸忠明、中本義章
    • Journal Title

      J.Org.Chem.

      Volume: 76 Pages: 328-331

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect ofIntra-Molecular Hydrogen Bond Beltand Complexation with Guest onRotation Behavior of Phenolic Unitsin Pillar[5]arenes.2010

    • Author(s)
      Ogoshi, T., Kitajima, K., Aoki, Y., Yamagishi, T., Nakamoto, Y.
    • Journal Title

      J.Phys.Chem.Lett. 1

      Pages: 817-821

    • Related Report
      2010 Final Research Report
  • [Journal Article] Polypseudorotaxane Constructed from Pillar[5]arene and Viologen Polymer.2010

    • Author(s)
      Ogoshi, T., Nishida, Y., Yamagishi, T., Nakamoto, Y.
    • Journal Title

      Macromolecules 43

      Pages: 3145-3147

    • Related Report
      2010 Final Research Report
  • [Journal Article] High Yield Synthesisof Polyrotaxane Constructed from Pillar[5]arene and Viologen Polymerand Stabilization of Its RadicalCation.2010

    • Author(s)
      Ogoshi, T., Nishida, Y., Yamagishi, T., Nakamoto, Y.
    • Journal Title

      Macromolecules 43

      Pages: 7068-7072

    • Related Report
      2010 Final Research Report
  • [Journal Article] High Yield Synthesis of Polyrotaxane Constructed from Pillar[5]arene and Viologen Polymer and Stabilization of Its Radical Cation2010

    • Author(s)
      生越友樹、西田陽子、山岸忠明、中本義章
    • Journal Title

      Macromolecules

      Volume: 43 Pages: 7068-7072

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Conformational Chazacteristics of Alkyl-Substituted Pillaz[5]arenes2010

    • Author(s)
      生越友樹、北島啓資、青木崇倫、藤波修平、山岸忠明、中本義章
    • Journal Title

      J.Org.Chem.

      Volume: 75 Pages: 3268-3273

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polypseudorotaxane Constructed from Pillar[5]arene and Viologen Polymer2010

    • Author(s)
      生越友樹、西田陽子、山岸忠明、中本義章
    • Journal Title

      Macromolecules 43

      Pages: 3145-3147

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Intra-Molecular Hydrogen Bond Belt and Complexation with Guest on Rotation Behavior of Phenolic Units in Pillar [5] arenes2010

    • Author(s)
      生越友樹、北島啓資、青木崇倫、山岸忠明、中本義章
    • Journal Title

      J.Phys.Chem.Lett. 1

      Pages: 817-821

    • NAID

      130004597247

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Conformational Characteristics of Nonsymmetric Pillar [5] arene2010

    • Author(s)
      生越友樹、北島啓資、山岸忠明、中本義章
    • Journal Title

      Org.Lett. 12

      Pages: 636-638

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Through-Space・-Delocalized Pillar[5]arene.2009

    • Author(s)
      Ogoshi, T., Umeda, K., Yamagishi, T., Nakamoto, Y.
    • Journal Title

      Chem.Commun.

      Pages: 4874-4876

    • Related Report
      2010 Final Research Report
  • [Presentation] 新規環状ホスト分子"Pillar[5]arene"の合成と超分子材料への応用2011

    • Author(s)
      生越友樹
    • Organizer
      第11回リング-チューブ超分子研究会シンポジウム
    • Place of Presentation
      東京工業大学・大岡山キャンパス 招待講演
    • Year and Date
      2011-03-10
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規環状ホスト分子"Pillar[5]arene"の合成と超分子材料への応用2011

    • Author(s)
      生越友樹
    • Organizer
      第11回リング・チューブ超分子研究会シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス
    • Year and Date
      2011-03-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] 新規環状ホスト分子"Pillar[5]arene"の合成と超分子材料への応用2010

    • Author(s)
      生越友樹
    • Organizer
      第56回高分子研究発表会(神戸)
    • Place of Presentation
      兵庫県民会館 ヤングサイエンティスト講演
    • Year and Date
      2010-07-16
    • Related Report
      2010 Final Research Report
  • [Presentation] 環状ホスト分子の合成とハイブリッド材料への応用2010

    • Author(s)
      生越友樹
    • Organizer
      第131回東海高分子研究会講演会
    • Place of Presentation
      名古屋工業大学 招待講演
    • Year and Date
      2010-04-24
    • Related Report
      2010 Final Research Report
  • [Presentation] 環状ホスト分子の合成とハイブリッド材料への応用2010

    • Author(s)
      生越友樹
    • Organizer
      10-1精密ネットワークポリマー研究会
    • Place of Presentation
      東京工業大学・大岡山キャンパス 招待講演
    • Year and Date
      2010-04-16
    • Related Report
      2010 Final Research Report
  • [Presentation] 環状ホスト分子の合成とハイブリッド材料への応用2009

    • Author(s)
      生越友樹
    • Organizer
      国際高分子基礎センター講演会
    • Place of Presentation
      東京工業大学・大岡山キャンパス 招待講演
    • Year and Date
      2009-12-02
    • Related Report
      2010 Final Research Report
  • [Presentation] 環状ホスト分子の合成とハイブリッド材料への応用2009

    • Author(s)
      生越友樹
    • Organizer
      平成21年度北陸地区高分子若手研究会
    • Place of Presentation
      ウェルサンピア新潟(新潟県)
    • Year and Date
      2009-08-26
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html6

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://kohka.ch.t.kanazawa-u.ac.jp/lab3/lab3.html

    • Related Report
      2009 Annual Research Report

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Published: 2009-04-01   Modified: 2016-04-21  

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