Development of Novel Heterogeneous Chiral Catalyst Using Functionalized Layered Hydroxy Double Salts
| Project/Area Number |
21760623
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Single-year Grants |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Chiba University |
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Principal Investigator |
HARA Takayoshi Chiba University, 大学院・工学研究科, 助教 (60437358)
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| Project Period (FY) |
2009 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2009: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Keywords | 層状粘土化合物 / パラジウム / アルコール酸化反応 / グリーンケミストリー / 不斉合成触媒 / アミノ酸錯体 |
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| Research Abstract |
In-situ prepared anionic D-Valine-Pd(II) complex intercalated into the anion exchangeable Ni-Zn mixed basic salt (NiZn), which is classified by layered hydroxy double salts, was synthesized via simple anion exchange procedure. Furthermore, a Bronsted basic PO_4^<3-> anion was also intercalated into NiZn interlayer, coexisted with the anionic D-Valine-Pd complex. The synthesized Bronsted basic clay-Pd(II) nanocomposite catalyzed the aerobic oxidation of wide range of alcohols into the corresponding aldehydes and ketones effectively.
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Report
(3 results)
Research Products
(40 results)
