| Project/Area Number |
21850013
|
|---|
| Research Category |
Grant-in-Aid for Research Activity Start-up
|
| Allocation Type | Single-year Grants |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Tokyo Institute of Technology |
|---|
Principal Investigator |
YAMAMOTO Takuya Tokyo Institute of Technology, 大学院・理工学研究科, 助教 (30525986)
|
|---|
| Project Period (FY) |
2009 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
|
|---|
| Keywords | 表面・界面物性 / 自己組織化 / 超薄膜 / 構造・機能材料 / トポロジー |
|---|
| Research Abstract |
Cyclic alkanedisulfides were synthesized from linear alkanedithiols consisting of 10 and 20 carbon atoms using a bromo-Wang resin. The size of the macrocycles was determined by SEC measurements. While an alkanedithiol consisting of 20 carbon atoms mainly produced monomeric, dimeric, and trimeric macrocycles with a decreasing yield as the increasing size of the macrocycle, that of 10 carbon atoms resulted in the formation of only dimeric and higher macrocycles.
|
