• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Achieving High-Speed and High-Efficiency Electrochemical Reactions through Ion Arrangement Control in Nanoparticle Crystals

Research Project

Project/Area Number 21K05241
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Review Section Basic Section 36020:Energy-related chemistry
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

Iwama Etsuro  東京農工大学, 工学(系)研究科(研究院), 准教授 (90726423)

Co-Investigator(Kenkyū-buntansha) 直井 勝彦  東京農工大学, 工学(系)研究科(研究院), 名誉教授 (70192664)
沖田 尚久  東京農工大学, 工学(系)研究科(研究院), 助教 (70846625)
Project Period (FY) 2021-04-01 – 2024-03-31
Project Status Completed (Fiscal Year 2023)
Budget Amount *help
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2023: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2022: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2021: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywordsイオン配列制御 / 高速充放電 / エネルギー高効率
Outline of Research at the Start

変動の激しい再生可能エネルギーの高効率回収や、環境発電で発生する微弱電流の高効率利用に繋がる新規蓄電材料の創製を目的としている。ナノ粒子化した電池材料に対し、結晶化度・固溶制御(非結晶化・カチオン無秩序化・欠陥導入・異種金属固溶)行うことで、結晶内の高イオン伝導性と粒子界面における電気伝導性を併せ持つ、安定に高速充放電可能な新規蓄電ナノ複合材料へと転換させる。

Outline of Final Research Achievements

This study focuses on the localized chemical arrangement within and on the surface of crystals (Local Chemical Order, "LCO"), as well as on vacancies, defects, and grain boundaries near the "LCO." Through quantitative analysis of these features, we aim to develop novel energy storage materials that enable high-output, high-efficiency, and stable electrochemical reactions. By controlling the ionic arrangement within the crystal (including cation arrangement and defect introduction), the goal is to manipulate the thermodynamic energy level distribution of redox reactions, thereby achieving more efficient reactions and faster charge-discharge cycles. Applying this approach to the numerous ion-insertion type battery electrode materials synthesized so far is expected to transform them into high-performance, novel energy storage materials.

Academic Significance and Societal Importance of the Research Achievements

局所化学配列(LCO)解析・制御に着目した本研究は、リチウムイオン電池負極材料Li3VO4をモデル材料として、X線散乱解析からcation-disorder化したLi3VO4結晶内の秩序配列距離の数値化を試みた点で画期的である。本手法を他のLCO制御材料に適用することで、秩序配列距離の数値比較を行い、材料特性と紐づけすることで新たな解析軸が生まれ、新規材料開発に繋がると期待される。さらに本研究で開発された材料転換手法を、これまで合成された無数のイオンインサーション型の電池電極材料群を原型として適用することで、高性能な新規蓄電材料群へと転換させることが可能となると期待される。

Report

(4 results)
  • 2023 Annual Research Report   Final Research Report ( PDF )
  • 2022 Research-status Report
  • 2021 Research-status Report
  • Research Products

    (41 results)

All 2024 2023 2022 2021 Other

All Int'l Joint Research (2 results) Journal Article (9 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results) Presentation (30 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results)

  • [Int'l Joint Research] CIRIMAT(フランス)

    • Related Report
      2023 Annual Research Report
  • [Int'l Joint Research] CIRIMAT(フランス)

    • Related Report
      2022 Research-status Report
  • [Journal Article] Ultralong lifespan of SuperRedox Capacitor using Ti-doped Li3V2(PO4)3 cathode with suppressed vanadium dissolution2024

    • Author(s)
      Harada Yuta、Okita Naohisa、Fukuyama Masahiro、Iwama Etsuro、Naoi Wako、Naoi Katsuhiko
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 12 Issue: 3 Pages: 1703-1713

    • DOI

      10.1039/d3ta06240f

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A structural study on a specific Li-ion ordered complex in dimethyl carbonate-based dual-cation electrolytes2024

    • Author(s)
      Chikaoka Yu、Tashiro Tomoya、Sawayama Saki、Kobayashi Ayana、Matsumoto Ayuna、Iwama Etsuro、Naoi Katsuhiko、Fujii Kenta
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 26 Issue: 5 Pages: 3920-3926

    • DOI

      10.1039/d3cp05526d

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhancing the Phase Stability of γ-Phase Li3VO4 for High-Performance Hybrid Supercapacitors: Investigating Influential Factors and Mechanistic Insights2024

    • Author(s)
      Kondo Tatsuya、Matsumura Keisuke、Rozier Patrick、Simon Patrice、Machida Kenji、Takeda Sekihiro、Ishimoto Shuichi、Tamamitsu Kenji、Iwama Etsuro、Naoi Wako、Naoi Katsuhiko
    • Journal Title

      Chemistry of Materials

      Volume: 36 Issue: 5 Pages: 2495-2507

    • DOI

      10.1021/acs.chemmater.3c03255

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Ultrafast cathode characteristics of a nano-V2(PO4)3 carbon composite for rechargeable magnesium batteries2024

    • Author(s)
      Harada Yuta、Chikaoka Yu、Kasai Marina、Koizumi Kyoya、Iwama Etsuro、Okita Naohisa、Orikasa Yuki、Naoi Wako、Naoi Katsuhiko
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 12 Issue: 4 Pages: 2081-2092

    • DOI

      10.1039/d3ta05912j

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Strategy for Ultrafast Cathode Reaction in Magnesium-Ion Batteries Using BF<sub>4</sub> Anion Based Dual-Salt Electrolyte Systems: A Case Study of FePO<sub>4</sub>2023

    • Author(s)
      Chikaoka Yu、Nakata Naomasa、Fujii Kenta、Sawayama Saki、Ochi Riko、Iwama Etsuro、Okita Naohisa、Harada Yuta、Orikasa Yuki、Naoi Wako、Naoi Katsuhiko
    • Journal Title

      ACS Applied Energy Materials

      Volume: - Issue: 9 Pages: 4657-4670

    • DOI

      10.1021/acsaem.2c04182

    • Related Report
      2023 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spray-drying synthesis and vanadium-catalyzed graphitization of a nanocrystalline γ-Li3.2V0.8Si0.2O4/C anode material with a unique double capsule structure2023

    • Author(s)
      Matsumura Keisuke、Iwama Etsuro、Takagi Kenta、Hashizume Naoki、Chikaoka Yu、Okita Naohisa、Naoi Wako、Naoi Katsuhiko
    • Journal Title

      Journal of Materials Chemistry A

      Volume: 11 Issue: 4 Pages: 1841-1855

    • DOI

      10.1039/d2ta07825b

    • Related Report
      2022 Research-status Report
    • Peer Reviewed
  • [Journal Article] Co-substitution Strategy for Boosting Rate-Capability of Lithium-Superionic-Conductor (LISICON)-Type Anode Materials in γ-Li3VO4Li4GeO4Li3PO4 Quasi-Ternary-System2023

    • Author(s)
      Matsumura Keisuke、Iwama Etsuro、Tomochika Yuka、Matsuura Taro、Naoi Wako、Naoi Katsuhiko
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 170 Issue: 1 Pages: 010524-010524

    • DOI

      10.1149/1945-7111/acaf40

    • Related Report
      2022 Research-status Report
    • Peer Reviewed
  • [Journal Article] Controlling the Phase Separation of Dimethyl Carbonate Solvents Using a Dual-Cation System: Applications in High-Power Lithium Ion-Based Hybrid Capacitors2022

    • Author(s)
      Chikaoka Yu、Ochi Riko、Fujii Kenta、Ariga Takaaki、Sakurai Masato、Matsumoto Ayuna、Ueda Tsukasa、Iwama Etsuro、Naoi Katsuhiko
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 126 Issue: 34 Pages: 14389-14398

    • DOI

      10.1021/acs.jpcc.2c03004

    • Related Report
      2022 Research-status Report
    • Peer Reviewed
  • [Journal Article] Degradation of Li3V2(PO4)3-based full-cells containing Li4Ti5O12 or Li3.2V0.8Si0.2O4 anodes modeled by charge-discharge cycling simulations2022

    • Author(s)
      Chikaoka Yu、Okuda Reiko、Hashimoto Taiga、Kuwao Masafumi、Naoi Wako、Iwama Etsuro、Naoi Katsuhiko
    • Journal Title

      Electrochimica Acta

      Volume: 423 Pages: 140558-140558

    • DOI

      10.1016/j.electacta.2022.140558

    • Related Report
      2022 Research-status Report
    • Peer Reviewed
  • [Presentation] Vanadium-Catalyzed Graphitization in Spray-Dry Synthesis for γ-Li3.2V0.8Si0.2O4/C Composites with Core/Shell Architecture2023

    • Author(s)
      Keisuke Matsumura, Etsuro Iwama, Naoki Hashizume, Kensuke Ishimura, Wako Naoi, Katsuhiko Naoi
    • Organizer
      74th Annual Meeting of ISE
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Prolonged Cycle Life for Ultrafast Li4Ti5O12//Ti-doped Li3V2(PO4)3 SuperRedox Capacitor2023

    • Author(s)
      Naohisa Okita, Yuta Harada, Masaya Nakagawa, Etsuro Iwama, Wako Naoi, Katsuhiko Naoi
    • Organizer
      74th Annual Meeting of ISE
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Prolonged Cycle Life for Ultrafast Ti-doped Li3V2(PO4)3 SuperRedox Capacitor2023

    • Author(s)
      Naohisa Okita, Yuta Harada, Masaya Nakagawa, Etsuro Iwama, Wako Naoi, Katsuhiko Naoi
    • Organizer
      7th International Conference on Advanced Capacitors
    • Related Report
      2023 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 高出力型負極材料 Cation-disordered Li3VO4の生成メカニズムの解明2023

    • Author(s)
      引地悠華、石村健介、松村圭祐、岩間悦郎、直井和子、直井勝彦
    • Organizer
      第13回CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] Li3V2(PO4)3/KB複合体のLi量最適化によるMgイオン電池正極特性の向上2023

    • Author(s)
      岩崎祐人、原田雄太、澁澤芽寛、沖田尚久、岩間悦郎、直井和子、直井勝彦
    • Organizer
      第13回CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] 柔粘性イオン結晶 / ポリマー複合体電解質におけるグラファイト負極へのカリウムイオン脱挿入の可逆化2023

    • Author(s)
      栗林日向子、源関輝人、近岡優、直井和子、直井勝彦、岩間悦郎
    • Organizer
      第13回CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] ナトリウムイオン電池用NaFSI-P12FSI電解液におけるハードカーボン負極特性のNa塩濃度依存性とPECポリマー添加効果2023

    • Author(s)
      宮城 莞爾、近岡 優、藤田 正博、直井 勝彦、直井 和子、岩間 悦郎
    • Organizer
      第64回電池討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] nano-V2(PO4)3/カーボン複合体のマグネシウムイオン電池正極特性2023

    • Author(s)
      澁澤芽寛、原田雄太、岩崎裕斗、稲垣葵、沖田尚久、岩間悦郎、直井和子、直井勝彦
    • Organizer
      第64回電池討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] スプレードライ法による高出力型負極材料Cation-disordered Li3VO4の創製2023

    • Author(s)
      石村 健介、引地 悠華、松村 圭祐、近藤 竜也、町田 健治、石本 修一、武田 積洋、岩間 悦郎、直井 和子、玉光 賢次、直井 勝彦
    • Organizer
      第64回電池討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Ti-doped Li3V2(PO4)3/ナノカーボン複合体のスーパーレドックスキャパシタ正極特性2023

    • Author(s)
      沖田尚久、原田雄太、中川正也、岩間悦郎、直井和子、直井勝彦
    • Organizer
      第64回電池討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] グラファイト負極への可逆なK+脱挿入を目指した柔粘性結晶/ポリマー複合電解質の最適化と4V級カリウムイオン電池の構築2023

    • Author(s)
      源関 輝人、栗林 日向子、近岡 優、藤田 正博、直井 勝彦、直井 和子、岩間 悦郎
    • Organizer
      第64回電池討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Disc型Multipore Cavity Microelectrode法 による蓄電材料の新規スクリーニング法の確立2023

    • Author(s)
      稲垣葵、直井和子、岩間悦郎
    • Organizer
      第13回CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] ナノ非結晶領域制御による 高容量ZnSiP2負極の長寿命化2023

    • Author(s)
      松山幸路、山口大介、直井和子、岩間悦郎
    • Organizer
      第13回CSJ化学フェスタ2023
    • Related Report
      2023 Annual Research Report
  • [Presentation] リチウムイオン電池負極用閃亜鉛鉱型AII-BIV-CV化合物ZnSiP2のサイクル特性の向上2023

    • Author(s)
      山口大介、松山幸路、直井和子、岩間悦郎
    • Organizer
      第64回電池討論会
    • Related Report
      2023 Annual Research Report
  • [Presentation] Spray-dry synthesis of capsule-like γ-Li3.2V0.8Si0.2O4/C nanocomposite for pseudocapacitive anode material2022

    • Author(s)
      Keisuke Matsumura,Naoki Hashizume, Etsuro Iwama, Wako Naoi, Patrick Rozier, Patrice Simon, Katsuhiko Naoi
    • Organizer
      ISEECap2022 Bologna
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] Ultralong-Lifespan Li4Ti5O12//Ti doped Li3V2(PO4)3 Full Cell by Significant Suppression of Vanadium Dissolution from LVP electrode2022

    • Author(s)
      Yuta Harada, Masahiro Fukuyama, Naohisa Okita, Etsuro Iwama, Wako Naoi, Katsuhiko Naoi
    • Organizer
      ISEECap2022 Bologna
    • Related Report
      2022 Research-status Report
    • Int'l Joint Research
  • [Presentation] 柔粘性イオン結晶の電解質利用によるリチウムイオン電池のサイクル特性向上2022

    • Author(s)
      橋本大河, 源関輝人, 近岡優, 岩間悦郎,直井和子,直井勝彦
    • Organizer
      第63回電池討論会
    • Related Report
      2022 Research-status Report
  • [Presentation] 窒素急冷法によるP置換型Li3VO4の結晶相制御と負極特性評価2022

    • Author(s)
      松浦太郎,松村圭祐 ,沖田尚久,岩間悦郎,直井和子, 直井勝彦
    • Organizer
      第63回電池討論会
    • Related Report
      2022 Research-status Report
  • [Presentation] 低誘電率溶媒DMCを用いたハイブリッドキャパシ用 高出力型デュアルカチオン電解液の高耐電圧化2022

    • Author(s)
      松岡昇吾, 近岡優, 岩間悦郎,直井和子,直井勝彦
    • Organizer
      第63回電池討論会
    • Related Report
      2022 Research-status Report
  • [Presentation] グリーンケミストリーに基づく高出力型負極材料 Cation-disordered Li3VO4 の創製2022

    • Author(s)
      橋詰 直輝 、松村 圭祐、石村 健介、直井 和子、直井 勝彦 、岩間 悦郎
    • Organizer
      第63回電池討論会
    • Related Report
      2022 Research-status Report
  • [Presentation] Ti-doped Li3V2(PO4)3によるバナジウム溶出抑止と Li4Ti5O12//Li3V2(PO4)3フルセルの長期サイクル安定化2022

    • Author(s)
      原田雄太、沖田尚久、冨田茉依、岩間悦郎、直井和子、直井勝彦
    • Organizer
      第63回電池討論会
    • Related Report
      2022 Research-status Report
  • [Presentation] Disc 型 cavity microelectrode 法を用いた正極粉末材料の電気化学評価2022

    • Author(s)
      片岡春菜、稲垣葵、岩間悦郎
    • Organizer
      第63回電池討論会
    • Related Report
      2022 Research-status Report
  • [Presentation] リチウムイオン電池負極用閃亜鉛鉱型 AII-BIV-CV 化合物 ZnSiP2 の創製と評価2022

    • Author(s)
      髙澤 豊身,山口 大介、松山 幸路、直井 和子、岩間 悦郎
    • Organizer
      第63回電池討論会
    • Related Report
      2022 Research-status Report
  • [Presentation] Hard Carbon//Li3V2(PO4)3フルセルの Liプレドープ処理による発現容量向上2022

    • Author(s)
      宮城莞爾、近岡優、橋本大河、岩間悦郎、直井和子、直井勝彦
    • Organizer
      第12回CSJ化学フェスタ2022
    • Related Report
      2022 Research-status Report
  • [Presentation] 低環境負荷かつ量産可能な合成手法を用いた 高出力型負極材料 Cation-disordered Li3VO4の創製2022

    • Author(s)
      石村健介、橋詰直輝、松村圭祐、岩間悦郎、直井和子、直井勝彦
    • Organizer
      第12回CSJ化学フェスタ2022
    • Related Report
      2022 Research-status Report
  • [Presentation] 低誘電率溶媒DMCを用いた ハイブリッドキャパシタ用 新規デュアルカチオン電解液の開発2022

    • Author(s)
      松本鮎奈、近岡優、藤井健太、越智梨瑚、岩間悦郎、直井和子、直井勝彦
    • Organizer
      第12回CSJ化学フェスタ2022
    • Related Report
      2022 Research-status Report
  • [Presentation] マグネシウムイオン電池用FePO4正極の 高速充放電を実現するDual-salt電解液の開発2022

    • Author(s)
      仲田尚正、近岡優、直井和子、直井勝彦、岩間悦郎
    • Organizer
      第12回CSJ化学フェスタ2022
    • Related Report
      2022 Research-status Report
  • [Presentation] 負極材料ZnSiP2の合成条件による性能比較2022

    • Author(s)
      山口大介、髙澤豊身、松山幸路、直井和子、岩間悦郎
    • Organizer
      第12回CSJ化学フェスタ2022
    • Related Report
      2022 Research-status Report
  • [Presentation] ナノ結晶界面・結晶内のイオン配列制御による蓄電反応の高速化2022

    • Author(s)
      岩間悦郎
    • Organizer
      電気化学会第89回大会
    • Related Report
      2021 Research-status Report
    • Invited
  • [Presentation] スプレードライ法を用いた高速な充放電が可能な負極材料Li3V0.8Si0.2O4/Cナノ複合体の創製2021

    • Author(s)
      橋詰直輝 ・松村圭祐 ・岩間悦郎 ・直井和子 ・直井勝彦
    • Organizer
      第11回CSJ化学フェスタ2021
    • Related Report
      2021 Research-status Report

URL: 

Published: 2021-04-28   Modified: 2025-01-30  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi