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Photocatalytic electron extraction from biomass and its application

Research Project

Project/Area Number 21K19032
Research Category

Grant-in-Aid for Challenging Research (Exploratory)

Allocation TypeMulti-year Fund
Review Section Medium-sized Section 36:Inorganic materials chemistry, energy-related chemistry, and related fields
Research InstitutionKindai University

Principal Investigator

KOMINAMI Hiroshi  近畿大学, 理工学部, 教授 (00257966)

Project Period (FY) 2021-07-09 – 2023-03-31
Project Status Completed (Fiscal Year 2022)
Budget Amount *help
¥5,720,000 (Direct Cost: ¥4,400,000、Indirect Cost: ¥1,320,000)
Fiscal Year 2022: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2021: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords光触媒 / グリセリン / 電子源 / 水素化 / バイオマス / 酸化チタン / 還元
Outline of Research at the Start

太陽エネルギー(光・熱)と光触媒を組み合わせるバイオマスからの電子抽出とその利用に挑戦する。これにより、「バイオマスがもつエネルギー・電子の有効利用」、「省エネルギー物質変換」、「バイオマス廃棄物の無害化」を達成する。具体的には、1)グリセリンに代表されるバイオマスからの電子抽出と光触媒探索、2)高難度バイオマスへの挑戦と還元反応の拡張【拡張性の評価】、3)アンモニアからの電子移動反応と無害化に取り組む。

Outline of Final Research Achievements

From the viewpoint of effective utilization of waste biomass, we focused on glycerin, which is a by-product of soap production (saponification reaction). Glycerin, which is a by-product of the saponification reaction, is produced with a large amount of water and a large amount of energy is required for the recovery and processing. In this study, we developed multiple material conversion reaction systems using TiO2 as a photocatalyst, glycerin as an electron source, and water as a solvent. It was found that glycerin functions effectively as an electron source in photocatalytic reduction reactions in aqueous media, and that it is easier to use as an electron source than other alcohols.

Academic Significance and Societal Importance of the Research Achievements

けん化反応により副生するグリセリンは含水率が高く,回収または処理,いずれの場合においても膨大なエネルギーを必要とするため,水中に溶存するグリセリンを温和な条件下で有効利用する方法が求められている.今回の研究により、光触媒を用いた物質変換反応におけるグリセリンの電子・水素源としての利用は,有用物質を製造するだけではなく,廃棄物の処理を兼ねることを明らかになった。このことは、ともにエネルギーを消費する物質製造と廃棄物処理において、省エネルギーが同時に達成できることを示している。

Report

(3 results)
  • 2022 Annual Research Report   Final Research Report ( PDF )
  • 2021 Research-status Report
  • Research Products

    (62 results)

All 2023 2022 2021 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (48 results) (of which Int'l Joint Research: 14 results,  Invited: 3 results) Book (2 results) Remarks (1 results)

  • [Journal Article] One-pot synthesis of secondary amines from aldehydes and primary amines over trifunctional Au-TiO2 as a water adsorbent, acid catalyst and photocatalyst without the use of hydrogen gas2023

    • Author(s)
      Fudo Eri、Kiyota Yusuke、Osawa Ryuto、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      Applied Catalysis A: General

      Volume: 657 Pages: 119156-119156

    • DOI

      10.1016/j.apcata.2023.119156

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of a stable Au/Ta2O5 plasmonic photoanode for water splitting under visible light irradiation2023

    • Author(s)
      Fudo Eri、Asakura Hiroyuki、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      Sustainable Energy & Fuels

      Volume: 7 Issue: 4 Pages: 1077-1083

    • DOI

      10.1039/d2se01677j

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bifunctions of a Cr hydroxide layer for water splitting over a platinized Au/TiO2 plasmonic photocatalyst under visible light irradiation2023

    • Author(s)
      Fudo Eri、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      Catalysis Today

      Volume: 410 Pages: 323-331

    • DOI

      10.1016/j.cattod.2022.05.024

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen‐Free Hydrogenation of a Nitrogen‐Containing Ring of Quinolines in an Alcoholic Suspension of a Titanium(IV) Oxide Photocatalyst Modified with Metal Cocatalysts (ChemCatChem 22/2022)2022

    • Author(s)
      Kominami Hiroshi、Yato Ryuichi、Tanaka Atsuhiro
    • Journal Title

      ChemCatChem

      Volume: 14 Issue: 22

    • DOI

      10.1002/cctc.202201254

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] AuOx Surface Oxide Layer as a Hole-Transferring Cocatalyst for Water Oxidation over Au Nanoparticle-Decorated TiO2 Photocatalysts2022

    • Author(s)
      Fudo Eri、Tanaka Atsuhiro、Kominami Hiroshi
    • Journal Title

      ACS Applied Nano Materials

      Volume: 5 Issue: 7 Pages: 8982-8990

    • DOI

      10.1021/acsanm.2c01186

    • Related Report
      2022 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bromine Substitution of Organic Modifiers Fixed on a Titanium(IV) Oxide Photocatalyst: A New Strategy Accelerating Visible Light‐Induced Hydrogen‐Free Hydrogenation of Furfural to Furfuryl Alcohol2022

    • Author(s)
      Yamamoto Yuhei, Toda Hibiki, Tanaka Atsuhiro, Kominami Hiroshi
    • Journal Title

      ChemCatChem

      Volume: 14 Issue: 5

    • DOI

      10.1002/cctc.202101496

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Glycerol as an excellent hydrogen and electron source for photocatalytic hydrogenation of nitrobenzene in water2022

    • Author(s)
      Kominami Hiroshi, Onogi Kazuhiro, Tanaka Atsuhiro
    • Journal Title

      Journal of Photochemistry and Photobiology A: Chemistry

      Volume: - Pages: 113963-113963

    • DOI

      10.1016/j.jphotochem.2022.113963

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Modification of gold nanoparticles with a hole-transferring cocatalyst: A new strategy for plasmonic water splitting under irradiation of visible light2021

    • Author(s)
      Fudo Eri, Tanaka Atsuhiro, Iguchi Shoji, Kominami Hiroshi
    • Journal Title

      Sustainable Energy & Fuels

      Volume: 5 Issue: 13 Pages: 3303-3311

    • DOI

      10.1039/d1se00367d

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Controlling the performance of a silver co-catalyst by a palladium core in TiO2-photocatalyzed alkyne semihydrogenation and H2 production2021

    • Author(s)
      Imai Shota, Kojima Yasumi, Fudo Eri, Tanaka Atsuhiro, Kominami Hiroshi
    • Journal Title

      Applied Catalysis A: General

      Volume: 624 Pages: 118331-118331

    • DOI

      10.1016/j.apcata.2021.118331

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] A Pd-Bi Dual-Cocatalyst-Loaded Gallium Oxide Photocatalyst for Selective and Stable Nonoxidative Coupling of Methane2021

    • Author(s)
      Singh Surya Pratap, Yamamoto Akira, Fudo Eri, Tanaka Atsuhiro, Kominami Hiroshi, Yoshida Hisao
    • Journal Title

      ACS Catalysis

      Volume: 11 Issue: 22 Pages: 13768-13781

    • DOI

      10.1021/acscatal.1c03786

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Journal Article] Simultaneous Formation of CO and H2O2 from CO2 and H2O with a Ag-MnOx/CaTiO3 Photocatalyst2021

    • Author(s)
      Soltani Tayyebeh, Yamamoto Akira, Singh Surya Pratap, Anzai Akihiko, Fudo Eri, Tanaka Atsuhiro, Kominami Hiroshi, Yoshida Hisao
    • Journal Title

      ACS Applied Energy Materials

      Volume: 4 Issue: 7 Pages: 6500-6510

    • DOI

      10.1021/acsaem.1c00510

    • Related Report
      2021 Research-status Report
    • Peer Reviewed
  • [Presentation] 流通型光触媒反応器の設計とその評価2023

    • Author(s)
      谷本捷倫・田中淳皓・古南博
    • Organizer
      第131回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] SrTiO3:Alを固定化材料に用いたAuプラズモニック光触媒の調製と水の可視光酸化2023

    • Author(s)
      田中淳皓・不動愛理・久富隆史・堂免一成・古南博
    • Organizer
      第131回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] プラズモン誘起光水素解離を利用した水素化反応のメカニズム2023

    • Author(s)
      岡本珠季・不動愛理・田中淳皓・古南博
    • Organizer
      第131回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] ロジウム酸化物クラスター修飾酸化チタンを用いた可視光水素生成反応2023

    • Author(s)
      福田雅晃・田中淳皓・古南博
    • Organizer
      第131回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 酸化チタン光触媒を用いるC-H結合の活性化2023

    • Author(s)
      吉田圭佑・田中淳晧・古南博
    • Organizer
      第131回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 水の酸化活性を向上させた金プラズモニック光触媒の合成と評価2023

    • Author(s)
      不動愛理・田中淳皓・古南博
    • Organizer
      第131回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] 金-酸化チタンプラズモニック光触媒を用いた可視光水分解に対する水酸化クロムの修飾効果2022

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      石油学会関西支部「第31回研究発表会」日本エネルギー学会関西支部「第67回研究発表会」
    • Related Report
      2022 Annual Research Report
  • [Presentation] 酸化タングステン(IV)光触媒を用いた還元的過酸化水素製紙における熱加速効果2022

    • Author(s)
      紙谷海成、田中淳皓、古南博
    • Organizer
      石油学会関西支部「第31回研究発表会」日本エネルギー学会関西支部「第67回研究発表会」
    • Related Report
      2022 Annual Research Report
  • [Presentation] 金の表面プラズモン共鳴に誘起された光水素解離を利用したスチレンの水素化反応2022

    • Author(s)
      岡本珠季、不動愛理、田中淳皓、古南博
    • Organizer
      石油学会関西支部「第31回研究発表会」日本エネルギー学会関西支部「第67回研究発表会」
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Reaction temperature dependence in reductive production of hydrogene peroxide over WO3 photocatalyst2022

    • Author(s)
      Kaisei Kamitani, Atsuhiro Tanaka,Hiroshi Kominami
    • Organizer
      OKCAT2022
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Plasmon-induced hydrogenation of styrene over Au/ZrO22022

    • Author(s)
      Tamaki Okamoto, Eri Fudo, Atsuhiro Tanaka,Hiroshi Kominami
    • Organizer
      OKCAT2022
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金ー酸化チタンプラズモニック光触媒の物性と活性に与える金粒径の影響2022

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      第130回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Pdナノ粒子のバンド間遷移を活用する光触媒的可視光脱塩素反応2022

    • Author(s)
      澤﨑新、田中淳皓、古南博
    • Organizer
      第130回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] グリセリンを水素源として用いたアルキンの光触媒的部分水素化反応2022

    • Author(s)
      赤股伶於、田中淳皓、古南博
    • Organizer
      第130回 触媒討論会
    • Related Report
      2022 Annual Research Report
  • [Presentation] Acceleration of water splitting on Au/TiO2 by modification of a hole-transferring cocatalyst2022

    • Author(s)
      Eri Fudo, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      12th International Conference on Environmental Catalysis
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Acceleration of visible light induced hydrogenation by introducing Br to organic modifiers fixed on titanium dioxide: A novel method for better photocatalytic material conversion2022

    • Author(s)
      Hibiki Toda, Yuhei Yamamoto, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      12th International Conference on Environmental Catalysis
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic and electrochemical evolution of H2 from alcohol in WO3-Cun+-H2O-O2 system2022

    • Author(s)
      Chihiro Shiba, Hayami Kazuki, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      12th International Conference on Environmental Catalysis
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] H2 evolution over Au/Ta2O5 plasmonic photocatalyst under cocatalyst-free conditions2022

    • Author(s)
      Eri Fudo, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      The 13th Asia-Pacific Conference on Near-Field Optics
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Plasmonic water splitting over gold-loded titanium(IV) oxide modified with a hole-transfoerring cocatalyst under irradiation of visible light2022

    • Author(s)
      Eri Fudo, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      TOCAT9
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Bromine substitution of organic modifiers fixed on a titanium(IV) oxide photocatalyst - A new strategy accelerating visible light-induced hydrogen-free hydrogenation of furfural to furfuryl alcohol -2022

    • Author(s)
      Hibiki Toda, Yuhei Yamamoto, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      TOCAT9
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Hydrogen evolution from alcohol in aqueous suspension of tungsten oxide in the presence of oxygen and copper ion2022

    • Author(s)
      Chihiro Shiba, Hayami Kazuki, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      TOCAT9
    • Related Report
      2022 Annual Research Report
    • Int'l Joint Research
  • [Presentation] アミン系化合物を多機能に利用する光触媒的物質変換反応2022

    • Author(s)
      戸田響生、田中淳皓、古南博
    • Organizer
      第41回 光がかかわる触媒化学シンポジウム
    • Related Report
      2022 Annual Research Report
  • [Presentation] 酸化タングステン光触媒による過酸化水素生成およびスルフィド選択的酸化における熱加速効果2022

    • Author(s)
      紙谷海成、田中淳皓、古南博
    • Organizer
      第41回 光がかかわる触媒化学シンポジウム
    • Related Report
      2022 Annual Research Report
  • [Presentation] Au粒子修飾酸化タングステン光電極を用いた水素生成反応2022

    • Author(s)
      尾上友一、田中淳皓、古南博
    • Organizer
      日本化学会 第102回 春季年会
    • Related Report
      2021 Research-status Report
  • [Presentation] 金プラズモニック光触媒における電子注入に対する金属酸化物伝導帯位置の影響2022

    • Author(s)
      岡本珠季、不動愛理、田中淳皓、古南博
    • Organizer
      日本化学会 第102回 春季年会
    • Related Report
      2021 Research-status Report
  • [Presentation] 可視光照射下における酸化タングステン光触媒を用いたスルフィドの選択的酸化反応2022

    • Author(s)
      紙谷海成、田中淳皓、古南博
    • Organizer
      日本化学会 第102回 春季年会
    • Related Report
      2021 Research-status Report
  • [Presentation] 金ナノ粒子修飾酸化タンタルの光アノード特性2022

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      第129回 触媒討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] Plasmonic photocatalysts having core-shell structure2021

    • Author(s)
      Hiroshi Kominami, Atsuhiro Tanaka, Eri Fudo
    • Organizer
      The 1st Japan-China Symposium on Catalysis (1stJCSC)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] Plasmonic photocatalysts having core-shell structure2021

    • Author(s)
      Hiroshi Kominami, Atsuhiro Tanaka, Eri Fudo
    • Organizer
      International Symposium on Energy/Environmental Catalysis (ISEEC 2022)
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 光触媒を用いるグリーン物質変換2021

    • Author(s)
      古南博
    • Organizer
      光機能材料研究会第83回講演会「光触媒研究と開発技術の最新動向と将来展望」
    • Related Report
      2021 Research-status Report
    • Invited
  • [Presentation] 金プラズモニック光触媒による水の酸化反応に対する正孔移動助触媒の修飾効果2021

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      第12回 触媒科学研究発表会
    • Related Report
      2021 Research-status Report
  • [Presentation] クロム種シェルを導入したパラジウム担持酸化チタン系光触媒のメタノールからの水素生成反応2021

    • Author(s)
      澤﨑新、田中淳皓、古南博
    • Organizer
      第12回 触媒科学研究発表会
    • Related Report
      2021 Research-status Report
  • [Presentation] 金プラズモニック光触媒を用いた脱酸素反応に対する金粒径の影響2021

    • Author(s)
      村田凌祐、田中淳皓、古南博
    • Organizer
      第12回 触媒科学研究発表会
    • Related Report
      2021 Research-status Report
  • [Presentation] 酸素雰囲気における銅イオン共存可視光応答型光触媒による水素生成反応2021

    • Author(s)
      柴千尋、速見一輝、田中淳皓、古南博
    • Organizer
      第40回 光がかかわる触媒化学シンンポジウム
    • Related Report
      2021 Research-status Report
  • [Presentation] アミン類を可視光吸収部位および電子源として用いたアルデヒド類の光触媒的還元反応2021

    • Author(s)
      戸田響生、田中淳皓、古南博
    • Organizer
      第40回 光がかかわる触媒化学シンンポジウム
    • Related Report
      2021 Research-status Report
  • [Presentation] 金ナノ粒子修飾酸化タンタルを用いた可視光水分解2021

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      第128回 触媒討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] 銅ナノ粒子修飾酸化チタン(IV)光触媒によるキノリンの水素化反応2021

    • Author(s)
      谷東龍一、田中淳皓、古南博
    • Organizer
      第128回 触媒討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] グリセリンを正孔捕捉剤として用いたピリジン-N-オキシドの光触媒的脱酸素反応2021

    • Author(s)
      赤股伶於、田中淳皓、古南博
    • Organizer
      第128回 触媒討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] ジオール修飾酸化チタン(IV)光触媒による可視光カルボニル還元反応2021

    • Author(s)
      戸田響生、山本祐平、田中淳皓、古南博
    • Organizer
      第128回 触媒討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] PdコアRuシェル粒子修飾酸化チタン光触媒によるフェノールの水素化反応2021

    • Author(s)
      野本康介、田中淳皓、古南博
    • Organizer
      第11回CSJ化学フェスタ2021
    • Related Report
      2021 Research-status Report
  • [Presentation] Cocatalyst-free hydrogen evolution over Au/Ta2O5 plasmonic photocatalyst under irradiation of visible light2021

    • Author(s)
      Eri Fudo, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      18th Japan-Korea Symposium on Catalysis
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] Photocatalytic hydrogenation of carbonyl groups over titanium(IV) oxide modified with diol compounds under visible light irradiation2021

    • Author(s)
      Hibiki Toda, Yuhei Yamamoto, Atsuhiro Tanaka, Hiroshi Kominami
    • Organizer
      18th Japan-Korea Symposium on Catalysis
    • Related Report
      2021 Research-status Report
    • Int'l Joint Research
  • [Presentation] 金ナノ粒子修飾酸化タンタルを用いた水分解に対する電位および照射波長の影響2021

    • Author(s)
      不動愛理、田中淳皓、古南博
    • Organizer
      第40回 固体・表面光化学討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] 助触媒修飾窒化炭素光触媒によるニトロベンゼンの還元反応2021

    • Author(s)
      高橋正莉、田中淳皓、古南博
    • Organizer
      第40回 固体・表面光化学討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] 酸素および銅イオン存在下における可視光応答型光触媒を用いた水素生成反応2021

    • Author(s)
      柴千尋、速見一輝、田中淳皓、古南博
    • Organizer
      第40回 固体・表面光化学討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] アミン系電子供与剤を可視光吸収部位として用いた光触媒的物質変換反応2021

    • Author(s)
      戸田響生、田中淳皓、古南博
    • Organizer
      第40回 固体・表面光化学討論会
    • Related Report
      2021 Research-status Report
  • [Presentation] 平衡反応と光触媒水素化反応を組み合わせた第2級アミンのone-pot合成2021

    • Author(s)
      清田雄介、大澤琉斗、田中淳皓、古南博
    • Organizer
      日本エネルギー学会関西支部「第66回 研究発表会」、石油学会関西支部「第30回 研究発表会」
    • Related Report
      2021 Research-status Report
  • [Presentation] グリセリンを電子源として用いた光触媒的脱酸素反応2021

    • Author(s)
      赤股伶於、田中淳皓、古南博
    • Organizer
      日本エネルギー学会関西支部「第66回 研究発表会」、石油学会関西支部「第30回 研究発表会」
    • Related Report
      2021 Research-status Report
  • [Book] 電子顕微鏡「固体表面キャラクタリゼーション 機能性材料・ナノマテリアルのためのスペクトロスコ ピー」2022

    • Author(s)
      古南 博、吉田朋子、田中淳皓、山本宗昭
    • Total Pages
      304
    • Publisher
      講談社
    • Related Report
      2021 Research-status Report
  • [Book] プラズモニック光触媒の機能化と水素生成、物質変換への応用「金属ナノ粒子、微粒子の合成、調製と最 新応用技術」2021

    • Author(s)
      古南 博、田中淳皓、不動愛理
    • Total Pages
      558
    • Publisher
      技術情報協会
    • Related Report
      2021 Research-status Report
  • [Remarks] 近畿大学理工学部応用化学科・表面設計化学研究室

    • URL

      https://www.apch.kindai.ac.jp/laboratory/kominami/surface-index.html

    • Related Report
      2022 Annual Research Report 2021 Research-status Report

URL: 

Published: 2021-07-13   Modified: 2024-01-30  

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