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Observation of Layer Fluctuations and Dynamics in Side-Chain polymer Nematic Liquid Crystals

Research Project

Project/Area Number 22340120
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Biophysics/Chemical physics
Research InstitutionTokyo Institute of Technology

Principal Investigator

TOKITA Masatoshi  東京工業大学, 理工学研究科, 准教授 (30301170)

Co-Investigator(Kenkyū-buntansha) MATSUOKA Tatsuro  名古屋大学, 大学院工学研究科, 准教授 (60252269)
KANG Sungmin  東京工業大学, 大学院理工学研究科, 助教 (00523664)
Project Period (FY) 2010-04-01 – 2013-03-31
Project Status Completed (Fiscal Year 2013)
Budget Amount *help
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2012: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥9,360,000 (Direct Cost: ¥7,200,000、Indirect Cost: ¥2,160,000)
Keywords二量体液晶 / 動的光散乱 / ネマチック液晶 / せん断流動 / スメクチック揺らぎ / 高分子液晶 / 光子相関スペクトル / 動的光散乱法 / スメクチック液晶 / 層ゆらぎ / せん断流動配向 / 側鎖型高分子液晶
Research Abstract

The dynamic behaviour of twin dimer nematic liquid crystals were investigated for alpha,omega-bis(4-cyanobiphenyl-4'-yloxy)alkanes (BCBO-m, m = 7-10: the number of spacer methylene units) by dynamic light scattering and the frequencies of the splay, twist and bend modes were determined successfully. The frequencies of BCBO-m are dependent on m: they oscillate depending on the parity of m with exhibiting larger values for even-membered BCBO-m and decrease with increasing m. Such an odd-even oscillation in the splay and bend mode frequencies are governed by that in the elastic constants.

Report

(4 results)
  • 2013 Final Research Report ( PDF )
  • 2012 Annual Research Report
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (40 results)

All 2014 2013 2012 2011 2010 Other

All Journal Article (25 results) (of which Peer Reviewed: 25 results) Presentation (15 results)

  • [Journal Article] Cholesteric induction power of β-galactose derivatives2014

    • Author(s)
      Kazuhiro Marumo, Manabu Itoh, Sungmin Kang, Koichi Sakajiri, Junji Watanabe and Masatoshi Tokita
    • Journal Title

      Liquid Crystals

      Volume: 41 Issue: 2 Pages: 234-238

    • DOI

      10.1080/02678292.2013.851288

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Macrocyclised pheynyl cinnamate dimer utilisable as photoresponsive chiral dopant for nematic liquid crystals2013

    • Author(s)
      Tokita M., Itoh M., Marumo K., Harada Y., Kang S., Sakajiri K., & Watanabe J.
    • Journal Title

      Liquid Crystals

      Volume: 40(7) Issue: 7 Pages: 900-905

    • DOI

      10.1080/02678292.2013.790094

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Lamellar Morphology of an ABA Triblock Copolymer with a Main-Chain Nematic Polyester Central Block2013

    • Author(s)
      Sato K., Koga M., Kang S., Sakajiri K., Watanabe J., & Tokita M.
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: 214(10) Issue: 10 Pages: 1089-1093

    • DOI

      10.1002/macp.201300073

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Thermotropic behavior of syndiotactic polymethylenes with alkyloxycarbonyl side chains2013

    • Author(s)
      Tokita M., Shikinaka K., Hoshino T., Fujii K., Mikami J., Koshimizu N. Shigehara K.
    • Journal Title

      Polymer

      Volume: 54(3) Issue: 3 Pages: 995-998

    • DOI

      10.1016/j.polymer.2012.12.072

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-density poly(hexyl methacrylate) brushes offering a surface for near-zero azimuthal anchoring of liquid crystals at room temperature2013

    • Author(s)
      Sato O., Kasai T., Sato M., Sakajiri K., Tsujii Y., Kang S., Tokita M.
    • Journal Title

      Journal of Materials Chemistry C

      Volume: 1(48) Issue: 48 Pages: 7992-7995

    • DOI

      10.1039/c3tc31700e

    • Related Report
      2013 Final Research Report 2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Viscoelastic PS brush surface offering strong anchoring at low temperature and near-zero anchoring at high temperature for LC molecules2013

    • Author(s)
      Sato O., Kasai T., Nomura A., Tsujii Y., Kang S., Tokita M., & Watanabe J.
    • Journal Title

      Liquid Crystals

      Volume: 40(2) Issue: 2 Pages: 221-227

    • DOI

      10.1080/02678292.2012.736546

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enlarged helical twisting power in chiral cyclic dimers based on conventional chiral alkyl diols2013

    • Author(s)
      Itoh M., Hegi H., Marumo K., Sakajiri K., Kang S., Tokita M., & Watanabe J.
    • Journal Title

      Liquid Crystals

      Volume: 40(3) Issue: 3 Pages: 339-344

    • DOI

      10.1080/02678292.2012.747706

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Influence of Smectic Liquid Crystallinity on Lamellar Microdomain Structure in a Main-Chain Liquid Crystal Block Copolymer Fiber2013

    • Author(s)
      Koga M., Sato K., Kang S., Sakajiri K., Watanabe J., & Tokita M.
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: 214(20) Issue: 20 Pages: 2295-2300

    • DOI

      10.1002/macp.201300353

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of regularly spaced wetting ridges at 1μm intervals on the surface of a liquid-crystalline polymer2012

    • Author(s)
      Okuda S., Yoshihara S., Kang S., Tokita M., & Watanabe J.
    • Journal Title

      Langmuir : The ACS Journal of Surfaces and Colloids

      Volume: 28(41) Issue: 41 Pages: 14518-21

    • DOI

      10.1021/la303335x

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Identifying smectic I phase of main-chain PB-10 polyester consisting of 4,4′-biphenol and 1,10-dodecanoic acid by fibre X-ray diffraction2012

    • Author(s)
      Tokita M., Okuda S., Yoshihara S., Takahashi C., Kang S., Sakajiri K., & Watanabe J.
    • Journal Title

      Polymer

      Volume: 53(24) Issue: 24 Pages: 5596-5599

    • DOI

      10.1016/j.polymer.2012.09.035

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Well-Ordered Lamellar Microphase- Separated Morphology of an ABA Triblock Copolymer Containing a Main-Chain Liquid Crystalline Polyester as the Middle Segment 2: Influence of Amorphous Segment Molecular Weight2012

    • Author(s)
      Koga M., Ishige R., Sato K., Ishii T., Kang S., Sakajiri K., Tokita M.
    • Journal Title

      Macromolecules

      Volume: 45(23) Issue: 23 Pages: 9383-9390

    • DOI

      10.1021/ma3015307

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel Behavior in Shear Flow Orientation of Side-Chain Polymethacrylate Nematic Liquid Crystals2012

    • Author(s)
      Tokita M., Ikoma A., Ishii T., Kang S., Watanabe J., & Matsuoka T.
    • Journal Title

      Macromolecules

      Volume: 45(11) Issue: 11 Pages: 4857-4862

    • DOI

      10.1021/ma3006763

    • Related Report
      2013 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Notable formation of a cubic phase from small bent-angle molecules based on the 1,7-naphthalene central core and alkylthio tails2012

    • Author(s)
      Sungmin Kang, Masatoshi Tokita, Junji Watanabe
    • Journal Title

      Soft Matter

      Volume: 8 Issue: 6 Pages: 1916-1922

    • DOI

      10.1039/c1sm06554h

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regular undulation and polarization modulation on the film surface of a planarly aligned SmC* polymer2011

    • Author(s)
      Zhang C., Ishige R., Yasumatsu R., Kang S., Tokita M., & Watanabe J.
    • Journal Title

      Soft Matter

      Volume: 7(1) Issue: 1 Pages: 258-264

    • DOI

      10.1039/c0sm00668h

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-Density Poly(methyl methacrylate) Brushes as Anchoring Surfaces of Nematic Liquid Crystals2011

    • Author(s)
      Tokita M., Sato O., Inagaki Y., Nomura A., Tsujii Y., Kang S., Watanabe J.
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 50(7) Issue: 7R Pages: 071701-071701

    • DOI

      10.1143/jjap.50.071701

    • NAID

      40018915964

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Well-Ordered Lamellar Microphase- Separated Morphology of an ABA Triblock Copolymer Containing a Main-Chain Liquid Crystalline Polyester as the Middle . Macromolecules2011

    • Author(s)
      Ishige R., Ishii T., Tokita M., Koga M., Kang S., & Watanabe J.
    • Journal Title

      Macromolecules

      Volume: 44(12) Issue: 12 Pages: 4586-4588

    • DOI

      10.1021/ma200409f

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Two-Step Smectic CA Phase Formation from Isotropic Liquid upon Supercooling in Main-Chain Liquid-Crystalline BB-5(1-Me) Polyester2011

    • Author(s)
      Ishige R., Tokita M., Funaoka S., Kang S., & Watanabe J.
    • Journal Title

      Macromolecular Chemistry and Physics

      Volume: 212(1) Issue: 1 Pages: 48-54

    • DOI

      10.1002/macp.201000398

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhancement of the cholesteric induction power by macrocyclization in liquid crystal dimers with a chiral spacer2011

    • Author(s)
      Itoh M., Tokita M., Hegi H., Hayakawa T., Kang S., & Watanabe J.
    • Journal Title

      Journal of Materials Chemistry

      Volume: 21(6) Issue: 6 Pages: 1697-1699

    • DOI

      10.1039/c0jm03161e

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Unusual chain configuration of main-chain liquid crystal polyesters having Y-shaped mesogens in nematic phase2011

    • Author(s)
      Tokita M., Kato K., Ishige R., Okuda S., Kawauchi S., Okoshi K., Watanabe J.
    • Journal Title

      Polymer

      Volume: 52(25) Issue: 25 Pages: 5830-5835

    • DOI

      10.1016/j.polymer.2011.10.047

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Control over Internal Structure of Liquid Crystal Polymer Nanofibers by Electrospinning2010

    • Author(s)
      Nakashima K., Tsuboi K., Matsumoto H., Ishige R., Tokita M., Watanabe J., & Tanioka A.
    • Journal Title

      Macromolecular Rapid Communications

      Volume: 31(18) Issue: 18 Pages: 1641-5

    • DOI

      10.1002/marc.201000211

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Spontaneous Formation of Polar Liquid Crystal in Lyotropic Solution of Helical Poly(γ-Benzyl Glutamate)2010

    • Author(s)
      Yen C.-C., Taguchi Y., Tokita M., & Watanabe J.
    • Journal Title

      Molecular Crystals and Liquid Crystals

      Volume: 516(1) Issue: 1 Pages: 91-98

    • DOI

      10.1080/15421400903400712

    • Related Report
      2013 Final Research Report
    • Peer Reviewed
  • [Journal Article] Control over internal structure of liquid crystal polymer nanofibers by electrospinning2010

    • Author(s)
      Keita Nakashima, Masatoshi Tokita, ほか5名
    • Journal Title

      Macromol.Rapid.Commun.

      Volume: 31 Pages: 1641-1645

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fiexible, Transparent Nanocomposite Film with a Large Clay Component and Ordered Structure Obtained by a Simple Solution-Casting Method2010

    • Author(s)
      Kazuhiro Shikinaka, Masatoshi Tokita, ほか5名
    • Journal Title

      Langmuir

      Volume: 26 Pages: 12493-12495

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of a homochiral antiferroelectric ground state in asymmetric bent-shaped molecules2010

    • Author(s)
      Seng Kue Lee, Sungmin Kang, Masatoshi Tokita, Junji Watanabe
    • Journal Title

      Liq.Cryst.

      Volume: 37 Pages: 593-598

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unique Reflection Property Due to Bumpy Multilayer Structure in Elytra of Rhomborrhina unicolor2010

    • Author(s)
      Susumu Edo, Masatoshi Tokita, ほか3名
    • Journal Title

      Jpn.J.Appl.Phys

      Volume: 49

    • NAID

      40017085103

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] ナノファイバーを利用した金属ナノワイヤーネットワークと透明電極膜の開発2013

    • Author(s)
      東啓介,坂尻浩一,松本英俊,姜聲敏,渡辺順次,戸木田雅利
    • Organizer
      第22回ポリマー材料フォーラム講演予稿集
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2013-11-13
    • Related Report
      2013 Final Research Report
  • [Presentation] 周期長に分布をもつコレステリック液晶フィルムの開発2013

    • Author(s)
      原田好寛,姜聲敏,坂尻浩一,戸木田雅利,渡辺順次
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2013-09-13
    • Related Report
      2013 Final Research Report
  • [Presentation] ポリスチレン/低分子液晶混合系における均一ネマチック相からの相分離挙動2013

    • Author(s)
      中村祐貴,姜聲敏,戸木田雅利,渡辺順次
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2013-09-11
    • Related Report
      2013 Final Research Report
  • [Presentation] 主鎖型スメクチック液晶性セグメントがブロック共重合体のラメラ構造に与える影響2013

    • Author(s)
      古賀舞都,佐藤和徳,姜聲敏,渡辺順次,戸木田雅利
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Year and Date
      2013-09-11
    • Related Report
      2013 Final Research Report
  • [Presentation] ビフェノールをメソゲンとした液晶性ポリエステルのスメクチック液晶構造と長周期ラメラ構造2013

    • Author(s)
      戸木田雅利,高橋千春,吉原秀輔,渡邊順次
    • Organizer
      繊維学会秋季研究発表会
    • Place of Presentation
      豊田工業大学
    • Year and Date
      2013-09-05
    • Related Report
      2013 Final Research Report
  • [Presentation] Well-Ordered Lamellar Microphase-Separated Morphology of an ABA Triblock Copolymer Containing a Main-Chain Liquid Crystalline Polyester Having a Wide Molecular Weight Dispersity as the Middle Segment2012

    • Author(s)
      Masatoshi Tokita
    • Organizer
      2012 Japan-Taiwan Bilateral Polymer Symposium (JTBPS'12)
    • Place of Presentation
      West Japan General Exhibition Center, Kitakyushu, Japan
    • Related Report
      2013 Final Research Report
  • [Presentation] Well-Ordered Lamellar Microphase-Separated Morphology of an ABA Triblock Copolymer Containing a Main-Chain Liquid Crystalline PolyesterHaving a Wide Molecular Weight Dispersity as the Middle Segment2012

    • Author(s)
      Masatoshi Tokita
    • Organizer
      2012 Japan-Taiwan Bilateral Polymer Symposium (JTBPS'12)
    • Place of Presentation
      West Japan General Exhibition Center, Kitakyushu, Japan
    • Related Report
      2011 Annual Research Report
  • [Presentation] 主鎖型液晶性高分子BB-5(1-Me)で観測される特異な二つの液晶化モード2010

    • Author(s)
      石毛亮平,姜聲敏,戸木田雅利,ほか3名
    • Organizer
      高分子討論会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-16
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] ポリメチルメタクリレート高密度ポリマーブラシによるネマチック液晶アンカリング2010

    • Author(s)
      稲垣佑典,姜聲敏,戸木田雅利,ほか5名
    • Organizer
      日本液晶学会討論会
    • Place of Presentation
      九州大学
    • Year and Date
      2010-09-05
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] 側鎖型液晶性高分子のスメクチック-ネマチック相転移に伴う配向状態変化2010

    • Author(s)
      生駒文,姜聲敏,戸木田雅利,ほか2名
    • Organizer
      繊維学会年次大会
    • Place of Presentation
      タワーホール船堀
    • Year and Date
      2010-06-17
    • Related Report
      2013 Final Research Report 2010 Annual Research Report
  • [Presentation] ナノファイバーを利用した金属ナノワイヤーネットワークと透明電極膜の開発

    • Author(s)
      東 啓介 , 坂尻 浩一 , 松本 英俊 , 姜 聲敏 , 渡辺 順次 , 戸木田 雅利
    • Organizer
      第22回ポリマー材料フォーラム講演予稿集
    • Place of Presentation
      タワーホール船堀
    • Related Report
      2012 Annual Research Report
  • [Presentation] ビフェノールをメソゲンとした液晶性ポリエステルのスメクチック液晶構造と長周期ラメラ構造

    • Author(s)
      戸木田雅利 , 高橋千春 , 吉原秀輔 , 渡邊順次
    • Organizer
      繊維学会秋季研究発表会
    • Place of Presentation
      豊田工業大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] ポリスチレン/低分子液晶混合系における均一ネマチック相からの相分離挙動

    • Author(s)
      中村祐貴 , 姜聲敏 , 戸木田雅利 , 渡辺順次
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 主鎖型スメクチック液晶性セグメントがブロック共重合体のラメラ構造に与える影響

    • Author(s)
      古賀舞都 , 佐藤和徳 , 姜聲敏 , 渡辺順次 , 戸木田雅利
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2012 Annual Research Report
  • [Presentation] 周期長に分布をもつコレステリック液晶フィルムの開発

    • Author(s)
      原田好寛 , 姜聲敏 , 坂尻浩一 , 戸木田雅利 , 渡辺順次
    • Organizer
      第62回高分子討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2012 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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