Construction of Polycyclic Aromatic Compounds Containing Heavier Group 14 Elements and Development of Their Functions by Utilizing the Features of Main Group Elements
| Project/Area Number |
22350017
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
SASAMORI Takahiro 京都大学, 化学研究所, 准教授 (70362390)
MIZUHATA Yoshiyuki 京都大学, 化学研究所, 助教 (30437264)
AGOU Tomohiro 京都大学, 化学研究所, 助教 (90466798)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2012: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2011: ¥7,020,000 (Direct Cost: ¥5,400,000、Indirect Cost: ¥1,620,000)
Fiscal Year 2010: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
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| Keywords | 有機元素化学 / 典型元素 / ケイ素 / π拡張分子 / 芳香族化合物 |
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| Research Abstract |
In order to reveal the effect of a number of heavier elements on aromatic skeletons, we investigated the constructions of various aromatic skeletons including two silicon or silicon and phosphorus atoms. As a result, novel disilaaromatic compounds have been successfully synthesized and we have revealed their functions on the basis of element chemistry. In addition, the construction of the fundamental skeletons of polycyclic disilaaromatic compounds and heavier heterocyclic compounds has been achieved.
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Report
(4 results)
Research Products
(132 results)
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[Journal Article] Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes2012
Author(s)
Agou, T.; Sugiyama, Y.; Sasamori, T.; Sakai, H.; Furukawa, Y.; Takagi, N.; Guo, J. D.; Nagase, S.; Hashizume, D.; Tokitoh, N
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Journal Title
J. Am. Chem. Soc.
Volume: 134
Pages: 4120-4123
Related Report
Peer Reviewed
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[Journal Article] Catalytic Activities for Olefin Polymerization: Titanium(III), Titanium(IV), Zirconium(IV), and Hafnium(IV) β-Diketiminato, 1-Aza-1,3-butadienyl-imido, and 1-Aza-2-butenyl-imido Complexes Bearing an Extremely Bulky Substituent, the Tbt Group (Tbt=2,4,6-[(2012
Author(s)
Hamaki, H.; Takeda, N.; Nabika, M.; Tokitoh, N
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Journal Title
Macromolecules
Volume: 45
Pages: 1758-1769
Related Report
Peer Reviewed
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[Journal Article] Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives2010
Author(s)
Tsurusaki, A.; Nagahora, N.; Sasamori, T.; Matsuda, K.; Kanemitsu, Y.; Watanabe, Y.; Hosoi, Y.; Furukawa, Y.; Tokitoh, N
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Journal Title
Bull. Chem. Soc. Jpn
Volume: 83
Pages: 456-478
NAID
Related Report
Peer Reviewed
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[Journal Article] Synthesis, Structures, and Reactivity of Kinetically Stabilized Anthryldiphosphene Derivatives2010
Author(s)
Tsurusaki, A.; Nagahora, N.; Sasamori, T.; Matsuda, K.; Kanemitsu, Y.; Watanabe, Y.; Hosoi, Y.; Furukawa, Y.; Tokitoh, N.
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Journal Title
Bull.Chem.Soc.Jpn.
Volume: 83
Pages: 456-478
NAID
Related Report
Peer Reviewed
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[Presentation] Kinetically Stabilized 1,2-Diaryl-1,2-dihydrodisilenes: Synthesis, Structure, and Their Thermal Isomerization2011
Author(s)
Tokitoh, N.; Agou, T.; Sugiyama, Y.; Sasamori, T.; Takagi, N.; Nagase, S
Organizer
The 15th Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry for Renewable Energy Research
Place of Presentation
Jeju, Korea
Year and Date
2011-10-07
Related Report
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[Presentation] Kinetically Stabilized 1,2-Diaryl-1,2-dihydrodisilenes : Synthesis, Structure, and Their Thermal Isomerization2011
Author(s)
Tokitoh, N.; Agou, T.; Sugiyama, Y.; Sasamori, T.; Takagi, N.; Nagase, S.
Organizer
The 15th Korea-Japan Joint Symposium on Organometallic and Coordination Chemistry for Renewable Energy Research
Place of Presentation
Jeju, Korea(招待講演)
Year and Date
2011-10-07
Related Report
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[Presentation] Synthesis, Structure and Reactivity of Kinetically Stabilized 1,2-Diaryl-1,2-dihydrodisilenes2011
Author(s)
Tokitoh, N.; Agou, T.; Sugiyama, Y.; Sasamori, T.; Takagi, N.; Nagase, S
Organizer
The 16th International Symposium on Silicon Chemistry
Place of Presentation
Hamilton, Canada
Year and Date
2011-08-16
Related Report
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[Presentation] Synthesis, Structure, and Reactivity of Kinetically Stabilized 1,2-Diaryl-1,2-dihydrodisilenes2011
Author(s)
Tokitoh, N.; Agou, T.; Sugiyama, Y.; Sasamori, T.; Takagi, N.; Nagase, S.
Organizer
Sixteenth International Symposium on Silicon Chemistry (ISOS-XVI)
Place of Presentation
Hamilton, Canada(招待講演)
Year and Date
2011-08-16
Related Report
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[Presentation] Chemistry of Heavy Aromatics
Author(s)
Tokitoh, N.
Organizer
Chemistry Colloquium at Department of Chemistry, The Chinese University of Hong Kong
Place of Presentation
The Chinese University of Hong Kong, Hong Kong
Related Report
Invited
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