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Design and Functionalization of Noncovalently Linked Metal Complexes for Development of Supramolecular Synthetic Chemistry

Research Project

Project/Area Number 22350061
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionKobe University

Principal Investigator

TSUDA Akihiko  神戸大学, 理学研究科, 准教授 (20359657)

Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥17,940,000 (Direct Cost: ¥13,800,000、Indirect Cost: ¥4,140,000)
Fiscal Year 2012: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2011: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2010: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Keywords超分子 / 光反応 / 金属錯体 / ホスト-ゲスト / 反応速度 / 触媒 / 超分子光反応 / キノン / 自己活性化 / 超分子反応 / 分子認識 / ハロメタン / 光分解 / ポリカーボネート / 尿素 / 二種活性化超分子反応 / 反応速度論 / エステル交換反応 / 自己活性化超分子
Research Abstract

In this research project, we have developed a novel supramolecular synthetic chemistry, which designs noncovalent metal complexes for the organic reactions. We found that characteristic electronic interactions of the host and guest, occurring in the ground and/or photoexcited states, bring about a variety of the unique supramolecular reactions. This reaction concept is also available into the photoreactions, whose handling is usually more difficult than that of the thermal reactions, and will be an important methodology for development of the next-generationreactions.

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (59 results)

All 2013 2012 2011 2010 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (46 results) (of which Invited: 4 results) Book (2 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Photochemical Molecular Storage of Cl_2, HCl, and COCl_2: Synthesis of Organochlorine Compounds, Salts, Ureas, and Polycarbonate with a Photodecomposed Chloroform2012

    • Author(s)
      Yuki Kuwahara, Ailing Zhang, Haruka Soma, Akihiko Tsuda
    • Journal Title

      Organic Letter

      Volume: 14巻 Issue: 13 Pages: 3376-3379

    • DOI

      10.1021/ol301356r

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Brominated Methanes as Photo-Responsive Molecular Storage of Elemental Br_22012

    • Author(s)
      Kazumitsu Kawakami, Akihiko Tsuda
    • Journal Title

      Chemistry An Asian Journal

      Volume: 7巻 Issue: 10 Pages: 2240-2252

    • DOI

      10.1002/asia.201200322

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Self-Assembled Helical Anthracene Nanofibre Whose P- and M-Isomers Show Unequal Linear Dichroism in a Vortex2011

    • Author(s)
      Yasunari Ando, Tomoki Sugihara, Kenjiro Kimura, Akihiko Tsuda
    • Journal Title

      Chemical Communiations

      Volume: 47巻 Issue: 42 Pages: 11748-11750

    • DOI

      10.1039/c1cc14241k

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic Visualization of Right- and Left-handed Helical Alignments of DNA in Chiral Vortex Flows2011

    • Author(s)
      Yuya Tsujimoto, Machiko Ie, Yasunari Ando, Taiki Yamamoto, Akihiko Tsuda
    • Journal Title

      Bulltin of the Chemical Society fo Japan

      Volume: 84巻 Issue: 10 Pages: 1013-1038

    • DOI

      10.1246/bcsj.20110178

    • NAID

      10030214895

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Doubly Activated Supramolecular Reaction: Transesterification of Acyclic Oligoether Esters with Metal Alkoxides2011

    • Author(s)
      Kazumitsu Kawakami, Yoshihisa Sei, Kentaro Yamaguchi, Akihiko Tsuda
    • Journal Title

      Journal of Organic Chemistry

      Volume: 76巻 Pages: 875-881

    • URL

      http://pubs.acs.org/doi/abs/10.1021/jo102106g

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Doubly Activated Supramolecular Reaction : Transesterification of Acyclic Oligoether Esters with Metal Alkoxides2011

    • Author(s)
      Kazumitsu Kawakami, Yoshihisa Sei, Kentaro Yamaguchi, Akihiko Tsuda
    • Journal Title

      Journal of Organic Chemistry

      Volume: 76(3) Pages: 875-881

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic Visualization of Sound-Induced Liquid Vibrations Using a Supramolecular Nanofiber2010

    • Author(s)
      Akihiko Tsuda, Yuka Nagamine, Reiko Watanabe, Yoshiki Nagatani, Noriyuki Ishii, Takuzo Aida
    • Journal Title

      Nature Chemistry

      Volume: 2巻 Pages: 977-983

    • URL

      http://www.nature.com/nchem/journal/v2/n11/abs/nchem.825.html

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Excitation Energy Migration Processes in Self-Assembled Porphyrin Boxes Constructed by Conjugated Porphyrin Dimers2010

    • Author(s)
      Pyosang Kim, Jong Min Lim, Min-Chul Yoon, Junko Aimi, Takuzo Aida, Akihiko Tsuda, Dongho Kim
    • Journal Title

      Journal of Physical Chemistry B

      Volume: 114巻 Pages: 9157-9164

    • URL

      http://pubs.acs.org/doi/abs/10.1021/jp103767m

    • Related Report
      2012 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spectroscopic Visualization of Sound-Induced Liquid Vibrations Using a Supramolecular Nanofibre2010

    • Author(s)
      Akihiko Tsuda, Yuka Nagamine, Reiko Watanabe, Yoshiki Nagatani, Noriyuki Ishii, Takuzo Aida
    • Journal Title

      Nature Chemistry

      Volume: 2 Pages: 977-983

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] クロロホルムの光リサイクル反応:ウレア、カーボネート、カルバメートへの変換2013

    • Author(s)
      津田 明彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学 びわこくさつキャンパス
    • Related Report
      2012 Final Research Report
  • [Presentation] クロロホルムの光リサイクル反応:ウレア、カーボネ ート、カルバメートへの変換2013

    • Author(s)
      津田 明彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこくさつキャンパス、滋賀県
    • Related Report
      2012 Annual Research Report
  • [Presentation] ナノファイバーによる音の認識(1):アントラセン超分子ポリマー2013

    • Author(s)
      津田 明彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこくさつキャンパス、滋賀県
    • Related Report
      2012 Annual Research Report
  • [Presentation] テトラクロロエタンおよびテトラクロロエチレンの光リサイクル反応:ウレア、アミド、カーボネート、エステルへの変換2013

    • Author(s)
      津田 明彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこくさつキャンパス、滋賀県
    • Related Report
      2012 Annual Research Report
  • [Presentation] ナノファイバーによる音の認識(3):ポルフィリン共有結合ポリマーの開発2013

    • Author(s)
      津田 明彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこくさつキャンパス、滋賀県
    • Related Report
      2012 Annual Research Report
  • [Presentation] 大環状オクタピロール骨格を持つフォトクロミックナノリングの開発2013

    • Author(s)
      津田 明彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこくさつキャンパス、滋賀県
    • Related Report
      2012 Annual Research Report
  • [Presentation] ナノファイバーによる音の認識(2):超分子ナノチューブの開発2013

    • Author(s)
      津田 明彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこくさつキャンパス、滋賀県
    • Related Report
      2012 Annual Research Report
  • [Presentation] 音のナノサイエンス:声で整列するナノファイバー2012

    • Author(s)
      津田明彦
    • Organizer
      ナノ学会第10回大会
    • Place of Presentation
      大阪大学会館
    • Year and Date
      2012-06-16
    • Related Report
      2012 Final Research Report
  • [Presentation] ねじれ構造を持つフォトクロミックナノリングの光構造制御(1)2012

    • Author(s)
      劉冠凡
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] ねじれ構造を持つフォトクロミックナノリングの光構造制御(2)2012

    • Author(s)
      山本泰輝
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Year and Date
      2012-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] キノン誘導体とオレフィンによる超分子光反応2012

    • Author(s)
      山元博明
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] ハロメタンの光リサイクル反応(1):クロロホルムと一級アミン類からの尿素誘導体の合成2012

    • Author(s)
      津田明彦
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] ハロメタンの光リサイクル反応(2):クロロホルムとフェノール2012

    • Author(s)
      桑原佑貴
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] ハロメタンの光リサイクル反応(3):ブロモメタンからの光臭素発生とその臭素化反応への応用2012

    • Author(s)
      川上一光
    • Organizer
      日本化学会第92春季年会(2012)
    • Place of Presentation
      慶應義塾大学(神奈川県)
    • Year and Date
      2012-03-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Acoustic Alignment of Supramolecular Nanofibers by Audible Sound2012

    • Author(s)
      津田明彦
    • Organizer
      Recent Advances in Spectroscopy and Microscopy: Fundamentals and Applications to Materials and Biology
    • Place of Presentation
      インド
    • Related Report
      2012 Final Research Report
  • [Presentation] 音と光による分子および分子集合体の状態と反応制御2012

    • Author(s)
      津田 明彦
    • Organizer
      第47回有機反応若手の会
    • Place of Presentation
      湯郷グランドホテル
    • Related Report
      2012 Final Research Report
  • [Presentation] Alignments of Supramolecular Nanofibers by Audible Sound2012

    • Author(s)
      津田 明彦
    • Organizer
      27th Philippine Chemistry Congress
    • Place of Presentation
      フィリピン
    • Related Report
      2012 Final Research Report
  • [Presentation] Alignments of Supramolecular Nanofibers by Audible Sound2012

    • Author(s)
      Akihiko Tsuda
    • Organizer
      27th Philippine Chemistry Congress
    • Place of Presentation
      Manila,Philippine
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 音のナノサイエンス:声で整列するナノファイバー2012

    • Author(s)
      津田 明彦
    • Organizer
      ナノ学会第10回大会
    • Place of Presentation
      大阪大学、大阪府
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] 音と光による分子および分子集合体の状態と反応制御2012

    • Author(s)
      津田 明彦
    • Organizer
      第47回有機反応若手の会
    • Place of Presentation
      湯郷グランドホテル、岡山県
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] ハロメタン光化学分子ストレージを利用 した有機反応化学2012

    • Author(s)
      津田 明彦
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京工業大学大岡山キャンパス、東京都
    • Related Report
      2012 Annual Research Report
  • [Presentation] Acoustic Alignment of Supramolecular Nanofibers by Audible Sound2012

    • Author(s)
      Akihiko Tsuda
    • Organizer
      Recent Advances in Spectroscopy and Microscopy: Fundamentals and Applications to Materials and Biology
    • Place of Presentation
      Hyderabad,India
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Chiral Hydrodynamic Alignments of Helical Nanofibers in a Vortex2011

    • Author(s)
      津田 明彦
    • Organizer
      BIT's 1st Annual World Congress of Nano-S&T
    • Place of Presentation
      中国
    • Year and Date
      2011-10-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Chiral Hydrodynamic Alignments of Helical Nanofibers in a Vortex2011

    • Author(s)
      津田明彦
    • Organizer
      BIT's 1^<st> Annual World Congress of Nano-S&T
    • Place of Presentation
      Dalinan, China(招待講演)
    • Year and Date
      2011-10-26
    • Related Report
      2011 Annual Research Report
  • [Presentation] Spectroscopic Visualization of Audible Sound-Induced Liquid Vibrations Using A Supramolecular Nanofiber2011

    • Author(s)
      津田 明彦
    • Organizer
      International Conference on Polymers and Advanced Materials POLYMAT 2011
    • Place of Presentation
      メキシコ
    • Year and Date
      2011-10-18
    • Related Report
      2012 Final Research Report
  • [Presentation] Spectroscopic Visualization of Audible Sound-Induced Liquid Vibrations Using A Supramolecvdar Nanofiber2011

    • Author(s)
      津田明彦
    • Organizer
      International Conference on Polymers and Advanced Materials (POLYMAT 2011)
    • Place of Presentation
      Huatulco, Mexico(招待講演)
    • Year and Date
      2011-10-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] Chiral Interaction of Cyclic Oligopyrrole with DNA2011

    • Author(s)
      家真知子
    • Organizer
      International Conference on Polymers and Advanced Materials (POLYMAT 2011)
    • Place of Presentation
      Huatulco, Mexico
    • Year and Date
      2011-10-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] Unequal Linear Dichroism of P- and M-Isomers of A Self-Assembled Helical Anthracene Nanofiber in A Vortex2011

    • Author(s)
      安藤康成
    • Organizer
      International Conference on Polymers and Advanced Materials (POLYMAT 2011)
    • Place of Presentation
      Huatulco, Mexico
    • Year and Date
      2011-10-18
    • Related Report
      2011 Annual Research Report
  • [Presentation] アゾベンゼンユニットを有する巨大環状オリゴピロールの合成と光異性化2011

    • Author(s)
      劉冠凡
    • Organizer
      日本化学会第91春季年会(2011)
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリアセチレンによるDNAのキラルセンシング2011

    • Author(s)
      辻本裕也
    • Organizer
      日本化学会第91春季年会(2011)
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] アントラセンナノファイバーによる液体流動の分光学的可視化2011

    • Author(s)
      安藤康成
    • Organizer
      日本化学会第91春季年会(2011)
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] DNAによる大環状オリゴピロールのねじれ誘導2011

    • Author(s)
      家真知子
    • Organizer
      日本化学会第91春季年会(2011)
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 自己活性化超分子錯体による二重活性化反応2011

    • Author(s)
      川上一光
    • Organizer
      日本化学会第91春季年会(2011)
    • Place of Presentation
      神奈川大学(神奈川県)
    • Year and Date
      2011-03-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 可聴音によるナノファイバーの整列現象2011

    • Author(s)
      津田明彦
    • Organizer
      京都大学グローバル COE シンポジウム 低温合成法による新機能製材料の創成(第9回)
    • Place of Presentation
      京都大学理学部
    • Year and Date
      2011-02-21
    • Related Report
      2012 Final Research Report
  • [Presentation] 可聴音によるナノファイバーの整列現象2011

    • Author(s)
      津田明彦
    • Organizer
      京都大学グローバルCOEシンポジウム 低温合成法による新機能製材料の創成(第9回)
    • Place of Presentation
      京都大学(京都府)(招待講演)
    • Year and Date
      2011-02-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Chiral Sensing of DNA with a Cationic Polyacetylene2011

    • Author(s)
      辻本裕也
    • Organizer
      Fifth International Conference on Advanced Materials and Nanotechnology
    • Place of Presentation
      Willington (New Zealand)
    • Year and Date
      2011-02-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Spectroscopic Visualization of Audible Sound-Induced Liquid Vibrations Using a Supramolecular Nanofiber2011

    • Author(s)
      津田 明彦
    • Organizer
      AMN-5 Fifth International Conference Advanced Materials and Nanotechnology
    • Place of Presentation
      ニュージーランド
    • Year and Date
      2011-02-10
    • Related Report
      2012 Final Research Report
  • [Presentation] Spectroscopic Visualization of Audible Sound-Induced Liquid Vibrations Using a Supramolecular Nanofiber2011

    • Author(s)
      津田明彦
    • Organizer
      Fifth International Conference on Advanced Materials and Nanotechnology
    • Place of Presentation
      Willington (New Zealand)
    • Year and Date
      2011-02-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Spectroscopic Visualization of Sound-Induced Liquid Vibrations using a Supramolecular Nanofiber2010

    • Author(s)
      津田 明彦
    • Organizer
      日本学術振興会二国間交流事業日印セミナー
    • Place of Presentation
      ホテル北野プラザ六甲荘
    • Year and Date
      2010-12-03
    • Related Report
      2012 Final Research Report
  • [Presentation] Spectroscopic Visualization of Sound-Induced Liquid Vibrations using a Supramolecular Nanofiber2010

    • Author(s)
      津田明彦
    • Organizer
      日本学術振興会二国間交流事業日印セミナーIndo-Japan Joint Workshop on "New Frontiers of Molecular Spectroscopy ; from Gas Phase to Proteins"
    • Place of Presentation
      ホテル北野プラザ六甲荘(兵庫県)(招待講演)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリアセチレンによるDNAのキラルセンシンク2010

    • Author(s)
      辻本裕也
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(北海道)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] DNAによる大環状オリゴピロールのねじれ誘導2010

    • Author(s)
      家真知子
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(北海道)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Double-Activated Supramolecular Reaction in Transesterification of Acyclic || Oligoether Substrates and Metal Alkoxides2010

    • Author(s)
      川上一光
    • Organizer
      39th International Conference on Coordination Chemistry
    • Place of Presentation
      Adelaide (South Australia)
    • Year and Date
      2010-07-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 自己活性化超分子錯体の反応化学2010

    • Author(s)
      津田 明彦
    • Organizer
      錯体化学会若手の会第42回近畿地区勉強会
    • Place of Presentation
      京都大学 桂キャンパス
    • Year and Date
      2010-05-29
    • Related Report
      2012 Final Research Report
  • [Presentation] 自己活性化超分子錯体の反応化学2010

    • Author(s)
      津田明彦
    • Organizer
      錯体化学会若手の会第42回近畿地区勉強会
    • Place of Presentation
      京都大学(京都府)(招待講演)
    • Year and Date
      2010-05-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] モリブデンブルーと機能性エレメントによる超分子ナノマテリアル2010

    • Author(s)
      津田 明彦
    • Organizer
      新素材技術部会講演会
    • Place of Presentation
      新化学発展協会
    • Year and Date
      2010-04-19
    • Related Report
      2012 Final Research Report
  • [Book] Multiporphyrin Arrays: Fundamentals and Applications2012

    • Author(s)
      津田明彦
    • Publisher
      Pan Stanford Publishing Pte. Ltd.
    • Related Report
      2012 Final Research Report
  • [Book] Multiporphyrin Arrays : Fundamentals and Applications2012

    • Author(s)
      Akihiko Tsuda
    • Publisher
      Pan Stanford Publishing Pte.Ltd.
    • Related Report
      2011 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www2.kobe-u.ac.jp/~akihiko/index.html

    • Related Report
      2012 Final Research Report
  • [Patent(Industrial Property Rights)] ハロゲン化炭化水素に光照射して得られる混合物の使用2012

    • Inventor(s)
      津田明彦
    • Industrial Property Rights Holder
      神戸大学
    • Industrial Property Number
      2012-048180
    • Filing Date
      2012-03-05
    • Related Report
      2012 Final Research Report 2011 Annual Research Report

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Published: 2010-08-23   Modified: 2019-07-29  

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