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Search and synthesis of new superconducting materials reacting with lithium

Research Project

Project/Area Number 22540376
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionNational Institute for Materials Science

Principal Investigator

TAKEYA Hiroyuki  独立行政法人物質・材料研究機構, 超伝導線材ユニット, 主席研究員 (80197342)

Co-Investigator(Kenkyū-buntansha) MOCHIKU Takashi  独立行政法人物質・材料研究機構, 超伝導物性ユニット主, 主幹研究員 (20354293)
TOGANO Kazumasa  独立行政法人物質・材料研究機構, 超伝導線材ユニット, 研究業務員 (60361169)
Project Period (FY) 2010 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2012: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords強相関系 / 新物質探索 / アルカリ土類金属 / ホモロガス化合物 / 超伝導 / 磁気抵抗効果 / 超伝導体 / リチウム / 低温物性
Research Abstract

Two kinds of new superconducting materials have been discovered in this research. One is LixRhBy (Tc=3K). We confirmed its superconductivity without a centro-symmetric structure. This material is received attention in the noncentro-symmetric superconductivity, which is similar to Li2Pd3B and Li2Pt3B. Another material is an homologous series compounds of AnM3n-1X2n [A:Ca, Sr, Ba, M: Rh, Pd, X:B] (Tc=4K, 6K, 9K) .

Report

(4 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report
  • Research Products

    (55 results)

All 2013 2012 2011 2010 Other

All Journal Article (28 results) (of which Peer Reviewed: 28 results) Presentation (18 results) (of which Invited: 2 results) Book (6 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Superconducting Fullerene Nanowhiskers2012

    • Author(s)
      H.Takeya, K.Miyazawa, R.Kato, T.Wakahara, T.Ozaki, H.Okazaki, T.Yamaguchi, Y.Takano
    • Journal Title

      Molecules

      Volume: 17 Issue: 5 Pages: 4851-4859

    • DOI

      10.3390/molecules17054851

    • NAID

      40019428182

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Comparative Photoemission Studies on Superconducting Gap of Filled Skutterudite Superconductors LaPt_4Ge_<12> and PrPt_4Ge_<12>2012

    • Author(s)
      Y. Nakamura, et al.
    • Journal Title

      Phys. Rev. B

      Volume: 86 Issue: 1 Pages: 014521-014521

    • DOI

      10.1103/physrevb.86.014521

    • Related Report
      2012 Annual Research Report 2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] One-step synthesis of K_xFe_<2-y>Se_2 single crystal for high critical current density2012

    • Author(s)
      Toshinori Ozaki
    • Journal Title

      Europhysics Letters

      Volume: 98 Issue: 2 Pages: 27002-27002

    • DOI

      10.1209/0295-5075/98/27002

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Quantum Limiting Behaviors of a Vortex Core in an Anisotropic Gap Superconductor2012

    • Author(s)
      Shin-ichi Kaneko, et al
    • Journal Title

      Journal of the Physical Society of Japan

      Volume: 81 Issue: 6 Pages: 063701-063701

    • DOI

      10.1143/jpsj.81.063701

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning in magnetic modes in Tb(CoxNi1-x)(2)B2C: From longitudinal spin-density waves to simple ferromagnetism2012

    • Author(s)
      M. ElMassalami
    • Journal Title

      Phys. Rev. B

      Volume: 85 Issue: 17

    • DOI

      10.1103/physrevb.85.174412

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Weak Spin Fluctuation with Finite Wave Vector and Superconducting Gap Symmetry in K_xFe_Se_2: ^<77>Se Nuclear Magnetic Resonance2012

    • Author(s)
      H. Kotegawa, H. Tou, 他4名
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 81 Issue: 10 Pages: 104712-104712

    • DOI

      10.1143/jpsj.81.104712

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unidirectional Electronic Structure in the Parent State of Iron-Chalcogenide Superconductor Fe1+delta Te2012

    • Author(s)
      T. Machida
    • Journal Title

      J. Phys. Soc. Jpn

      Volume: 81 Issue: 7 Pages: 74714-74714

    • DOI

      10.1143/jpsj.81.074714

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-dimensional Electronic Order in Fe1.07Te Probed by Scanning Tunneling Spectroscopy2012

    • Author(s)
      T. Machida
    • Journal Title

      J. Superconductivity and Novel Magnetism

      Volume: 25 Issue: 5 Pages: 1273-1276

    • DOI

      10.1007/s10948-012-1581-6

    • Related Report
      2012 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Transport properties of the new Fe-based superconductor KxFe2Se2 (Tc=33K)2011

    • Author(s)
      Y.Mizuguchi, H.Takeya, Y.Kawasaki, T.Ozaki, S.Tsuda, T.Yamaguchi, Y.Takano
    • Journal Title

      Appl.Phys.Lett

      Volume: 98 Issue: 4

    • DOI

      10.1063/1.3549702

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] A New Noncentrosymmetric Superconducting Phase in the Li-Rh-B System2011

    • Author(s)
      H.Takeya, H.Fujii, M.ElMassalami, F.Chaves, S.Ooi, T.Mochiku, Y.Takano, K.Hirata, K.Togano
    • Journal Title

      J.Phys.Soc.Jpn

      Volume: 80 Issue: 1 Pages: 013702-013702

    • DOI

      10.1143/jpsj.80.013702

    • NAID

      210000108839

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] On the ferromagnetism of AlFe2B22011

    • Author(s)
      M. ElMassalami, DD. Oliveira, H. Takeya
    • Journal Title

      J. Magn. Magn. Mater

      Volume: 323[16] Issue: 16 Pages: 2133-2136

    • DOI

      10.1016/j.jmmm.2011.03.008

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Linear magnetoresistivity in the ternary AM_2B_2 and A_3Rh_8B_6 phases (A = Ca, Sr; M = Rh, Ir)2011

    • Author(s)
      H. Takeya, M. ElMassalami
    • Journal Title

      Phys. Rev.

      Volume: B, 84 Issue: 6

    • DOI

      10.1103/physrevb.84.064408

    • Related Report
      2012 Final Research Report 2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nanoscale phase separation in the iron chalcogenide superconductor K0.8Fe1.6Se2 as seen via scanning nanofocused x-ray diffraction2011

    • Author(s)
      A.Ricci, N.Poccia, G.Campi, B.Joseph, G.Arrighetti, L.Barba, M.Reynolds, M.Burghammer, H.Takeya, Y.Mizuguchi, Y.Takano, M.Colapietro, N.L.Saini, A.Bianconi
    • Journal Title

      Phys.Rev.B

      Volume: 84[6] Issue: 6

    • DOI

      10.1103/physrevb.84.060511

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Pressure Study of the New Iron-Based Superconductor K0.8Fe2Se22011

    • Author(s)
      Y.Kawasaki, Y.Mizuguchi, K.Deguchi, T.Watanabe, T.Ozaki, S.Tsuda, T.Yamaguchi, H.Takeya, Y.Takano
    • Journal Title

      J.Phys.Soc.Jpn

      Volume: 80 Issue: 7 Pages: 075002-075002

    • DOI

      10.1143/jpsj.80.075002

    • NAID

      210000109120

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Intrinsic phase separation in superconducting K0.8Fe1.6Se2 (Tc=31.8K) single crystals2011

    • Author(s)
      A.Ricci, N.Poccia, B.Joseph, G.Arrighetti, L.Barba, J.Plaisier, G.Campi, Y.Mizuguchi, H.Takeya, Y.Takano, N.L.Saini, A.Bianconi
    • Journal Title

      Supercond.Sci.Technol.

      Volume: 24[8] Issue: 8 Pages: 082002-082002

    • DOI

      10.1088/0953-2048/24/8/082002

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A New Noncentrosymmetric Superconducting Phase in the Li-Rh-B System2011

    • Author(s)
      Hiroyuki Takeya
    • Journal Title

      J.Phys.Soc.Jpn.

      Volume: 80

    • NAID

      40017436297

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution from Non-Fermi-to Fermi-Liquid Transport via Isovalent Doping in BaFe2(As1-xPx) 2 Superconductors2010

    • Author(s)
      S. Kasahara, T. Shibauchi, K. Hashimoto, K. Ikada, S. Tonegawa, H. Ikeda, H. Takeya, K. Hirata, T. Terashima, and Y. Matsuda
    • Journal Title

      Phys. Rev

      Volume: B81 Issue: 18 Pages: 184519-184519

    • DOI

      10.1103/physrevb.81.184519

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Structure of the Novel Filled Skutterudite PrPt_4Ge_12 Superconductor2010

    • Author(s)
      Y. Nakamura, H. Okazaki, R. Yoshida, T. Wakita, M. Hirai, Y. Muraoka, H. Takeya, K. Hirata,H. Kumigashira, M. Oshima and T. Yokoya
    • Journal Title

      J. Phys. Soc. Jpn.

      Volume: 79[12] Issue: 12 Pages: 124701-124701

    • DOI

      10.1143/jpsj.79.124701

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of FeSe single crystals2010

    • Author(s)
      Hiroyuki Takeya
    • Journal Title

      Physics C

      Volume: 470

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Specific heat investigation on the magnetic phase diagrams of RNi2B2C(R=Gd, Er)2010

    • Author(s)
      M.ELMassalami
    • Journal Title

      J.Mag.Mag.Mat.

      Volume: 322 Pages: 523-529

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Superconductivity induced by isovalent doping in single crystals of BaFe2(As1-xPx)22010

    • Author(s)
      S.Kasahara
    • Journal Title

      Physica C

      Volume: 470

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evolution from non-Fermi- to Fermi-liquid transport via isovalent dopingin BaFe2(As1-xPx)2 superconductors2010

    • Author(s)
      S.Kasahara
    • Journal Title

      Phys.Rev.B

      Volume: 81

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electronic Structure of the Novel Filled Skutterudite PrPt4Ge12 Superconductor2010

    • Author(s)
      Yoshiaki NAKAMURA
    • Journal Title

      J.Phys.Soc.Jpn.

      Volume: 79

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Ni and Co doping on the physical properties of tetragonal FeSe0.5Te0.5 superconductor2010

    • Author(s)
      R.Shipra
    • Journal Title

      Physica C

      Volume: 470 Pages: 528-532

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The influence of B variation on the electronic properties of Al3Ni20Bx(6〓x〓12)2010

    • Author(s)
      M.Elhadi
    • Journal Title

      J.Alloys and Compounds

      Volume: 499 Pages: 11-16

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Creation of vortices by ferromagnetic order in ErNi2B2C2010

    • Author(s)
      Hazuki Kawano-Furukawa
    • Journal Title

      Physica C

      Volume: 470

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Unusual pinning induced by vortex motion in YNi2B2C2010

    • Author(s)
      S.Okuma
    • Journal Title

      Physica C

      Volume: 470

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Importance of dislocations in vortex creep revealed in YNi2B2C by observations in real time and space by STM2010

    • Author(s)
      Kazuharu Uchiyama
    • Journal Title

      Physica C

      Volume: 470

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Presentation] Ca/Sr-Rh-B系ホモロガス化合物の合成と結晶化学2013

    • Author(s)
      竹屋 浩幸
    • Organizer
      日本物理学会 第68回年次大会
    • Place of Presentation
      広島大学
    • Related Report
      2012 Final Research Report
  • [Presentation] Ca/Sr-Rh-B系ホモロガス化合物の合成と結晶化学 / Ca/Sr-Rh-B系ホモロガス化合物の合成と結晶化学2013

    • Author(s)
      竹屋 浩幸
    • Organizer
      日本物理学会 第68回年次大会
    • Place of Presentation
      広島大学、東広島市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Characterization and Properties of Potassium-doped Fullerene Nanowhiskers2012

    • Author(s)
      竹屋 浩幸
    • Organizer
      STAC-6
    • Place of Presentation
      Mielparque -Yokohama横浜市
    • Year and Date
      2012-06-26
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis and Superconducting Properties of Potassium-doped Fullerene2012

    • Author(s)
      竹屋 浩幸
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      パシフィコ横浜,横浜
    • Related Report
      2012 Final Research Report
  • [Presentation] フラーレンナノウィスカーの超伝導2012

    • Author(s)
      竹屋 浩幸
    • Organizer
      日本物理学会 第67回年次大会
    • Place of Presentation
      関西学院大学(西ノ宮)
    • Related Report
      2012 Final Research Report
  • [Presentation] Synthesis of the C60 nanowhiskers that exhibited a good superconductivity2012

    • Author(s)
      竹屋 浩幸
    • Organizer
      第42回フラーレン・ナノチューブ・グラフェン総合シンポジウム
    • Place of Presentation
      東大本郷(東京)
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Synthesis and Superconducting Properties of Potassium-doped Fullerene2012

    • Author(s)
      竹屋 浩幸
    • Organizer
      IUMRS-ICEM2012
    • Place of Presentation
      パシフィコ横浜、横浜市
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] Characterization and Properties of Potassium-doped Fullerene Nanowhiskers2012

    • Author(s)
      竹屋 浩幸
    • Organizer
      STAC-6
    • Place of Presentation
      Mielparque-Yokohama、横浜市
    • Related Report
      2012 Annual Research Report
    • Invited
  • [Presentation] One-step合成法によるTe置換KxFe2-ySe2単結晶育成と超伝導特性 / One-step合成法によるTe置換KxFe2-ySe2単結晶育成と超伝導特性2012

    • Author(s)
      尾崎壽紀
    • Organizer
      2012年 秋季 第73回応用物理学会学術講演会
    • Place of Presentation
      愛媛大学、松山大学、松山市
    • Related Report
      2012 Annual Research Report
  • [Presentation] Fabrication and superconducting properties of iron-chalgogenide superconducting wires2012

    • Author(s)
      尾崎壽紀
    • Organizer
      CEC24ーICMC2012
    • Place of Presentation
      福岡国際会議場、博多区
    • Related Report
      2012 Annual Research Report
  • [Presentation] フラーレンナノウィスカーの超伝導2012

    • Author(s)
      竹屋浩幸
    • Organizer
      日本物理学会第67回年次大会
    • Place of Presentation
      関西学院大学(西ノ宮)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Single Crystal Growth and Polycrystalline Fabrication of K_0.8Fe_1.6Se_2 Superconductors2011

    • Author(s)
      竹屋 浩幸
    • Organizer
      New Science Created by Materials with Nano Spaces
    • Place of Presentation
      東北大学(仙台)
    • Related Report
      2012 Final Research Report
  • [Presentation] Fabrication of Dense Polycrystalline KxFe2-x/2Se2 by High Temperature Melting Process2011

    • Author(s)
      竹屋 浩幸
    • Organizer
      EUCUS2011
    • Place of Presentation
      ハーグ国際会議場(オランダ)
    • Related Report
      2012 Final Research Report 2011 Annual Research Report
  • [Presentation] Li-Rh-B系における空間反転対称性の破れた新超伝導相と周辺物質2011

    • Author(s)
      竹屋 浩幸
    • Organizer
      新学術領域「トポロジカル量子現象」第6回集中連携研究会
    • Place of Presentation
      大阪大学(豊中市)
    • Related Report
      2012 Final Research Report
  • [Presentation] New Noncentrosymmetric Superconducting Materials in Ternary Alkaline Rhodium-Borides2011

    • Author(s)
      竹屋 浩幸
    • Organizer
      Novel Superconductors and Super Materials
    • Place of Presentation
      日本科学未来館(東京)
    • Related Report
      2012 Final Research Report
  • [Presentation] Li-Rh-B系における空間反転対称性の破れた新超伝導相と周辺物質2011

    • Author(s)
      竹屋浩幸
    • Organizer
      新学術領域「トポロジカル量子現象」第6回集中連携研究会
    • Place of Presentation
      大阪大学(豊中市)(招待講演)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Single Crystal Growth and Polycrystalline Fabrication of K0.8Fe1.6Se2 Superconductors2011

    • Author(s)
      竹屋浩幸
    • Organizer
      New Science Created by Materials with Nano Spaces
    • Place of Presentation
      東北大学(仙台)
    • Related Report
      2011 Annual Research Report
  • [Presentation] New Noncentrosymmetric Superconducting Materials in Ternary Alkaline Rhodium-Borides2011

    • Author(s)
      Hiroyuki Takeya
    • Organizer
      Novel Superconductors and Super Materials 2011
    • Place of Presentation
      日本科学未来館(東京)
    • Related Report
      2010 Annual Research Report
  • [Book] MATERIALS INTEGRATIO Nvol.25 No.102012

    • Author(s)
      竹屋浩幸, 宮澤薫一, 高野義彦
    • Publisher
      アルカリ金属添加による超伝導フラーレンナノウィスカーの開発
    • Related Report
      2012 Final Research Report
  • [Book] 機能材料 Vol.32 No.102012

    • Author(s)
      竹屋浩幸, 宮澤薫一, 高野義彦
    • Publisher
      超伝導状態になる炭素系フラーレン繊維
    • Related Report
      2012 Final Research Report
  • [Book] 機能材料 Vol.32 No.102012

    • Author(s)
      竹屋浩幸
    • Total Pages
      6
    • Publisher
      シー・エム・シー出版
    • Related Report
      2012 Annual Research Report
  • [Book] MATERIALS INTEGRATION Vol.25 No.102012

    • Author(s)
      竹屋浩幸
    • Total Pages
      7
    • Publisher
      ティー・アイ・シー
    • Related Report
      2012 Annual Research Report
  • [Book] 工業材料 Vol.60/Number 112012

    • Author(s)
      宮澤薫一
    • Total Pages
      4
    • Publisher
      日刊工業新聞
    • Related Report
      2012 Annual Research Report
  • [Book] 2013ナノカーボン技術大全2012

    • Author(s)
      宮澤薫一
    • Total Pages
      5
    • Publisher
      電子ジャーナル
    • Related Report
      2012 Annual Research Report
  • [Remarks]

    • URL

      http://samurai.nims.go.jp/TAKEYA_Hiroyuki-j.html

    • Related Report
      2012 Final Research Report
  • [Remarks] NIMS Researchers Database SAMURAI

    • URL

      http://samurai.nims.go.jp/TAKEYA_Hiroyuki-j.html

    • Related Report
      2012 Annual Research Report
  • [Patent(Industrial Property Rights)] 超電導フラーレン材料及びその製造方法2011

    • Inventor(s)
      竹屋浩幸/山口尚秀/高野義彦/加藤良栄/若原孝次/宮澤薫一
    • Industrial Property Rights Holder
      物質・材料研究機構
    • Industrial Property Number
      2011-279825
    • Filing Date
      2011-12-21
    • Related Report
      2011 Annual Research Report

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Published: 2010-08-23   Modified: 2020-05-15  

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