Photo-melting and photo-crystallization of metal complexes toward photo-controlled molecular accumulation
Project/Area Number |
22550049
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
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Research Institution | Hokkaido University |
Principal Investigator |
CHANG Ho-chol 北海道大学, 大学院・理学研究院, 准教授 (60335198)
|
Project Period (FY) |
2010 – 2011
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Project Status |
Completed (Fiscal Year 2011)
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Budget Amount *help |
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
|
Keywords | 金属錯体 / 光融解 / 原子互変異性 / パルス光 / 結晶化 / 電子移動 / 準安定 / 励起状態 / 原子価互変異性 / コバルト錯体 / 光誘起電子移動 / 融解 / 双安定性 |
Research Abstract |
In this study, we found that a cobalt complex showing valence tautomerization demonstrated light-induced melting phenomenon triggered by ns-pulsed light. The experiments at 3 K revealed that the light-induced melting is triggered by an intramolecular electron transfer processes
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Report
(3 results)
Research Products
(46 results)
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[Journal Article] Chromic Behaviors of Hexagonal Columnar Liquid Crystalline Platinum Complexes with Catecholato, 2-Thiophenolato, and Benzenedithiolato2011
Author(s)
Ho-Chol Chang, Kazuki Komasaka, Keisuke Kishida, Tomoki Shiozaki, Takashi Ohmori, Takeshi Matsumoto, Atsushi Kobayashi, Masako Kato, Susumu Kitagawa
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Journal Title
Inorg. Chem.
Volume: 50
Pages: 4279-4288
Related Report
Peer Reviewed
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[Journal Article]2011
Author(s)
H.-C.Chang, K.Komasaka, K.Kishida, T.Shiozaki, T.Ohmori, T.Matsumoto, A.Kobayashi, M.Kato, S.Kitagawa
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Journal Title
Inorg. Chem.
Volume: 50
Issue: 10
Pages: 4279-4288
DOI
Related Report
Peer Reviewed
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