Design and Synthesis of Suprarmolecular Metal Complexes Under the Chemical Reaction Fields of Polyoxometalates
| Project/Area Number |
22550065
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kanagawa University |
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Principal Investigator |
NOMIYA Kenji 神奈川大学, 理学部, 教授 (80119354)
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| Project Period (FY) |
2010 – 2012
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| Project Status |
Completed (Fiscal Year 2012)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2012: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2010: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
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| Keywords | 超分子金属錯体 / ポリオキソメタレート / 飽和型 / 欠損型 / 第4属金属イオン / 第11属金属イオン / ルイス酸触媒作用 / エポキシ化触媒作用 / 欠損種 / 反応場 / チタン / ジルコニウム / ハフニウム / 金 / ポリオキソメタレート(ポリ酸塩) / チタン(IV) / ジルコニウム(IV) / ハフニウム(IV) / 金(I) / 合成 |
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| Research Abstract |
Novel supramolecular metal complexes were synthesized using Group IV (Ti, Zr, Hf) and Group XI (Ag, Au) metal ions under the chemical reaction fields of the saturated and lacunary species ofpolyoxometalates (POMs) and their solid-state and solution structures were determined. Using some ofthe complexes, Lewis acid catalysis and epoxidation catalysis were also examined.
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Report
(4 results)
Research Products
(83 results)
